NEW INITIATOR SYSTEMS FOR POLYMERIZATION OF VINYL MONOMERS TERTIARY HYDROPEROXIDES — COMPLEX OF COPPER(II) CHLORIDE WITH PIPERIDIN-1-YL PIPERIDINE-1-CARBODITHIOATE
Kinetics of polymerization of styrene in-bulk initiated by tertiary hydroperoxides of butyl and cumene, by the complex of copper(II) chloride with piperidin-1-yl piperidine-1-carbodithioate and systems on their basis in a temperature range 293—363 K is studied. The kinetic parameters of polymerizati...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Odessa I. I. Mechnikov National University
2015-02-01
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| Series: | Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
| Subjects: | |
| Online Access: | http://heraldchem.onu.edu.ua/article/view/38128 |
| Summary: | Kinetics of polymerization of styrene in-bulk initiated by tertiary hydroperoxides
of butyl and cumene, by the complex of copper(II) chloride with piperidin-1-yl piperidine-1-carbodithioate and systems on their basis in a temperature range 293—363 K is studied. The kinetic parameters of polymerization process are determined. It is set that application of the double-base systems tertiary hydroperoxides — complex of copper(II) chloride with piperidin-1-yl piperidine-1-carbodithioate for polymerization of styrene is accompanied by the substantial decline of energy of activation of initiating. |
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| ISSN: | 2304-0947 2414-5963 |