{(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvate
In the title complex, [Cu(C27H40BN6S3)(C18H15P)]·2CHCl3, the CuI atom is surrounded in a trigonal-planar arrangement by the triphenylphosphane ligand and two of the three S atoms of the scorpionate ligand with an additional 3-center–2-electron B—H...Cu interaction, with the H atom as the apex of a p...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-12-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314617017722 |
| _version_ | 1819056406720937984 |
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| author | Stefan Holler Ferdinand Belaj Nadia C. Mösch-Zanetti |
| author_facet | Stefan Holler Ferdinand Belaj Nadia C. Mösch-Zanetti |
| author_sort | Stefan Holler |
| collection | DOAJ |
| description | In the title complex, [Cu(C27H40BN6S3)(C18H15P)]·2CHCl3, the CuI atom is surrounded in a trigonal-planar arrangement by the triphenylphosphane ligand and two of the three S atoms of the scorpionate ligand with an additional 3-center–2-electron B—H...Cu interaction, with the H atom as the apex of a pyramid [B—H = 1.140 (17) Å and Cu—H = 1.826 (16) Å]. |
| first_indexed | 2024-12-21T13:22:55Z |
| format | Article |
| id | doaj.art-c4508f172bfc41fbb93a002088be7dbd |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-21T13:22:55Z |
| publishDate | 2017-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-c4508f172bfc41fbb93a002088be7dbd2022-12-21T19:02:32ZengInternational Union of CrystallographyIUCrData2414-31462017-12-01212x17177210.1107/S2414314617017722wm4062{(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvateStefan Holler0Ferdinand Belaj1Nadia C. Mösch-Zanetti2Institute of Chemistry, University of Graz, Schubertstr. 1, 8010 Graz, AustriaInstitute of Chemistry, University of Graz, Schubertstr. 1, 8010 Graz, AustriaInstitute of Chemistry, University of Graz, Schubertstr. 1, 8010 Graz, AustriaIn the title complex, [Cu(C27H40BN6S3)(C18H15P)]·2CHCl3, the CuI atom is surrounded in a trigonal-planar arrangement by the triphenylphosphane ligand and two of the three S atoms of the scorpionate ligand with an additional 3-center–2-electron B—H...Cu interaction, with the H atom as the apex of a pyramid [B—H = 1.140 (17) Å and Cu—H = 1.826 (16) Å].http://scripts.iucr.org/cgi-bin/paper?S2414314617017722crystal structurescorpionate ligandcopper complex |
| spellingShingle | Stefan Holler Ferdinand Belaj Nadia C. Mösch-Zanetti {(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvate IUCrData crystal structure scorpionate ligand copper complex |
| title | {(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvate |
| title_full | {(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvate |
| title_fullStr | {(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvate |
| title_full_unstemmed | {(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvate |
| title_short | {(Hydrogen 2,2′,2′′-boranetriyl)tris[6-tert-butyl-4-methylpyridazine-3(2H)-thione]-κ3H,S,S′}(triphenylphosphane-κP)copper(I) chloroform disolvate |
| title_sort | hydrogen 2 2 2 boranetriyl tris 6 tert butyl 4 methylpyridazine 3 2h thione κ3h s s triphenylphosphane κp copper i chloroform disolvate |
| topic | crystal structure scorpionate ligand copper complex |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314617017722 |
| work_keys_str_mv | AT stefanholler hydrogen222boranetriyltris6tertbutyl4methylpyridazine32hthionek3hsstriphenylphosphanekpcopperichloroformdisolvate AT ferdinandbelaj hydrogen222boranetriyltris6tertbutyl4methylpyridazine32hthionek3hsstriphenylphosphanekpcopperichloroformdisolvate AT nadiacmoschzanetti hydrogen222boranetriyltris6tertbutyl4methylpyridazine32hthionek3hsstriphenylphosphanekpcopperichloroformdisolvate |