Electrochemical synthesis of poly(2-methyl aniline): electrochemical and spectroscopic characterization
Poly(2-methyl aniline) or poly(ortho-toluidine), as ring substituted derivative of aniline, has been synthesized electrochemically in various concentrations of H2SO4 and HCl, and then characterized by cyclic voltammetry, as well as by impedance and Raman spectroscopy. The cyclic voltammo...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2001-01-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390101027B.pdf |
| _version_ | 1818865857422426112 |
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| author | Buzarovska Aleksandra Arsova Irena Arsov Ljubomir |
| author_facet | Buzarovska Aleksandra Arsova Irena Arsov Ljubomir |
| author_sort | Buzarovska Aleksandra |
| collection | DOAJ |
| description | Poly(2-methyl aniline) or poly(ortho-toluidine), as ring substituted
derivative of aniline, has been synthesized electrochemically in various
concentrations of H2SO4 and HCl, and then characterized by cyclic
voltammetry, as well as by impedance and Raman spectroscopy. The cyclic
voltammograms of poly(o-toluidine) and poly(aniline) show that the
electrochemical polymerization of these two polymers proceeds by almost
identical mechanisms. The Raman spectroscopical measurements suggest that
the redox reactions of poly(aniline) and poly(o-toluidine) are similar in
the potential range between -0.2 and 0.7V vs. SCE. The impedance
measurements showed that the conductivity of poly(o-toluidine) is an order
of magnitude lower than that of the corresponding poly(aniline) form. |
| first_indexed | 2024-12-19T10:54:13Z |
| format | Article |
| id | doaj.art-c44f7b8cd7ea4ba5938f329915bff874 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-19T10:54:13Z |
| publishDate | 2001-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-c44f7b8cd7ea4ba5938f329915bff8742022-12-21T20:24:52ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212001-01-01661273710.2298/JSC0101027B0352-51390101027BElectrochemical synthesis of poly(2-methyl aniline): electrochemical and spectroscopic characterizationBuzarovska Aleksandra0Arsova Irena1Arsov Ljubomir2University “St. Cyril and Methodius”, Faculty of Technology and Metallurgy, Skopje, MacedoniaUniversity “St. Cyril and Methodius”, Faculty of Technology and Metallurgy, Skopje, MacedoniaUniversity “St. Cyril and Methodius”, Faculty of Technology and Metallurgy, Skopje, MacedoniaPoly(2-methyl aniline) or poly(ortho-toluidine), as ring substituted derivative of aniline, has been synthesized electrochemically in various concentrations of H2SO4 and HCl, and then characterized by cyclic voltammetry, as well as by impedance and Raman spectroscopy. The cyclic voltammograms of poly(o-toluidine) and poly(aniline) show that the electrochemical polymerization of these two polymers proceeds by almost identical mechanisms. The Raman spectroscopical measurements suggest that the redox reactions of poly(aniline) and poly(o-toluidine) are similar in the potential range between -0.2 and 0.7V vs. SCE. The impedance measurements showed that the conductivity of poly(o-toluidine) is an order of magnitude lower than that of the corresponding poly(aniline) form.http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390101027B.pdfpoly(2-methyl aniline)electropolymerizationcyclic voltammetryraman spectroscopy |
| spellingShingle | Buzarovska Aleksandra Arsova Irena Arsov Ljubomir Electrochemical synthesis of poly(2-methyl aniline): electrochemical and spectroscopic characterization Journal of the Serbian Chemical Society poly(2-methyl aniline) electropolymerization cyclic voltammetry raman spectroscopy |
| title | Electrochemical synthesis of poly(2-methyl aniline): electrochemical and spectroscopic characterization |
| title_full | Electrochemical synthesis of poly(2-methyl aniline): electrochemical and spectroscopic characterization |
| title_fullStr | Electrochemical synthesis of poly(2-methyl aniline): electrochemical and spectroscopic characterization |
| title_full_unstemmed | Electrochemical synthesis of poly(2-methyl aniline): electrochemical and spectroscopic characterization |
| title_short | Electrochemical synthesis of poly(2-methyl aniline): electrochemical and spectroscopic characterization |
| title_sort | electrochemical synthesis of poly 2 methyl aniline electrochemical and spectroscopic characterization |
| topic | poly(2-methyl aniline) electropolymerization cyclic voltammetry raman spectroscopy |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390101027B.pdf |
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