Investigation of Novel Flax Fiber/Epoxy Composites with Increased Biobased Content

Currently, biobased epoxy resins derived from plant oils and natural fibers are available on the market and are a promising substitute for fossil-based products. The purpose of this work is to investigate novel lightweight thermoset fiber-reinforced composites with extremely high biobased content. P...

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Main Authors: Bianca Dal Pont, Vito Gigante, Luca Panariello, Ilaria Canesi, Laura Aliotta, Andrea Lazzeri
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/19/4030
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author Bianca Dal Pont
Vito Gigante
Luca Panariello
Ilaria Canesi
Laura Aliotta
Andrea Lazzeri
author_facet Bianca Dal Pont
Vito Gigante
Luca Panariello
Ilaria Canesi
Laura Aliotta
Andrea Lazzeri
author_sort Bianca Dal Pont
collection DOAJ
description Currently, biobased epoxy resins derived from plant oils and natural fibers are available on the market and are a promising substitute for fossil-based products. The purpose of this work is to investigate novel lightweight thermoset fiber-reinforced composites with extremely high biobased content. Paying attention to the biobased content, following a cascade pathway, many trials were carried out with different types of resins and hardeners to select the best ones. The most promising formulations were then used to produce flax fiber reinforced composites by vacuum bagging process. The main biocomposite properties such as tensile, bending, and impact properties as well as the individuation of their glass transition temperatures (by DSC) were assessed. Three biocomposite systems were investigated with biobased content ranging from 60 to 91%, obtaining an elastic modulus that varied from 2.7 to 6.3 GPa, a flexural strength from 23 to 108.5 MPa, and Charpy impact strength from 11.9 to 12.2 kJ/m<sup>2</sup>. The properties reached by the new biocomposites are very encouraging; in fact, their stiffness vs. lightweight (calculated by the <i>E/ρ</i><sup>3</sup> ratio) is comparable to some typical epoxy–glass composites.
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spelling doaj.art-c438adb0c947403c9ecac7a46e6cfe372023-11-19T14:57:54ZengMDPI AGPolymers2073-43602023-10-011519403010.3390/polym15194030Investigation of Novel Flax Fiber/Epoxy Composites with Increased Biobased ContentBianca Dal Pont0Vito Gigante1Luca Panariello2Ilaria Canesi3Laura Aliotta4Andrea Lazzeri5Department of Civil and Industrial Engineering, University of Pisa, Via Diotisalvi, 2, 56122 Pisa, ItalyDepartment of Civil and Industrial Engineering, University of Pisa, Via Diotisalvi, 2, 56122 Pisa, ItalyDepartment of Civil and Industrial Engineering, University of Pisa, Via Diotisalvi, 2, 56122 Pisa, ItalyPlanet Bioplastics, Via San Giovanni Bosco 23, 56127 Pisa, ItalyDepartment of Civil and Industrial Engineering, University of Pisa, Via Diotisalvi, 2, 56122 Pisa, ItalyDepartment of Civil and Industrial Engineering, University of Pisa, Via Diotisalvi, 2, 56122 Pisa, ItalyCurrently, biobased epoxy resins derived from plant oils and natural fibers are available on the market and are a promising substitute for fossil-based products. The purpose of this work is to investigate novel lightweight thermoset fiber-reinforced composites with extremely high biobased content. Paying attention to the biobased content, following a cascade pathway, many trials were carried out with different types of resins and hardeners to select the best ones. The most promising formulations were then used to produce flax fiber reinforced composites by vacuum bagging process. The main biocomposite properties such as tensile, bending, and impact properties as well as the individuation of their glass transition temperatures (by DSC) were assessed. Three biocomposite systems were investigated with biobased content ranging from 60 to 91%, obtaining an elastic modulus that varied from 2.7 to 6.3 GPa, a flexural strength from 23 to 108.5 MPa, and Charpy impact strength from 11.9 to 12.2 kJ/m<sup>2</sup>. The properties reached by the new biocomposites are very encouraging; in fact, their stiffness vs. lightweight (calculated by the <i>E/ρ</i><sup>3</sup> ratio) is comparable to some typical epoxy–glass composites.https://www.mdpi.com/2073-4360/15/19/4030fibersmechanical propertiesthermosets
spellingShingle Bianca Dal Pont
Vito Gigante
Luca Panariello
Ilaria Canesi
Laura Aliotta
Andrea Lazzeri
Investigation of Novel Flax Fiber/Epoxy Composites with Increased Biobased Content
Polymers
fibers
mechanical properties
thermosets
title Investigation of Novel Flax Fiber/Epoxy Composites with Increased Biobased Content
title_full Investigation of Novel Flax Fiber/Epoxy Composites with Increased Biobased Content
title_fullStr Investigation of Novel Flax Fiber/Epoxy Composites with Increased Biobased Content
title_full_unstemmed Investigation of Novel Flax Fiber/Epoxy Composites with Increased Biobased Content
title_short Investigation of Novel Flax Fiber/Epoxy Composites with Increased Biobased Content
title_sort investigation of novel flax fiber epoxy composites with increased biobased content
topic fibers
mechanical properties
thermosets
url https://www.mdpi.com/2073-4360/15/19/4030
work_keys_str_mv AT biancadalpont investigationofnovelflaxfiberepoxycompositeswithincreasedbiobasedcontent
AT vitogigante investigationofnovelflaxfiberepoxycompositeswithincreasedbiobasedcontent
AT lucapanariello investigationofnovelflaxfiberepoxycompositeswithincreasedbiobasedcontent
AT ilariacanesi investigationofnovelflaxfiberepoxycompositeswithincreasedbiobasedcontent
AT lauraaliotta investigationofnovelflaxfiberepoxycompositeswithincreasedbiobasedcontent
AT andrealazzeri investigationofnovelflaxfiberepoxycompositeswithincreasedbiobasedcontent