Modelling of hydrogen sulfide fate and emissions in extended aeration sewage treatment plant using TOXCHEM simulations

Abstract Odors due to the emission of hydrogen sulfide (H2S) have been a concern in the sewage treatment plants over the last decades. H2S fate and emissions from extended aeration activated sludge (EAAS) system in Muharram Aisha-sewage treatment plant (MA-STP) were studied using TOXCHEM model. Sens...

Full description

Bibliographic Details
Main Authors: Haider M. Zwain, Basim K. Nile, Ahmed M. Faris, Mohammadtaghi Vakili, Irvan Dahlan
Format: Article
Language:English
Published: Nature Portfolio 2020-12-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-020-79395-8
_version_ 1818855489165852672
author Haider M. Zwain
Basim K. Nile
Ahmed M. Faris
Mohammadtaghi Vakili
Irvan Dahlan
author_facet Haider M. Zwain
Basim K. Nile
Ahmed M. Faris
Mohammadtaghi Vakili
Irvan Dahlan
author_sort Haider M. Zwain
collection DOAJ
description Abstract Odors due to the emission of hydrogen sulfide (H2S) have been a concern in the sewage treatment plants over the last decades. H2S fate and emissions from extended aeration activated sludge (EAAS) system in Muharram Aisha-sewage treatment plant (MA-STP) were studied using TOXCHEM model. Sensitivity analysis at different aeration flowrate, H2S loading rate, wastewater pH, wastewater temperature and wind speed were studied. The predicted data were validated against actual results, where all the data were validated within the limits, and the statistical evaluation of normalized mean square error (NMSE), geometric variance (VG), and correlation coefficient (R) were close to the ideal fit. The results showed that the major processes occurring in the system were degradation and emission. During summer (27 °C) and winter (12 °C), about 25 and 23%, 1 and 2%, 2 and 2%, and 72 and 73% were fated as emitted to air, discharged with effluent, sorbed to sludge, and biodegraded, respectively. At summer and winter, the total emitted concentrations of H2S were 6.403 and 5.614 ppm, respectively. The sensitivity results indicated that aeration flowrate, H2S loading rate and wastewater pH highly influenced the emission and degradation of H2S processes compared to wastewater temperature and wind speed. To conclude, TOXCHEM model successfully predicted the H2S fate and emissions in EAAS system.
first_indexed 2024-12-19T08:09:25Z
format Article
id doaj.art-c3f8f37d08a64931ad67567080e4a0ad
institution Directory Open Access Journal
issn 2045-2322
language English
last_indexed 2024-12-19T08:09:25Z
publishDate 2020-12-01
publisher Nature Portfolio
record_format Article
series Scientific Reports
spelling doaj.art-c3f8f37d08a64931ad67567080e4a0ad2022-12-21T20:29:40ZengNature PortfolioScientific Reports2045-23222020-12-0110111110.1038/s41598-020-79395-8Modelling of hydrogen sulfide fate and emissions in extended aeration sewage treatment plant using TOXCHEM simulationsHaider M. Zwain0Basim K. Nile1Ahmed M. Faris2Mohammadtaghi Vakili3Irvan Dahlan4College of Water Resources Engineering, Al-Qasim Green UniversityCollege of Engineering, University of KerbalaSchool of Civil Engineering, Iran University of Science and TechnologyGreen Intelligence Environmental School, Yangtze Normal UniversitySchool of Chemical Engineering, Universiti Sains Malaysia, Engineering CampusAbstract Odors due to the emission of hydrogen sulfide (H2S) have been a concern in the sewage treatment plants over the last decades. H2S fate and emissions from extended aeration activated sludge (EAAS) system in Muharram Aisha-sewage treatment plant (MA-STP) were studied using TOXCHEM model. Sensitivity analysis at different aeration flowrate, H2S loading rate, wastewater pH, wastewater temperature and wind speed were studied. The predicted data were validated against actual results, where all the data were validated within the limits, and the statistical evaluation of normalized mean square error (NMSE), geometric variance (VG), and correlation coefficient (R) were close to the ideal fit. The results showed that the major processes occurring in the system were degradation and emission. During summer (27 °C) and winter (12 °C), about 25 and 23%, 1 and 2%, 2 and 2%, and 72 and 73% were fated as emitted to air, discharged with effluent, sorbed to sludge, and biodegraded, respectively. At summer and winter, the total emitted concentrations of H2S were 6.403 and 5.614 ppm, respectively. The sensitivity results indicated that aeration flowrate, H2S loading rate and wastewater pH highly influenced the emission and degradation of H2S processes compared to wastewater temperature and wind speed. To conclude, TOXCHEM model successfully predicted the H2S fate and emissions in EAAS system.https://doi.org/10.1038/s41598-020-79395-8
spellingShingle Haider M. Zwain
Basim K. Nile
Ahmed M. Faris
Mohammadtaghi Vakili
Irvan Dahlan
Modelling of hydrogen sulfide fate and emissions in extended aeration sewage treatment plant using TOXCHEM simulations
Scientific Reports
title Modelling of hydrogen sulfide fate and emissions in extended aeration sewage treatment plant using TOXCHEM simulations
title_full Modelling of hydrogen sulfide fate and emissions in extended aeration sewage treatment plant using TOXCHEM simulations
title_fullStr Modelling of hydrogen sulfide fate and emissions in extended aeration sewage treatment plant using TOXCHEM simulations
title_full_unstemmed Modelling of hydrogen sulfide fate and emissions in extended aeration sewage treatment plant using TOXCHEM simulations
title_short Modelling of hydrogen sulfide fate and emissions in extended aeration sewage treatment plant using TOXCHEM simulations
title_sort modelling of hydrogen sulfide fate and emissions in extended aeration sewage treatment plant using toxchem simulations
url https://doi.org/10.1038/s41598-020-79395-8
work_keys_str_mv AT haidermzwain modellingofhydrogensulfidefateandemissionsinextendedaerationsewagetreatmentplantusingtoxchemsimulations
AT basimknile modellingofhydrogensulfidefateandemissionsinextendedaerationsewagetreatmentplantusingtoxchemsimulations
AT ahmedmfaris modellingofhydrogensulfidefateandemissionsinextendedaerationsewagetreatmentplantusingtoxchemsimulations
AT mohammadtaghivakili modellingofhydrogensulfidefateandemissionsinextendedaerationsewagetreatmentplantusingtoxchemsimulations
AT irvandahlan modellingofhydrogensulfidefateandemissionsinextendedaerationsewagetreatmentplantusingtoxchemsimulations