Microgels at Interfaces Behave as 2D Elastic Particles Featuring Reentrant Dynamics
Soft colloids are increasingly used as model systems to address fundamental issues such as crystallization and the glass and jamming transitions. Among the available classes of soft colloids, microgels are emerging as the gold standard. Since their great internal complexity makes their theoretical c...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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American Physical Society
2020-07-01
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| Series: | Physical Review X |
| Online Access: | http://doi.org/10.1103/PhysRevX.10.031012 |
| _version_ | 1818856785746853888 |
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| author | Fabrizio Camerin Nicoletta Gnan José Ruiz-Franco Andrea Ninarello Lorenzo Rovigatti Emanuela Zaccarelli |
| author_facet | Fabrizio Camerin Nicoletta Gnan José Ruiz-Franco Andrea Ninarello Lorenzo Rovigatti Emanuela Zaccarelli |
| author_sort | Fabrizio Camerin |
| collection | DOAJ |
| description | Soft colloids are increasingly used as model systems to address fundamental issues such as crystallization and the glass and jamming transitions. Among the available classes of soft colloids, microgels are emerging as the gold standard. Since their great internal complexity makes their theoretical characterization very hard, microgels are commonly modeled, at least in the small-deformation regime, within the simple framework of linear elasticity theory. Here we show that there exist conditions where its range of validity can be greatly extended, providing strong numerical evidence that microgels adsorbed at an interface follow the two-dimensional Hertzian theory, and hence behave like 2D elastic particles, up to very large deformations, in stark contrast to what found in bulk conditions. We are also able to estimate Young’s modulus of the individual particles and, by comparing it with its counterpart in bulk conditions, we demonstrate a significant stiffening of the polymer network at the interface. Finally, by analyzing dynamical properties, we predict multiple reentrant phenomena: By a continuous increase of particle density, microgels first arrest and then refluidify due to the high penetrability of their extended coronas. We observe this anomalous behavior in a range of experimentally accessible conditions for small and loosely cross-linked microgels. The present work thus establishes microgels at interfaces as a new model system for fundamental investigations, paving the way for the experimental synthesis and research on unique high-density liquidlike states. In addition, these results can guide the development of novel assembly and patterning strategies on surfaces and the design of novel materials with desired interfacial behavior. |
| first_indexed | 2024-12-19T08:30:01Z |
| format | Article |
| id | doaj.art-c3e9b738a20f48d79ab9046c76c22522 |
| institution | Directory Open Access Journal |
| issn | 2160-3308 |
| language | English |
| last_indexed | 2024-12-19T08:30:01Z |
| publishDate | 2020-07-01 |
| publisher | American Physical Society |
| record_format | Article |
| series | Physical Review X |
| spelling | doaj.art-c3e9b738a20f48d79ab9046c76c225222022-12-21T20:29:12ZengAmerican Physical SocietyPhysical Review X2160-33082020-07-0110303101210.1103/PhysRevX.10.031012Microgels at Interfaces Behave as 2D Elastic Particles Featuring Reentrant DynamicsFabrizio CamerinNicoletta GnanJosé Ruiz-FrancoAndrea NinarelloLorenzo RovigattiEmanuela ZaccarelliSoft colloids are increasingly used as model systems to address fundamental issues such as crystallization and the glass and jamming transitions. Among the available classes of soft colloids, microgels are emerging as the gold standard. Since their great internal complexity makes their theoretical characterization very hard, microgels are commonly modeled, at least in the small-deformation regime, within the simple framework of linear elasticity theory. Here we show that there exist conditions where its range of validity can be greatly extended, providing strong numerical evidence that microgels adsorbed at an interface follow the two-dimensional Hertzian theory, and hence behave like 2D elastic particles, up to very large deformations, in stark contrast to what found in bulk conditions. We are also able to estimate Young’s modulus of the individual particles and, by comparing it with its counterpart in bulk conditions, we demonstrate a significant stiffening of the polymer network at the interface. Finally, by analyzing dynamical properties, we predict multiple reentrant phenomena: By a continuous increase of particle density, microgels first arrest and then refluidify due to the high penetrability of their extended coronas. We observe this anomalous behavior in a range of experimentally accessible conditions for small and loosely cross-linked microgels. The present work thus establishes microgels at interfaces as a new model system for fundamental investigations, paving the way for the experimental synthesis and research on unique high-density liquidlike states. In addition, these results can guide the development of novel assembly and patterning strategies on surfaces and the design of novel materials with desired interfacial behavior.http://doi.org/10.1103/PhysRevX.10.031012 |
| spellingShingle | Fabrizio Camerin Nicoletta Gnan José Ruiz-Franco Andrea Ninarello Lorenzo Rovigatti Emanuela Zaccarelli Microgels at Interfaces Behave as 2D Elastic Particles Featuring Reentrant Dynamics Physical Review X |
| title | Microgels at Interfaces Behave as 2D Elastic Particles Featuring Reentrant Dynamics |
| title_full | Microgels at Interfaces Behave as 2D Elastic Particles Featuring Reentrant Dynamics |
| title_fullStr | Microgels at Interfaces Behave as 2D Elastic Particles Featuring Reentrant Dynamics |
| title_full_unstemmed | Microgels at Interfaces Behave as 2D Elastic Particles Featuring Reentrant Dynamics |
| title_short | Microgels at Interfaces Behave as 2D Elastic Particles Featuring Reentrant Dynamics |
| title_sort | microgels at interfaces behave as 2d elastic particles featuring reentrant dynamics |
| url | http://doi.org/10.1103/PhysRevX.10.031012 |
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