Molecular theory of partial molar volume and its applications to biomolecular systems
The paial molar volume (PMV) is a thermodynamic quantity which contains important information about the solute-solvent interactions as well as the solute structure in solution.Additionally, the PMV is the most essential quantity in the analysis of the pressure effect on chemical reactions. This aicl...
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| Format: | Article |
| Language: | English |
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Institute for Condensed Matter Physics
2007-09-01
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| Series: | Condensed Matter Physics |
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| Online Access: | http://dx.doi.org/10.5488/CMP.10.3.343 |
| _version_ | 1818114698864754688 |
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| author | T.Imai |
| author_facet | T.Imai |
| author_sort | T.Imai |
| collection | DOAJ |
| description | The paial molar volume (PMV) is a thermodynamic quantity which contains important information about the solute-solvent interactions as well as the solute structure in solution.Additionally, the PMV is the most essential quantity in the analysis of the pressure effect on chemical reactions. This aicle reviews the recent developments in molecular theories of the PMV, especially the reference interaction site model (RISM)theory of molecular liquids and its three-dimensional generalization version (3D-RISM), which are combined with the Kirkwood-Buff solution theory to calculate the PMV. This aicle also introduces our recent applications of the theory to some interesting issues concerning the PMV of biomolecules. In addition, theoretical representations of the effects of intramolecular fluctuation on the PMV, which are significant for biomacromolecules, are briefly discussed. |
| first_indexed | 2024-12-11T03:54:52Z |
| format | Article |
| id | doaj.art-c54be362bd304bbe83fc44cf37b7f2c5 |
| institution | Directory Open Access Journal |
| issn | 1607-324X |
| language | English |
| last_indexed | 2024-12-11T03:54:52Z |
| publishDate | 2007-09-01 |
| publisher | Institute for Condensed Matter Physics |
| record_format | Article |
| series | Condensed Matter Physics |
| spelling | doaj.art-c54be362bd304bbe83fc44cf37b7f2c52022-12-22T01:21:49ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2007-09-01103343Molecular theory of partial molar volume and its applications to biomolecular systemsT.ImaiThe paial molar volume (PMV) is a thermodynamic quantity which contains important information about the solute-solvent interactions as well as the solute structure in solution.Additionally, the PMV is the most essential quantity in the analysis of the pressure effect on chemical reactions. This aicle reviews the recent developments in molecular theories of the PMV, especially the reference interaction site model (RISM)theory of molecular liquids and its three-dimensional generalization version (3D-RISM), which are combined with the Kirkwood-Buff solution theory to calculate the PMV. This aicle also introduces our recent applications of the theory to some interesting issues concerning the PMV of biomolecules. In addition, theoretical representations of the effects of intramolecular fluctuation on the PMV, which are significant for biomacromolecules, are briefly discussed.http://dx.doi.org/10.5488/CMP.10.3.343paial molar volumepressure effectbiomolecular solutionKirkwood-Buff theoryRISM theory |
| spellingShingle | T.Imai Molecular theory of partial molar volume and its applications to biomolecular systems Condensed Matter Physics paial molar volume pressure effect biomolecular solution Kirkwood-Buff theory RISM theory |
| title | Molecular theory of partial molar volume and its applications to biomolecular systems |
| title_full | Molecular theory of partial molar volume and its applications to biomolecular systems |
| title_fullStr | Molecular theory of partial molar volume and its applications to biomolecular systems |
| title_full_unstemmed | Molecular theory of partial molar volume and its applications to biomolecular systems |
| title_short | Molecular theory of partial molar volume and its applications to biomolecular systems |
| title_sort | molecular theory of partial molar volume and its applications to biomolecular systems |
| topic | paial molar volume pressure effect biomolecular solution Kirkwood-Buff theory RISM theory |
| url | http://dx.doi.org/10.5488/CMP.10.3.343 |
| work_keys_str_mv | AT timai moleculartheoryofpartialmolarvolumeanditsapplicationstobiomolecularsystems |