Synthesis of gold nanoparticles using plum waste extract with green solvents
The current study focuses on the synthesis of gold nanoparticles (AuNPs) using the plum peel extract obtained by deep eutectic solvent (DES) (Betaine-Urea and Choline chloride-Urea). Formation mechanism of DESs and molecular interactions between components has been studied using quantum chemical met...
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Elsevier
2024-06-01
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Series: | Sustainable Chemistry for the Environment |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2949839224000294 |
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author | Victoria Vorobyova Margarita Skiba Kateryna Vinnichuk Georgii Vasyliev |
author_facet | Victoria Vorobyova Margarita Skiba Kateryna Vinnichuk Georgii Vasyliev |
author_sort | Victoria Vorobyova |
collection | DOAJ |
description | The current study focuses on the synthesis of gold nanoparticles (AuNPs) using the plum peel extract obtained by deep eutectic solvent (DES) (Betaine-Urea and Choline chloride-Urea). Formation mechanism of DESs and molecular interactions between components has been studied using quantum chemical methods. DESs have been used for obtaining extracts from plum peel. It has been established that the reducing ability of extracts obtained using DESs is higher (489–580 mg ASE/g extract) than when using a traditional aqueous-alcohol solution (336 mg ASE/g extract). Gold nanoparticles were characterized by UV–vis spectroscopy, FTIR, and SEM-XRD analysis. The size of AuNPs was found to be 5–10 nm as per the particle size analyzer, and the zeta potential is − 46 to 47 mV. The scavenging ability of the sample solution to ABTS radical was determined by ABTS radical scavenging test. The AuNPs synthesized by extracting Cl-U exhibited significant antioxidant potential against ABTS•+, with an IC50 of 110 mg/mL. For the first time in a cosmetic product, AgNPs synthesized by plum peel extract in a deep eutectic solvent was used. The creams were evaluated for their organoleptic characteristics, physicochemical properties, and in vitro antibacterial activity against Escherichia coli and Bacillus subtilis. Results show that the cream with 0.5% AuNp increases the value of moisturizer for the skin. |
first_indexed | 2024-04-24T11:20:32Z |
format | Article |
id | doaj.art-c46b2aec023d4708b5db661b7a5994db |
institution | Directory Open Access Journal |
issn | 2949-8392 |
language | English |
last_indexed | 2024-04-24T11:20:32Z |
publishDate | 2024-06-01 |
publisher | Elsevier |
record_format | Article |
series | Sustainable Chemistry for the Environment |
spelling | doaj.art-c46b2aec023d4708b5db661b7a5994db2024-04-11T04:42:16ZengElsevierSustainable Chemistry for the Environment2949-83922024-06-016100086Synthesis of gold nanoparticles using plum waste extract with green solventsVictoria Vorobyova0Margarita Skiba1Kateryna Vinnichuk2Georgii Vasyliev3Chemical Technology Department, National Technical University of Ukraine ''Igor Sikorsky Kyiv Polytechnic Institute'', Kyiv 03056, Ukraine; Corresponding author.Department of Inorganic Materials Technology and Ecology, Ukrainian State University of Chemical Technology, Dnipro 49005, UkraineChemical Technology Department, National Technical University of Ukraine ''Igor Sikorsky Kyiv Polytechnic Institute'', Kyiv 03056, UkraineChemical Technology Department, National Technical University of Ukraine ''Igor Sikorsky Kyiv Polytechnic Institute'', Kyiv 03056, UkraineThe current study focuses on the synthesis of gold nanoparticles (AuNPs) using the plum peel extract obtained by deep eutectic solvent (DES) (Betaine-Urea and Choline chloride-Urea). Formation mechanism of DESs and molecular interactions between components has been studied using quantum chemical methods. DESs have been used for obtaining extracts from plum peel. It has been established that the reducing ability of extracts obtained using DESs is higher (489–580 mg ASE/g extract) than when using a traditional aqueous-alcohol solution (336 mg ASE/g extract). Gold nanoparticles were characterized by UV–vis spectroscopy, FTIR, and SEM-XRD analysis. The size of AuNPs was found to be 5–10 nm as per the particle size analyzer, and the zeta potential is − 46 to 47 mV. The scavenging ability of the sample solution to ABTS radical was determined by ABTS radical scavenging test. The AuNPs synthesized by extracting Cl-U exhibited significant antioxidant potential against ABTS•+, with an IC50 of 110 mg/mL. For the first time in a cosmetic product, AgNPs synthesized by plum peel extract in a deep eutectic solvent was used. The creams were evaluated for their organoleptic characteristics, physicochemical properties, and in vitro antibacterial activity against Escherichia coli and Bacillus subtilis. Results show that the cream with 0.5% AuNp increases the value of moisturizer for the skin.http://www.sciencedirect.com/science/article/pii/S2949839224000294Gold nanoparticlesGreen synthesisMoisturizing creamsDry skinAgro-industrial by-products |
spellingShingle | Victoria Vorobyova Margarita Skiba Kateryna Vinnichuk Georgii Vasyliev Synthesis of gold nanoparticles using plum waste extract with green solvents Sustainable Chemistry for the Environment Gold nanoparticles Green synthesis Moisturizing creams Dry skin Agro-industrial by-products |
title | Synthesis of gold nanoparticles using plum waste extract with green solvents |
title_full | Synthesis of gold nanoparticles using plum waste extract with green solvents |
title_fullStr | Synthesis of gold nanoparticles using plum waste extract with green solvents |
title_full_unstemmed | Synthesis of gold nanoparticles using plum waste extract with green solvents |
title_short | Synthesis of gold nanoparticles using plum waste extract with green solvents |
title_sort | synthesis of gold nanoparticles using plum waste extract with green solvents |
topic | Gold nanoparticles Green synthesis Moisturizing creams Dry skin Agro-industrial by-products |
url | http://www.sciencedirect.com/science/article/pii/S2949839224000294 |
work_keys_str_mv | AT victoriavorobyova synthesisofgoldnanoparticlesusingplumwasteextractwithgreensolvents AT margaritaskiba synthesisofgoldnanoparticlesusingplumwasteextractwithgreensolvents AT katerynavinnichuk synthesisofgoldnanoparticlesusingplumwasteextractwithgreensolvents AT georgiivasyliev synthesisofgoldnanoparticlesusingplumwasteextractwithgreensolvents |