Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process
This study explored the use of a combination of hydrothermal and sol–gel methods to produce porous titanium dioxide (PTi) powder with a high specific surface area of 112.84 m<sup>2</sup>/g. The PTi powder was utilized as a filler in the fabrication of ultrafiltration nanocomposite membra...
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MDPI AG
2023-06-01
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author | Ahmadreza Zahedipoor Mehdi Faramarzi Amir Mansourizadeh Abdolmohammad Ghaedi Daryoush Emadzadeh |
author_facet | Ahmadreza Zahedipoor Mehdi Faramarzi Amir Mansourizadeh Abdolmohammad Ghaedi Daryoush Emadzadeh |
author_sort | Ahmadreza Zahedipoor |
collection | DOAJ |
description | This study explored the use of a combination of hydrothermal and sol–gel methods to produce porous titanium dioxide (PTi) powder with a high specific surface area of 112.84 m<sup>2</sup>/g. The PTi powder was utilized as a filler in the fabrication of ultrafiltration nanocomposite membranes using polysulfone (PSf) as the polymer. The synthesized nanoparticles and membranes were analyzed using various techniques, including BET, TEM, XRD, AFM, FESEM, FTIR, and contact angle measurements. The membrane’s performance and antifouling properties were also assessed using bovine serum albumin (BSA) as a simulated wastewater feed solution. Furthermore, the ultrafiltration membranes were tested in the forward osmosis (FO) system using a 0.6-weight-percent solution of poly (sodium 4-styrene sulfonate) as the osmosis solution to evaluate the osmosis membrane bioreactor (OsMBR) process. The results revealed that the incorporation of PTi nanoparticles into the polymer matrix enhanced the hydrophilicity and surface energy of the membrane, resulting in better performance. The optimized membrane containing 1% PTi displayed a water flux of 31.5 L/m<sup>2</sup>h, compared to the neat membrane water value of 13.7 L/m<sup>2</sup>h. The membrane also demonstrated excellent antifouling properties, with a flux recovery of 96%. These results highlight the potential of the PTi-infused membrane as a simulated osmosis membrane bioreactor (OsMBR) for wastewater treatment applications. |
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institution | Directory Open Access Journal |
issn | 2077-0375 |
language | English |
last_indexed | 2024-03-11T02:10:46Z |
publishDate | 2023-06-01 |
publisher | MDPI AG |
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series | Membranes |
spelling | doaj.art-c3f91c381b714cbebbb2ed09bd2267282023-11-18T11:33:34ZengMDPI AGMembranes2077-03752023-06-0113657710.3390/membranes13060577Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) ProcessAhmadreza Zahedipoor0Mehdi Faramarzi1Amir Mansourizadeh2Abdolmohammad Ghaedi3Daryoush Emadzadeh4Department of Chemical Engineering, Membrane Science and Technology Research Center (MSTRC), Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranDepartment of Chemical Engineering, Membrane Science and Technology Research Center (MSTRC), Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranDepartment of Chemical Engineering, Membrane Science and Technology Research Center (MSTRC), Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranDepartment of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranDepartment of Chemical Engineering, Membrane Science and Technology Research Center (MSTRC), Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranThis study explored the use of a combination of hydrothermal and sol–gel methods to produce porous titanium dioxide (PTi) powder with a high specific surface area of 112.84 m<sup>2</sup>/g. The PTi powder was utilized as a filler in the fabrication of ultrafiltration nanocomposite membranes using polysulfone (PSf) as the polymer. The synthesized nanoparticles and membranes were analyzed using various techniques, including BET, TEM, XRD, AFM, FESEM, FTIR, and contact angle measurements. The membrane’s performance and antifouling properties were also assessed using bovine serum albumin (BSA) as a simulated wastewater feed solution. Furthermore, the ultrafiltration membranes were tested in the forward osmosis (FO) system using a 0.6-weight-percent solution of poly (sodium 4-styrene sulfonate) as the osmosis solution to evaluate the osmosis membrane bioreactor (OsMBR) process. The results revealed that the incorporation of PTi nanoparticles into the polymer matrix enhanced the hydrophilicity and surface energy of the membrane, resulting in better performance. The optimized membrane containing 1% PTi displayed a water flux of 31.5 L/m<sup>2</sup>h, compared to the neat membrane water value of 13.7 L/m<sup>2</sup>h. The membrane also demonstrated excellent antifouling properties, with a flux recovery of 96%. These results highlight the potential of the PTi-infused membrane as a simulated osmosis membrane bioreactor (OsMBR) for wastewater treatment applications.https://www.mdpi.com/2077-0375/13/6/577porous titanium dioxideultrafiltrationnanocomposite membraneosmosis membrane bioreactorwastewater treatmentantifouling |
spellingShingle | Ahmadreza Zahedipoor Mehdi Faramarzi Amir Mansourizadeh Abdolmohammad Ghaedi Daryoush Emadzadeh Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process Membranes porous titanium dioxide ultrafiltration nanocomposite membrane osmosis membrane bioreactor wastewater treatment antifouling |
title | Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process |
title_full | Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process |
title_fullStr | Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process |
title_full_unstemmed | Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process |
title_short | Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process |
title_sort | integration of porous nanomaterial infused membrane in uf fo membrane hybrid for simulated osmosis membrane bioreactor osmbr process |
topic | porous titanium dioxide ultrafiltration nanocomposite membrane osmosis membrane bioreactor wastewater treatment antifouling |
url | https://www.mdpi.com/2077-0375/13/6/577 |
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