High-Performance Boron Nitride-Based Membranes for Water Purification

In recent years, nanotechnology-based approaches have resulted in the development of new alternative sustainable technologies for water purification. Two-dimensional (2D) nanomaterials are an emerging class of materials for nanofiltration membranes. In this work, we report the production, characteri...

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Main Authors: Natalia García Doménech, Finn Purcell-Milton, Adrián Sanz Arjona, Maria-Luisa Casasín García, Maeve Ward, Marc Brunet Cabré, Aran Rafferty, Kim McKelvey, Peter Dunne, Yurii K. Gun’ko
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/12/3/473
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author Natalia García Doménech
Finn Purcell-Milton
Adrián Sanz Arjona
Maria-Luisa Casasín García
Maeve Ward
Marc Brunet Cabré
Aran Rafferty
Kim McKelvey
Peter Dunne
Yurii K. Gun’ko
author_facet Natalia García Doménech
Finn Purcell-Milton
Adrián Sanz Arjona
Maria-Luisa Casasín García
Maeve Ward
Marc Brunet Cabré
Aran Rafferty
Kim McKelvey
Peter Dunne
Yurii K. Gun’ko
author_sort Natalia García Doménech
collection DOAJ
description In recent years, nanotechnology-based approaches have resulted in the development of new alternative sustainable technologies for water purification. Two-dimensional (2D) nanomaterials are an emerging class of materials for nanofiltration membranes. In this work, we report the production, characterisation and testing of a promising nanofiltration membrane made from water-exfoliated boron nitride (BN) 2D nanosheets. The membranes have been tested for water purification and removal of typical water-soluble dyes such as methyl orange, methylene blue and Evans blue, with the water-exfoliated BN membranes achieving retention values close to 100%. In addition, we compared the performance of membranes made from water-exfoliated BN with those produced from BN using sonication-assisted liquid exfoliation in selected organic solvents such as 2-propanol and N-methyl-2-pyrrolidone. It was found that membranes from the water-exfoliated BN showed superior performance. We believe this research opens up a unique opportunity for the development of new high-performance environmentally friendly membranes for nanofiltration and new sustainable separation technologies.
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spelling doaj.art-c41218db9a2a48818e054ac3d2ba44b82023-11-23T17:21:23ZengMDPI AGNanomaterials2079-49912022-01-0112347310.3390/nano12030473High-Performance Boron Nitride-Based Membranes for Water PurificationNatalia García Doménech0Finn Purcell-Milton1Adrián Sanz Arjona2Maria-Luisa Casasín García3Maeve Ward4Marc Brunet Cabré5Aran Rafferty6Kim McKelvey7Peter Dunne8Yurii K. Gun’ko9School of Chemistry, Trinity College Dublin, D02 PN40 Dublin, IrelandSchool of Chemistry, Trinity College Dublin, D02 PN40 Dublin, IrelandSchool of Chemistry, Trinity College Dublin, D02 PN40 Dublin, IrelandSchool of Chemistry, Trinity College Dublin, D02 PN40 Dublin, IrelandSchool of Chemistry, Trinity College Dublin, D02 PN40 Dublin, IrelandSchool of Chemistry, Trinity College Dublin, D02 PN40 Dublin, IrelandSchool of Chemistry, Trinity College Dublin, D02 PN40 Dublin, IrelandSchool of Chemical and Physical Sciences, Victoria University of Wellington, Wellington 6012, New ZealandSchool of Chemistry, Trinity College Dublin, D02 PN40 Dublin, IrelandSchool of Chemistry, Trinity College Dublin, D02 PN40 Dublin, IrelandIn recent years, nanotechnology-based approaches have resulted in the development of new alternative sustainable technologies for water purification. Two-dimensional (2D) nanomaterials are an emerging class of materials for nanofiltration membranes. In this work, we report the production, characterisation and testing of a promising nanofiltration membrane made from water-exfoliated boron nitride (BN) 2D nanosheets. The membranes have been tested for water purification and removal of typical water-soluble dyes such as methyl orange, methylene blue and Evans blue, with the water-exfoliated BN membranes achieving retention values close to 100%. In addition, we compared the performance of membranes made from water-exfoliated BN with those produced from BN using sonication-assisted liquid exfoliation in selected organic solvents such as 2-propanol and N-methyl-2-pyrrolidone. It was found that membranes from the water-exfoliated BN showed superior performance. We believe this research opens up a unique opportunity for the development of new high-performance environmentally friendly membranes for nanofiltration and new sustainable separation technologies.https://www.mdpi.com/2079-4991/12/3/473nanofiltrationmembraneswater purificationsustainableseparation technologies2D nanomaterials
spellingShingle Natalia García Doménech
Finn Purcell-Milton
Adrián Sanz Arjona
Maria-Luisa Casasín García
Maeve Ward
Marc Brunet Cabré
Aran Rafferty
Kim McKelvey
Peter Dunne
Yurii K. Gun’ko
High-Performance Boron Nitride-Based Membranes for Water Purification
Nanomaterials
nanofiltration
membranes
water purification
sustainable
separation technologies
2D nanomaterials
title High-Performance Boron Nitride-Based Membranes for Water Purification
title_full High-Performance Boron Nitride-Based Membranes for Water Purification
title_fullStr High-Performance Boron Nitride-Based Membranes for Water Purification
title_full_unstemmed High-Performance Boron Nitride-Based Membranes for Water Purification
title_short High-Performance Boron Nitride-Based Membranes for Water Purification
title_sort high performance boron nitride based membranes for water purification
topic nanofiltration
membranes
water purification
sustainable
separation technologies
2D nanomaterials
url https://www.mdpi.com/2079-4991/12/3/473
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AT marialuisacasasingarcia highperformanceboronnitridebasedmembranesforwaterpurification
AT maeveward highperformanceboronnitridebasedmembranesforwaterpurification
AT marcbrunetcabre highperformanceboronnitridebasedmembranesforwaterpurification
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