Diaqua(nitrato-κ2O,O′)[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]cadmium(II) nitrate
In the title complex, [Cd(C14H9N5)(NO3)(H2O)2]NO3, the CdII ion is coordinated in a distorted pentagonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate ligand. Two aqua li...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-11-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810039735 |
| _version_ | 1818283731264208896 |
|---|---|
| author | Shi Guo Zhang Hui Ming Zhang |
| author_facet | Shi Guo Zhang Hui Ming Zhang |
| author_sort | Shi Guo Zhang |
| collection | DOAJ |
| description | In the title complex, [Cd(C14H9N5)(NO3)(H2O)2]NO3, the CdII ion is coordinated in a distorted pentagonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate ligand. Two aqua ligands are coordinated at the axial sites. All non-H atoms in the equatorial plane are co-planar within 0.0673 Å. In the crystal, intermolecular O—H...O and O—H...N hydrogen bonds connect the components into a two-dimensional network parallel to (001). In addition, there is a π–π stacking interaction between symmetry-related benzene rings, with a centroid–centroid distance of 3.598 (3) Å. |
| first_indexed | 2024-12-13T00:41:34Z |
| format | Article |
| id | doaj.art-c4a78921302b4e7ea23f153197210816 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:41:34Z |
| publishDate | 2010-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c4a78921302b4e7ea23f1531972108162022-12-22T00:05:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1392m139210.1107/S1600536810039735Diaqua(nitrato-κ2O,O′)[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]cadmium(II) nitrateShi Guo ZhangHui Ming ZhangIn the title complex, [Cd(C14H9N5)(NO3)(H2O)2]NO3, the CdII ion is coordinated in a distorted pentagonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate ligand. Two aqua ligands are coordinated at the axial sites. All non-H atoms in the equatorial plane are co-planar within 0.0673 Å. In the crystal, intermolecular O—H...O and O—H...N hydrogen bonds connect the components into a two-dimensional network parallel to (001). In addition, there is a π–π stacking interaction between symmetry-related benzene rings, with a centroid–centroid distance of 3.598 (3) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536810039735 |
| spellingShingle | Shi Guo Zhang Hui Ming Zhang Diaqua(nitrato-κ2O,O′)[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]cadmium(II) nitrate Acta Crystallographica Section E |
| title | Diaqua(nitrato-κ2O,O′)[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]cadmium(II) nitrate |
| title_full | Diaqua(nitrato-κ2O,O′)[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]cadmium(II) nitrate |
| title_fullStr | Diaqua(nitrato-κ2O,O′)[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]cadmium(II) nitrate |
| title_full_unstemmed | Diaqua(nitrato-κ2O,O′)[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]cadmium(II) nitrate |
| title_short | Diaqua(nitrato-κ2O,O′)[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]cadmium(II) nitrate |
| title_sort | diaqua nitrato amp 954 2o o amp 8242 2 1h 1 2 4 triazol 1 yl amp 954 n2 1 10 phenanthroline amp 954 2n n amp 8242 cadmium ii nitrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810039735 |
| work_keys_str_mv | AT shiguozhang diaquanitratoamp9542ooamp824221h124triazol1ylamp954n2110phenanthrolineamp9542nnamp8242cadmiumiinitrate AT huimingzhang diaquanitratoamp9542ooamp824221h124triazol1ylamp954n2110phenanthrolineamp9542nnamp8242cadmiumiinitrate |