Probing relaxations of atomic-scale junctions in the Pauli repulsion range

Clean metal as well as C _60 -terminated tips of an atomic force microscope probe the interaction with C _60 molecules adsorbed on Cu(111) and Pb(111). The force measurements unveil a monotonic shift of the point of maximum attraction with the bias voltage. The conventional superposition of long-ran...

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Bibliographic Details
Main Authors: J Brand, N Néel, J Kröger
Format: Article
Language:English
Published: IOP Publishing 2019-01-01
Series:New Journal of Physics
Subjects:
Online Access:https://doi.org/10.1088/1367-2630/ab4c84
Description
Summary:Clean metal as well as C _60 -terminated tips of an atomic force microscope probe the interaction with C _60 molecules adsorbed on Cu(111) and Pb(111). The force measurements unveil a monotonic shift of the point of maximum attraction with the bias voltage. The conventional superposition of long-range van der Waals and electrostatic forces with short-range Pauli repulsion does not reproduce the shift. By phenomenologically including bias-dependent relaxations of the electrode geometry in the analytical expression for the short-range force the experimental data can qualitatively be described.
ISSN:1367-2630