Orientation morphology evolution and mechanical properties of injection molded thermoplastic polyurethane

The effects of melt flow on the orientation evolution, residual stress and mechanical properties of thermoplastic polyurethane (TPU) during injection molding were studied by birefringence, small angle X-ray scattering (SAXS) and wide angle X-ray scattering (WAXS). The birefringence results show that...

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Main Authors: XIANG Ning, ZHANG Xiao-wen, GE Yong, DING Yao, ZHENG Meng-yao, YAN Yue
Format: Article
Language:zho
Published: Journal of Materials Engineering 2021-12-01
Series:Cailiao gongcheng
Subjects:
Online Access:http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2021.000121
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author XIANG Ning
ZHANG Xiao-wen
GE Yong
DING Yao
ZHENG Meng-yao
YAN Yue
author_facet XIANG Ning
ZHANG Xiao-wen
GE Yong
DING Yao
ZHENG Meng-yao
YAN Yue
author_sort XIANG Ning
collection DOAJ
description The effects of melt flow on the orientation evolution, residual stress and mechanical properties of thermoplastic polyurethane (TPU) during injection molding were studied by birefringence, small angle X-ray scattering (SAXS) and wide angle X-ray scattering (WAXS). The birefringence results show that the residual stress is decreased along the melt flow direction. The hard segments of TPU molecular chains are oriented along the melt flow direction, while the hard domains are oriented perpendicular to the melt flow direction according to the results of SAXS and WAXS. The tensile properties of TPU parts show obvious differences along the melt flow direction and perpendicular to the melt flow direction. The tensile strength of the middle region of the part is the highest because the orientation degree of hard segment and hard domain is the highest in the middle region of the part, and the orientation of hard segment and hard domain is helpful to improve the tensile strength.
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spelling doaj.art-c4f08e672c944539ab7f6dfd4a33eb0b2023-01-02T01:11:42ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43812021-12-01491215616310.11868/j.issn.1001-4381.2021.0001211639966371555-1254182782Orientation morphology evolution and mechanical properties of injection molded thermoplastic polyurethaneXIANG Ning0ZHANG Xiao-wen1GE Yong2DING Yao3ZHENG Meng-yao4YAN Yue5AECC Beijing Institute of Aeronautical Materials, Beijing 100095, ChinaAECC Beijing Institute of Aeronautical Materials, Beijing 100095, ChinaAECC Beijing Institute of Aeronautical Materials, Beijing 100095, ChinaAECC Beijing Institute of Aeronautical Materials, Beijing 100095, ChinaAECC Beijing Institute of Aeronautical Materials, Beijing 100095, ChinaAECC Beijing Institute of Aeronautical Materials, Beijing 100095, ChinaThe effects of melt flow on the orientation evolution, residual stress and mechanical properties of thermoplastic polyurethane (TPU) during injection molding were studied by birefringence, small angle X-ray scattering (SAXS) and wide angle X-ray scattering (WAXS). The birefringence results show that the residual stress is decreased along the melt flow direction. The hard segments of TPU molecular chains are oriented along the melt flow direction, while the hard domains are oriented perpendicular to the melt flow direction according to the results of SAXS and WAXS. The tensile properties of TPU parts show obvious differences along the melt flow direction and perpendicular to the melt flow direction. The tensile strength of the middle region of the part is the highest because the orientation degree of hard segment and hard domain is the highest in the middle region of the part, and the orientation of hard segment and hard domain is helpful to improve the tensile strength.http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2021.000121thermoplastic polyurethaneinjection moldingorientation degreeresidual stresstensile property
spellingShingle XIANG Ning
ZHANG Xiao-wen
GE Yong
DING Yao
ZHENG Meng-yao
YAN Yue
Orientation morphology evolution and mechanical properties of injection molded thermoplastic polyurethane
Cailiao gongcheng
thermoplastic polyurethane
injection molding
orientation degree
residual stress
tensile property
title Orientation morphology evolution and mechanical properties of injection molded thermoplastic polyurethane
title_full Orientation morphology evolution and mechanical properties of injection molded thermoplastic polyurethane
title_fullStr Orientation morphology evolution and mechanical properties of injection molded thermoplastic polyurethane
title_full_unstemmed Orientation morphology evolution and mechanical properties of injection molded thermoplastic polyurethane
title_short Orientation morphology evolution and mechanical properties of injection molded thermoplastic polyurethane
title_sort orientation morphology evolution and mechanical properties of injection molded thermoplastic polyurethane
topic thermoplastic polyurethane
injection molding
orientation degree
residual stress
tensile property
url http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2021.000121
work_keys_str_mv AT xiangning orientationmorphologyevolutionandmechanicalpropertiesofinjectionmoldedthermoplasticpolyurethane
AT zhangxiaowen orientationmorphologyevolutionandmechanicalpropertiesofinjectionmoldedthermoplasticpolyurethane
AT geyong orientationmorphologyevolutionandmechanicalpropertiesofinjectionmoldedthermoplasticpolyurethane
AT dingyao orientationmorphologyevolutionandmechanicalpropertiesofinjectionmoldedthermoplasticpolyurethane
AT zhengmengyao orientationmorphologyevolutionandmechanicalpropertiesofinjectionmoldedthermoplasticpolyurethane
AT yanyue orientationmorphologyevolutionandmechanicalpropertiesofinjectionmoldedthermoplasticpolyurethane