Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II)
In the asymmetric unit of the title compound, [Cu(C19H20N2O4)(H2O)], there are two independent mononuclear CuII complexes. The coordination environment of each CuII ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water molecule occupyin...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809042755 |
| Summary: | In the asymmetric unit of the title compound, [Cu(C19H20N2O4)(H2O)], there are two independent mononuclear CuII complexes. The coordination environment of each CuII ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water molecule occupying the apical position. Neighbouring complexes are connected via O—H...O hydrogen bonds between the water molecule and the methoxy group, forming a chain structure along the a axis. The propylene groups of the two independent complexes are disordered over two positions with site occupancies of 0.361 (7):0.639 (7) and 0.224 (8):0.776 (8). The crystal under investigation was a partial inversion twin. |
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| ISSN: | 1600-5368 |