Preliminary Study of Epoxidation of Soybean Oil in Stirred Tank Reactor: the Effect of the Mixing Program

Epoxidated vegetable oils are largely employed as plasticizer instead of harmful phthalates and they represent a sustainable choice to produce lubricants and intermediates. In this work, the epoxidation of soybean oil is carried using hydrogen peroxide (H2O2) 32wt.% and acetic acid instead of the co...

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Main Authors: C. Vianello, D. Piccolo, E. Salzano, G. Maschio
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2017-03-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/2239
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author C. Vianello
D. Piccolo
E. Salzano
G. Maschio
author_facet C. Vianello
D. Piccolo
E. Salzano
G. Maschio
author_sort C. Vianello
collection DOAJ
description Epoxidated vegetable oils are largely employed as plasticizer instead of harmful phthalates and they represent a sustainable choice to produce lubricants and intermediates. In this work, the epoxidation of soybean oil is carried using hydrogen peroxide (H2O2) 32wt.% and acetic acid instead of the commonly used H2O2 at 60wt.% and formic acid to reduce the risk of detonation and corrosion. The efficacy of an acid catalyst (sulfuric acid) is tested. Particular attention is focussed on a proper mixing program.
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spelling doaj.art-c53484be4eb34aeeabd2314d8f8898672022-12-21T19:47:43ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162017-03-015710.3303/CET1757176Preliminary Study of Epoxidation of Soybean Oil in Stirred Tank Reactor: the Effect of the Mixing ProgramC. VianelloD. PiccoloE. SalzanoG. MaschioEpoxidated vegetable oils are largely employed as plasticizer instead of harmful phthalates and they represent a sustainable choice to produce lubricants and intermediates. In this work, the epoxidation of soybean oil is carried using hydrogen peroxide (H2O2) 32wt.% and acetic acid instead of the commonly used H2O2 at 60wt.% and formic acid to reduce the risk of detonation and corrosion. The efficacy of an acid catalyst (sulfuric acid) is tested. Particular attention is focussed on a proper mixing program.https://www.cetjournal.it/index.php/cet/article/view/2239
spellingShingle C. Vianello
D. Piccolo
E. Salzano
G. Maschio
Preliminary Study of Epoxidation of Soybean Oil in Stirred Tank Reactor: the Effect of the Mixing Program
Chemical Engineering Transactions
title Preliminary Study of Epoxidation of Soybean Oil in Stirred Tank Reactor: the Effect of the Mixing Program
title_full Preliminary Study of Epoxidation of Soybean Oil in Stirred Tank Reactor: the Effect of the Mixing Program
title_fullStr Preliminary Study of Epoxidation of Soybean Oil in Stirred Tank Reactor: the Effect of the Mixing Program
title_full_unstemmed Preliminary Study of Epoxidation of Soybean Oil in Stirred Tank Reactor: the Effect of the Mixing Program
title_short Preliminary Study of Epoxidation of Soybean Oil in Stirred Tank Reactor: the Effect of the Mixing Program
title_sort preliminary study of epoxidation of soybean oil in stirred tank reactor the effect of the mixing program
url https://www.cetjournal.it/index.php/cet/article/view/2239
work_keys_str_mv AT cvianello preliminarystudyofepoxidationofsoybeanoilinstirredtankreactortheeffectofthemixingprogram
AT dpiccolo preliminarystudyofepoxidationofsoybeanoilinstirredtankreactortheeffectofthemixingprogram
AT esalzano preliminarystudyofepoxidationofsoybeanoilinstirredtankreactortheeffectofthemixingprogram
AT gmaschio preliminarystudyofepoxidationofsoybeanoilinstirredtankreactortheeffectofthemixingprogram