A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine
A novel organic dianion, N,N'-Disulfo-1,4-benzoquinonediimine (1) has been prepared, which is a strong electron acceptor. The reduction potential of the PPh4 salt indicates that 1 is a stronger acceptor than DDQ (2,3-dichloro-5,6-dicyano-1,4-benzoquinone). The dianionic acceptor provided a BEDT...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2012-04-01
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| Series: | Crystals |
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| Online Access: | http://www.mdpi.com/2073-4352/2/2/182/ |
| _version_ | 1798040354216214528 |
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| author | Scott S. Turner Shin’ichi Nakatsuji Jun-ichi Yamada Hiroki Akutsu |
| author_facet | Scott S. Turner Shin’ichi Nakatsuji Jun-ichi Yamada Hiroki Akutsu |
| author_sort | Scott S. Turner |
| collection | DOAJ |
| description | A novel organic dianion, N,N'-Disulfo-1,4-benzoquinonediimine (1) has been prepared, which is a strong electron acceptor. The reduction potential of the PPh4 salt indicates that 1 is a stronger acceptor than DDQ (2,3-dichloro-5,6-dicyano-1,4-benzoquinone). The dianionic acceptor provided a BEDT-TTF salt, (BEDT-TTF)41·3H2O, the structures and physical properties of which are reported. |
| first_indexed | 2024-04-11T22:06:27Z |
| format | Article |
| id | doaj.art-c4259e061575408693e04a2482409b9e |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-11T22:06:27Z |
| publishDate | 2012-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-c4259e061575408693e04a2482409b9e2022-12-22T04:00:43ZengMDPI AGCrystals2073-43522012-04-012218219210.3390/cryst2020182A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimineScott S. TurnerShin’ichi NakatsujiJun-ichi YamadaHiroki AkutsuA novel organic dianion, N,N'-Disulfo-1,4-benzoquinonediimine (1) has been prepared, which is a strong electron acceptor. The reduction potential of the PPh4 salt indicates that 1 is a stronger acceptor than DDQ (2,3-dichloro-5,6-dicyano-1,4-benzoquinone). The dianionic acceptor provided a BEDT-TTF salt, (BEDT-TTF)41·3H2O, the structures and physical properties of which are reported.http://www.mdpi.com/2073-4352/2/2/182/organic conductorBEDT-TTFhole doping effectanionic acceptortransport propertiesmagnetic properties |
| spellingShingle | Scott S. Turner Shin’ichi Nakatsuji Jun-ichi Yamada Hiroki Akutsu A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine Crystals organic conductor BEDT-TTF hole doping effect anionic acceptor transport properties magnetic properties |
| title | A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine |
| title_full | A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine |
| title_fullStr | A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine |
| title_full_unstemmed | A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine |
| title_short | A New BEDT-TTF-Based Organic Charge Transfer Salt with a New Anionic Strong Acceptor, N,N'-Disulfo-1,4-benzoquinonediimine |
| title_sort | new bedt ttf based organic charge transfer salt with a new anionic strong acceptor n n disulfo 1 4 benzoquinonediimine |
| topic | organic conductor BEDT-TTF hole doping effect anionic acceptor transport properties magnetic properties |
| url | http://www.mdpi.com/2073-4352/2/2/182/ |
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