Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds
Novel methodologies for introducing sulfoxonium groups into organic molecules are desirable. Here the authors report the synthesis of an iodonium-sulfoxonium ylide reagent that enables the preparation of sulfoxonium-containing cyclic structures upon reaction with alkenes, alkynes, nitriles or allene...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-11-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-34401-7 |
| _version_ | 1811328675191193600 |
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| author | Li Li Kun Deng Yajie Xing Cheng Ma Shao-Fei Ni Zhaofeng Wang Yong Huang |
| author_facet | Li Li Kun Deng Yajie Xing Cheng Ma Shao-Fei Ni Zhaofeng Wang Yong Huang |
| author_sort | Li Li |
| collection | DOAJ |
| description | Novel methodologies for introducing sulfoxonium groups into organic molecules are desirable. Here the authors report the synthesis of an iodonium-sulfoxonium ylide reagent that enables the preparation of sulfoxonium-containing cyclic structures upon reaction with alkenes, alkynes, nitriles or allenes. |
| first_indexed | 2024-04-13T15:29:08Z |
| format | Article |
| id | doaj.art-c4a967369e794af197e47e168d846152 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-13T15:29:08Z |
| publishDate | 2022-11-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-c4a967369e794af197e47e168d8461522022-12-22T02:41:25ZengNature PortfolioNature Communications2041-17232022-11-011311910.1038/s41467-022-34401-7Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bondsLi Li0Kun Deng1Yajie Xing2Cheng Ma3Shao-Fei Ni4Zhaofeng Wang5Yong Huang6Department of Chemistry, The Hong Kong University of Science and TechnologyState Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan UniversityDepartment of Chemistry, The Hong Kong University of Science and TechnologyDepartment of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou UniversityDepartment of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou UniversityState Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan UniversityDepartment of Chemistry, The Hong Kong University of Science and TechnologyNovel methodologies for introducing sulfoxonium groups into organic molecules are desirable. Here the authors report the synthesis of an iodonium-sulfoxonium ylide reagent that enables the preparation of sulfoxonium-containing cyclic structures upon reaction with alkenes, alkynes, nitriles or allenes.https://doi.org/10.1038/s41467-022-34401-7 |
| spellingShingle | Li Li Kun Deng Yajie Xing Cheng Ma Shao-Fei Ni Zhaofeng Wang Yong Huang Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds Nature Communications |
| title | Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds |
| title_full | Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds |
| title_fullStr | Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds |
| title_full_unstemmed | Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds |
| title_short | Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds |
| title_sort | synthesis of i iii s vi reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds |
| url | https://doi.org/10.1038/s41467-022-34401-7 |
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