Structure of X-ray photoelectron spectra of low-energy and core electrons of Ln(C6H4OCH3COO-)3
This paper deals with the results of an X-ray photo electron spectroscopy of lanthanide ortho-metoxybenzoates Ln(C6H4OCH3COO-)3, where Ln represents lanthanides La through Lu except for Pm and C6H4OCH3COO- - residuum of ortho-metoxybenzoic acid. The core and outer electron X-ray photo electron spect...
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| Format: | Article |
| Language: | English |
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VINCA Institute of Nuclear Sciences
2005-01-01
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| Series: | Nuclear Technology and Radiation Protection |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/1451-3994/2005/1451-39940502017T.pdf |
| _version_ | 1828294450556698624 |
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| author | Teterin Yury A. Vukčević Labud Teterin Anton YU. |
| author_facet | Teterin Yury A. Vukčević Labud Teterin Anton YU. |
| author_sort | Teterin Yury A. |
| collection | DOAJ |
| description | This paper deals with the results of an X-ray photo electron spectroscopy of lanthanide ortho-metoxybenzoates Ln(C6H4OCH3COO-)3, where Ln represents lanthanides La through Lu except for Pm and C6H4OCH3COO- - residuum of ortho-metoxybenzoic acid. The core and outer electron X-ray photo electron spectroscopy spectra in the binding energy range of 0-1250 eV were shown to exhibit a complex, fine structure. The said structure was established due to the outer (0-15 eV binding energy) and inner (15-50 eV binding energy) valence molecular orbital from the filled Ln5p and O2s atomic shells multiple splitting, many-body perturbation, dynamic effect, etc. The mechanisms of such a fine structure formation were shown to manifest different probabilities in the spectrum of a certain electronic shell. There fore, the fine X-ray photo electron spectroscopy spectral structure resulting from a certain mechanism can be interpreted and its quantitative parameters related to the physical and chemical properties of the studied com pounds (degree of delocalization and participation of Ln4f electrons in the chemical bond, electronic configuration and oxidation states, density of uncoupled electrons on paramagnetic ions, degree of participation of the low binding energy filled electronic shells of lanthanide and ligands information of the outer and in nervalence molecular orbitals, lanthanide close environment structure in amorphous materials, etc). |
| first_indexed | 2024-04-13T11:37:53Z |
| format | Article |
| id | doaj.art-c43a68a5aefa48eba5a17c90a02c80b2 |
| institution | Directory Open Access Journal |
| issn | 1451-3994 |
| language | English |
| last_indexed | 2024-04-13T11:37:53Z |
| publishDate | 2005-01-01 |
| publisher | VINCA Institute of Nuclear Sciences |
| record_format | Article |
| series | Nuclear Technology and Radiation Protection |
| spelling | doaj.art-c43a68a5aefa48eba5a17c90a02c80b22022-12-22T02:48:23ZengVINCA Institute of Nuclear SciencesNuclear Technology and Radiation Protection1451-39942005-01-01202172210.2298/NTRP0502017TStructure of X-ray photoelectron spectra of low-energy and core electrons of Ln(C6H4OCH3COO-)3Teterin Yury A.Vukčević LabudTeterin Anton YU.This paper deals with the results of an X-ray photo electron spectroscopy of lanthanide ortho-metoxybenzoates Ln(C6H4OCH3COO-)3, where Ln represents lanthanides La through Lu except for Pm and C6H4OCH3COO- - residuum of ortho-metoxybenzoic acid. The core and outer electron X-ray photo electron spectroscopy spectra in the binding energy range of 0-1250 eV were shown to exhibit a complex, fine structure. The said structure was established due to the outer (0-15 eV binding energy) and inner (15-50 eV binding energy) valence molecular orbital from the filled Ln5p and O2s atomic shells multiple splitting, many-body perturbation, dynamic effect, etc. The mechanisms of such a fine structure formation were shown to manifest different probabilities in the spectrum of a certain electronic shell. There fore, the fine X-ray photo electron spectroscopy spectral structure resulting from a certain mechanism can be interpreted and its quantitative parameters related to the physical and chemical properties of the studied com pounds (degree of delocalization and participation of Ln4f electrons in the chemical bond, electronic configuration and oxidation states, density of uncoupled electrons on paramagnetic ions, degree of participation of the low binding energy filled electronic shells of lanthanide and ligands information of the outer and in nervalence molecular orbitals, lanthanide close environment structure in amorphous materials, etc).http://www.doiserbia.nb.rs/img/doi/1451-3994/2005/1451-39940502017T.pdfX-ray photoelectron spectroscopyouter and inner valence molecular orbitallanthanide |
| spellingShingle | Teterin Yury A. Vukčević Labud Teterin Anton YU. Structure of X-ray photoelectron spectra of low-energy and core electrons of Ln(C6H4OCH3COO-)3 Nuclear Technology and Radiation Protection X-ray photoelectron spectroscopy outer and inner valence molecular orbital lanthanide |
| title | Structure of X-ray photoelectron spectra of low-energy and core electrons of Ln(C6H4OCH3COO-)3 |
| title_full | Structure of X-ray photoelectron spectra of low-energy and core electrons of Ln(C6H4OCH3COO-)3 |
| title_fullStr | Structure of X-ray photoelectron spectra of low-energy and core electrons of Ln(C6H4OCH3COO-)3 |
| title_full_unstemmed | Structure of X-ray photoelectron spectra of low-energy and core electrons of Ln(C6H4OCH3COO-)3 |
| title_short | Structure of X-ray photoelectron spectra of low-energy and core electrons of Ln(C6H4OCH3COO-)3 |
| title_sort | structure of x ray photoelectron spectra of low energy and core electrons of ln c6h4och3coo 3 |
| topic | X-ray photoelectron spectroscopy outer and inner valence molecular orbital lanthanide |
| url | http://www.doiserbia.nb.rs/img/doi/1451-3994/2005/1451-39940502017T.pdf |
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