1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone
The title compound C8H8N2Se, is the product of the reaction of 2-chloro-1-methylbenzimidazole with sodium hydroselenide. The molecule is almost planar (r.m.s. deviation = 0.041 Å) owing to the presence of the long chain of conjugated bonds (Se=C—NMe&#...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812013700 |
| _version_ | 1819289292297469952 |
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| author | Alexander V. Borisov Victor N. Khrustalev Vladimir K. Osmanov Gunay Z. Mammadova Zhanna V. Matsulevich |
| author_facet | Alexander V. Borisov Victor N. Khrustalev Vladimir K. Osmanov Gunay Z. Mammadova Zhanna V. Matsulevich |
| author_sort | Alexander V. Borisov |
| collection | DOAJ |
| description | The title compound C8H8N2Se, is the product of the reaction of 2-chloro-1-methylbenzimidazole with sodium hydroselenide. The molecule is almost planar (r.m.s. deviation = 0.041 Å) owing to the presence of the long chain of conjugated bonds (Se=C—NMe—C=C—C=C—C=C—NH). The C=Se bond length [1.838 (2) Å] corresponds well to those found in the close analogs and indicates its pronounced double-bond character. In the crystal, molecules form helicoidal chains along the b axis by means of N—H...Se hydrogen bonds. |
| first_indexed | 2024-12-24T03:04:32Z |
| format | Article |
| id | doaj.art-c45ef6dec0684cd8ab83d3d4aa3c1976 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:04:32Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c45ef6dec0684cd8ab83d3d4aa3c19762022-12-21T17:18:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685o1381o138110.1107/S16005368120137001-Methyl-2,3-dihydro-1H-benzimidazole-2-seloneAlexander V. BorisovVictor N. KhrustalevVladimir K. OsmanovGunay Z. MammadovaZhanna V. MatsulevichThe title compound C8H8N2Se, is the product of the reaction of 2-chloro-1-methylbenzimidazole with sodium hydroselenide. The molecule is almost planar (r.m.s. deviation = 0.041 Å) owing to the presence of the long chain of conjugated bonds (Se=C—NMe—C=C—C=C—C=C—NH). The C=Se bond length [1.838 (2) Å] corresponds well to those found in the close analogs and indicates its pronounced double-bond character. In the crystal, molecules form helicoidal chains along the b axis by means of N—H...Se hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812013700 |
| spellingShingle | Alexander V. Borisov Victor N. Khrustalev Vladimir K. Osmanov Gunay Z. Mammadova Zhanna V. Matsulevich 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone Acta Crystallographica Section E |
| title | 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone |
| title_full | 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone |
| title_fullStr | 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone |
| title_full_unstemmed | 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone |
| title_short | 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone |
| title_sort | 1 methyl 2 3 dihydro 1h benzimidazole 2 selone |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812013700 |
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