{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II)
In the title compound, [Ni(C19H16Cl4N2O2)], the NiII ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetradentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, molecules are linked into...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812002085 |
| _version_ | 1828130775536500736 |
|---|---|
| author | Hadi Kargar Reza Kia Saeideh Abbasian Muhammad Nawaz Tahir |
| author_facet | Hadi Kargar Reza Kia Saeideh Abbasian Muhammad Nawaz Tahir |
| author_sort | Hadi Kargar |
| collection | DOAJ |
| description | In the title compound, [Ni(C19H16Cl4N2O2)], the NiII ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetradentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, molecules are linked into chains along the b axis by weak C—H...O and C—H...Cl interactions. An intermolecular Cl...Cl [3.4564 (19) Å] interaction is present which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 Å). |
| first_indexed | 2024-04-11T16:37:29Z |
| format | Article |
| id | doaj.art-c5400d49894c4cb48816ed817f32329d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:37:29Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c5400d49894c4cb48816ed817f32329d2022-12-22T04:13:48ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m193m19310.1107/S1600536812002085{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II)Hadi KargarReza KiaSaeideh AbbasianMuhammad Nawaz TahirIn the title compound, [Ni(C19H16Cl4N2O2)], the NiII ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetradentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, molecules are linked into chains along the b axis by weak C—H...O and C—H...Cl interactions. An intermolecular Cl...Cl [3.4564 (19) Å] interaction is present which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 Å).http://scripts.iucr.org/cgi-bin/paper?S1600536812002085 |
| spellingShingle | Hadi Kargar Reza Kia Saeideh Abbasian Muhammad Nawaz Tahir {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II) Acta Crystallographica Section E |
| title | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II) |
| title_full | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II) |
| title_fullStr | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II) |
| title_full_unstemmed | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II) |
| title_short | {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II) |
| title_sort | 4 4 amp 8242 6 6 amp 8242 tetrachloro 2 2 amp 8242 2 2 dimethylpropane 1 3 diylbis nitrilomethanylylidene nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812002085 |
| work_keys_str_mv | AT hadikargar 44amp824266amp8242tetrachloro22amp824222dimethylpropane13diylbisnitrilomethanylylidenenickelii AT rezakia 44amp824266amp8242tetrachloro22amp824222dimethylpropane13diylbisnitrilomethanylylidenenickelii AT saeidehabbasian 44amp824266amp8242tetrachloro22amp824222dimethylpropane13diylbisnitrilomethanylylidenenickelii AT muhammadnawaztahir 44amp824266amp8242tetrachloro22amp824222dimethylpropane13diylbisnitrilomethanylylidenenickelii |