| 总结: | Nanostructured Bi<sub>2</sub>WO<sub>6</sub> thin film electrodes with enhanced solar energy conversion and photocatalytic properties have been fabricated using Aerosol-Assisted Chemical Vapor Deposition (AACVD). By conveniently controlling the deposition process parameters, Bi<sub>2</sub>WO<sub>6</sub> electrodes were fabricated with nanoplates and hierarchical buckyball-shaped microsphere structures morphology. A detailed study has been conducted to correlate the structure and morphology with the photoelectrochemical (PEC) and photocatalytic dye degradation performance. The PEC investigations revealed that the hierarchical buckyball-shaped microsphere structured Bi<sub>2</sub>WO<sub>6</sub> electrodes have shown the photocurrent density of 220 μAcm<sup>−2</sup> while nanoplates have a photocurrent density of 170 μAcm<sup>−2</sup> at 0.23 V (vs. Ag/AgCl/3M KCl) under AM1.5 illumination. The PEC characterization of Bi<sub>2</sub>WO<sub>6</sub> electrodes also reveals that the photocurrent density and photocurrent onset potential is strongly dependent on the orientation and morphology, hence the deposition parameters. Similarly, the methylene blue (MB) and rhodamine B (RhB) photodegradation performance of Bi<sub>2</sub>WO<sub>6</sub> electrodes also show a strong correlation with morphology. This finding provides an appropriate route to engineer the energetic and interfacial properties of Bi<sub>2</sub>WO<sub>6</sub> electrode to enhance solar energy conversion and the photocatalytic performance of semiconductor materials.
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