Isothermal section of the Ni-Mn-Sb ternary system at 773K
The isothermal section of the Ni-Mn-Sb ternary system at 773 K was measured by means of 117 alloys which were analyzed by using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), and electron probe microanalysis (EPMA) techniques. The existence of 7 bi...
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| Format: | Article |
| Language: | English |
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Technical Faculty, Bor
2019-01-01
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| Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2019/1450-53391900019A.pdf |
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| author | Ao W.-Q. Yu H.-Z. Liu F.-L. Liu F.-S. Li J.-Q. Du Y. Liu S.-H. Shi C.-Y. |
| author_facet | Ao W.-Q. Yu H.-Z. Liu F.-L. Liu F.-S. Li J.-Q. Du Y. Liu S.-H. Shi C.-Y. |
| author_sort | Ao W.-Q. |
| collection | DOAJ |
| description | The isothermal section of the Ni-Mn-Sb ternary system at 773 K was measured by means of 117 alloys which were analyzed by using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), and electron probe microanalysis (EPMA) techniques. The existence of 7 binary compounds, namely NiMn, Mn2Sb, MnSb, NiSb2, NiSb, Ni5Sb2, Ni3Sb and 2 ternary compounds, namely Ni2MnSb and NiMnSb were confirmed for this isothermal section. The four binary compounds Ni3Sb (Cu3Ti structure, Pmmn space group), Ni5Sb2 (Ni5Sb2-type structure, C2 space group), NiSb2 (FeS2-type structure, Pnnm space group) and Mn2Sb (Cu2Sb-type structure, P4/nmm space group) in the binary systems Ni-Sb and Mn-Sb were stoichiometric compounds, the homogeneity ranges of which were negligible. However the five single phases in the Ni-Mn system and the two binary compounds MnSb and NiSb showed more or less homogeneity ranges formed by substitution of Mn and Sb for Ni atom. The Heusler compound μ (Ni2MnSb) has L21-type ordered structure with space group Fm-3m, a = 0.6017 nm. And the crystal structure for the Half-Heusler compound κ (NiMnSb) is C1b-type (F-43m) with a = 0.5961 nm. The approximate homogeneity ranges of the two ternary compounds μ and κ at 773 K were investigated. |
| first_indexed | 2024-12-12T09:21:42Z |
| format | Article |
| id | doaj.art-c47abeaa493d48ea8278bad9c9764732 |
| institution | Directory Open Access Journal |
| issn | 1450-5339 2217-7175 |
| language | English |
| last_indexed | 2024-12-12T09:21:42Z |
| publishDate | 2019-01-01 |
| publisher | Technical Faculty, Bor |
| record_format | Article |
| series | Journal of Mining and Metallurgy. Section B: Metallurgy |
| spelling | doaj.art-c47abeaa493d48ea8278bad9c97647322022-12-22T00:29:12ZengTechnical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752019-01-0155214715610.2298/JMMB181104019A1450-53391900019AIsothermal section of the Ni-Mn-Sb ternary system at 773KAo W.-Q.0Yu H.-Z.1Liu F.-L.2Liu F.-S.3Li J.-Q.4Du Y.5Liu S.-H.6Shi C.-Y.7State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China + College of Materials Science and Engineering, Shenzhen University, Guangdong Research Center for Interfacial Engineering of Functional Materials and Shenzhen Key LaboraCollege of Materials Science and Engineering, Shenzhen University, Guangdong Research Center for Interfacial Engineering of Functional Materials and Shenzhen Key Laboratory of Special Functional Materials, Shenzhen,ChinaCollege of Materials Science and Engineering, Shenzhen University, Guangdong Research Center for Interfacial Engineering of Functional Materials and Shenzhen Key Laboratory of Special Functional Materials, Shenzhen,ChinaCollege of Materials Science and Engineering, Shenzhen University, Guangdong Research Center for Interfacial Engineering of Functional Materials and Shenzhen Key Laboratory of Special Functional Materials, Shenzhen,ChinaCollege of Materials Science and Engineering, Shenzhen University, Guangdong Research Center for Interfacial Engineering of Functional Materials and Shenzhen Key Laboratory of Special Functional Materials, Shenzhen,ChinaState Key Laboratory of Powder Metallurgy, Central South University, Changsha, ChinaState Key Laboratory of Powder Metallurgy, Central South University, Changsha, ChinaState Key Laboratory of Powder Metallurgy, Central South University, Changsha, ChinaThe isothermal section of the Ni-Mn-Sb ternary system at 773 K was measured by means of 117 alloys which were analyzed by using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), and electron probe microanalysis (EPMA) techniques. The existence of 7 binary compounds, namely NiMn, Mn2Sb, MnSb, NiSb2, NiSb, Ni5Sb2, Ni3Sb and 2 ternary compounds, namely Ni2MnSb and NiMnSb were confirmed for this isothermal section. The four binary compounds Ni3Sb (Cu3Ti structure, Pmmn space group), Ni5Sb2 (Ni5Sb2-type structure, C2 space group), NiSb2 (FeS2-type structure, Pnnm space group) and Mn2Sb (Cu2Sb-type structure, P4/nmm space group) in the binary systems Ni-Sb and Mn-Sb were stoichiometric compounds, the homogeneity ranges of which were negligible. However the five single phases in the Ni-Mn system and the two binary compounds MnSb and NiSb showed more or less homogeneity ranges formed by substitution of Mn and Sb for Ni atom. The Heusler compound μ (Ni2MnSb) has L21-type ordered structure with space group Fm-3m, a = 0.6017 nm. And the crystal structure for the Half-Heusler compound κ (NiMnSb) is C1b-type (F-43m) with a = 0.5961 nm. The approximate homogeneity ranges of the two ternary compounds μ and κ at 773 K were investigated.http://www.doiserbia.nb.rs/img/doi/1450-5339/2019/1450-53391900019A.pdfni-mn-sbternary systemphase diagrammetals and alloys |
| spellingShingle | Ao W.-Q. Yu H.-Z. Liu F.-L. Liu F.-S. Li J.-Q. Du Y. Liu S.-H. Shi C.-Y. Isothermal section of the Ni-Mn-Sb ternary system at 773K Journal of Mining and Metallurgy. Section B: Metallurgy ni-mn-sb ternary system phase diagram metals and alloys |
| title | Isothermal section of the Ni-Mn-Sb ternary system at 773K |
| title_full | Isothermal section of the Ni-Mn-Sb ternary system at 773K |
| title_fullStr | Isothermal section of the Ni-Mn-Sb ternary system at 773K |
| title_full_unstemmed | Isothermal section of the Ni-Mn-Sb ternary system at 773K |
| title_short | Isothermal section of the Ni-Mn-Sb ternary system at 773K |
| title_sort | isothermal section of the ni mn sb ternary system at 773k |
| topic | ni-mn-sb ternary system phase diagram metals and alloys |
| url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2019/1450-53391900019A.pdf |
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