Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process

This study explored the use of a combination of hydrothermal and sol–gel methods to produce porous titanium dioxide (PTi) powder with a high specific surface area of 112.84 m<sup>2</sup>/g. The PTi powder was utilized as a filler in the fabrication of ultrafiltration nanocomposite membra...

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Main Authors: Ahmadreza Zahedipoor, Mehdi Faramarzi, Amir Mansourizadeh, Abdolmohammad Ghaedi, Daryoush Emadzadeh
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/13/6/577
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author Ahmadreza Zahedipoor
Mehdi Faramarzi
Amir Mansourizadeh
Abdolmohammad Ghaedi
Daryoush Emadzadeh
author_facet Ahmadreza Zahedipoor
Mehdi Faramarzi
Amir Mansourizadeh
Abdolmohammad Ghaedi
Daryoush Emadzadeh
author_sort Ahmadreza Zahedipoor
collection DOAJ
description This study explored the use of a combination of hydrothermal and sol–gel methods to produce porous titanium dioxide (PTi) powder with a high specific surface area of 112.84 m<sup>2</sup>/g. The PTi powder was utilized as a filler in the fabrication of ultrafiltration nanocomposite membranes using polysulfone (PSf) as the polymer. The synthesized nanoparticles and membranes were analyzed using various techniques, including BET, TEM, XRD, AFM, FESEM, FTIR, and contact angle measurements. The membrane’s performance and antifouling properties were also assessed using bovine serum albumin (BSA) as a simulated wastewater feed solution. Furthermore, the ultrafiltration membranes were tested in the forward osmosis (FO) system using a 0.6-weight-percent solution of poly (sodium 4-styrene sulfonate) as the osmosis solution to evaluate the osmosis membrane bioreactor (OsMBR) process. The results revealed that the incorporation of PTi nanoparticles into the polymer matrix enhanced the hydrophilicity and surface energy of the membrane, resulting in better performance. The optimized membrane containing 1% PTi displayed a water flux of 31.5 L/m<sup>2</sup>h, compared to the neat membrane water value of 13.7 L/m<sup>2</sup>h. The membrane also demonstrated excellent antifouling properties, with a flux recovery of 96%. These results highlight the potential of the PTi-infused membrane as a simulated osmosis membrane bioreactor (OsMBR) for wastewater treatment applications.
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spelling doaj.art-c3f91c381b714cbebbb2ed09bd2267282023-11-18T11:33:34ZengMDPI AGMembranes2077-03752023-06-0113657710.3390/membranes13060577Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) ProcessAhmadreza Zahedipoor0Mehdi Faramarzi1Amir Mansourizadeh2Abdolmohammad Ghaedi3Daryoush Emadzadeh4Department of Chemical Engineering, Membrane Science and Technology Research Center (MSTRC), Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranDepartment of Chemical Engineering, Membrane Science and Technology Research Center (MSTRC), Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranDepartment of Chemical Engineering, Membrane Science and Technology Research Center (MSTRC), Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranDepartment of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranDepartment of Chemical Engineering, Membrane Science and Technology Research Center (MSTRC), Gachsaran Branch, Islamic Azad University, Gachsaran P.O. Box 75818-63876, IranThis study explored the use of a combination of hydrothermal and sol–gel methods to produce porous titanium dioxide (PTi) powder with a high specific surface area of 112.84 m<sup>2</sup>/g. The PTi powder was utilized as a filler in the fabrication of ultrafiltration nanocomposite membranes using polysulfone (PSf) as the polymer. The synthesized nanoparticles and membranes were analyzed using various techniques, including BET, TEM, XRD, AFM, FESEM, FTIR, and contact angle measurements. The membrane’s performance and antifouling properties were also assessed using bovine serum albumin (BSA) as a simulated wastewater feed solution. Furthermore, the ultrafiltration membranes were tested in the forward osmosis (FO) system using a 0.6-weight-percent solution of poly (sodium 4-styrene sulfonate) as the osmosis solution to evaluate the osmosis membrane bioreactor (OsMBR) process. The results revealed that the incorporation of PTi nanoparticles into the polymer matrix enhanced the hydrophilicity and surface energy of the membrane, resulting in better performance. The optimized membrane containing 1% PTi displayed a water flux of 31.5 L/m<sup>2</sup>h, compared to the neat membrane water value of 13.7 L/m<sup>2</sup>h. The membrane also demonstrated excellent antifouling properties, with a flux recovery of 96%. These results highlight the potential of the PTi-infused membrane as a simulated osmosis membrane bioreactor (OsMBR) for wastewater treatment applications.https://www.mdpi.com/2077-0375/13/6/577porous titanium dioxideultrafiltrationnanocomposite membraneosmosis membrane bioreactorwastewater treatmentantifouling
spellingShingle Ahmadreza Zahedipoor
Mehdi Faramarzi
Amir Mansourizadeh
Abdolmohammad Ghaedi
Daryoush Emadzadeh
Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process
Membranes
porous titanium dioxide
ultrafiltration
nanocomposite membrane
osmosis membrane bioreactor
wastewater treatment
antifouling
title Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process
title_full Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process
title_fullStr Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process
title_full_unstemmed Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process
title_short Integration of Porous Nanomaterial-Infused Membrane in UF/FO Membrane Hybrid for Simulated Osmosis Membrane Bioreactor (OsMBR) Process
title_sort integration of porous nanomaterial infused membrane in uf fo membrane hybrid for simulated osmosis membrane bioreactor osmbr process
topic porous titanium dioxide
ultrafiltration
nanocomposite membrane
osmosis membrane bioreactor
wastewater treatment
antifouling
url https://www.mdpi.com/2077-0375/13/6/577
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