Sunscreen Enhancement of Octyl Methoxycinnamate Microcapsules by Using Two Biopolymers as Wall Materials

Octyl methoxycinnamate (OMC) is widely used as a chemical sunscreen in sunscreen cosmetics. However, its direct contact with the skin would bring certain risks, such as skin photosensitive reaction. How to improve the effect of skin photodamage protection has become a current research hotspot. Encap...

Full description

Bibliographic Details
Main Authors: Chuntao Xu, Xuemin Zeng, Zujin Yang, Hongbing Ji
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/13/6/866
_version_ 1797541712824893440
author Chuntao Xu
Xuemin Zeng
Zujin Yang
Hongbing Ji
author_facet Chuntao Xu
Xuemin Zeng
Zujin Yang
Hongbing Ji
author_sort Chuntao Xu
collection DOAJ
description Octyl methoxycinnamate (OMC) is widely used as a chemical sunscreen in sunscreen cosmetics. However, its direct contact with the skin would bring certain risks, such as skin photosensitive reaction. How to improve the effect of skin photodamage protection has become a current research hotspot. Encapsulating ultraviolet (UV) filters into microcapsules is an interesting method to increase the photostability of filters. In this study, sodium caseinate (SC) and arabic gum (GA) are chosen as wall materials to prepare synergistic sunscreen microcapsules by complex coacervation technology. A series of experiments are conducted to investigate the effects of pH, wall material concentration, and wall/core ratio on the formation of OMC microcapsules. The morphology, composition, and stability of OMC microcapsules are characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). The OMC microcapsule is uniform in size distribution, smooth in surface morphology, and has good thermal stability. The results show that the ultraviolet absorption of the OMC microcapsules is better than that of the uncoated OMC for the ultraviolet-B (280–320 nm). Moreover, the OMC microcapsule released 40% in 12 h, while OMC released 65%, but the sun protection factor (SPF) of the OMC microcapsule sunscreen is 18.75% higher than that of OMC. This phenomenon may be attributed to the hydrophobic interaction between SC and OMC and the electrostatic interaction between SC and GA.
first_indexed 2024-03-10T13:20:38Z
format Article
id doaj.art-c5603e7a1203448997d12e501a4d65d5
institution Directory Open Access Journal
issn 2073-4360
language English
last_indexed 2024-03-10T13:20:38Z
publishDate 2021-03-01
publisher MDPI AG
record_format Article
series Polymers
spelling doaj.art-c5603e7a1203448997d12e501a4d65d52023-11-21T10:06:17ZengMDPI AGPolymers2073-43602021-03-0113686610.3390/polym13060866Sunscreen Enhancement of Octyl Methoxycinnamate Microcapsules by Using Two Biopolymers as Wall MaterialsChuntao Xu0Xuemin Zeng1Zujin Yang2Hongbing Ji3School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, ChinaFine Chemical Industry Research Institute, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, ChinaSchool of Chemical Engineering and Technology, Sun Yat-Sen University, Zhuhai 519082, ChinaSchool of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, ChinaOctyl methoxycinnamate (OMC) is widely used as a chemical sunscreen in sunscreen cosmetics. However, its direct contact with the skin would bring certain risks, such as skin photosensitive reaction. How to improve the effect of skin photodamage protection has become a current research hotspot. Encapsulating ultraviolet (UV) filters into microcapsules is an interesting method to increase the photostability of filters. In this study, sodium caseinate (SC) and arabic gum (GA) are chosen as wall materials to prepare synergistic sunscreen microcapsules by complex coacervation technology. A series of experiments are conducted to investigate the effects of pH, wall material concentration, and wall/core ratio on the formation of OMC microcapsules. The morphology, composition, and stability of OMC microcapsules are characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). The OMC microcapsule is uniform in size distribution, smooth in surface morphology, and has good thermal stability. The results show that the ultraviolet absorption of the OMC microcapsules is better than that of the uncoated OMC for the ultraviolet-B (280–320 nm). Moreover, the OMC microcapsule released 40% in 12 h, while OMC released 65%, but the sun protection factor (SPF) of the OMC microcapsule sunscreen is 18.75% higher than that of OMC. This phenomenon may be attributed to the hydrophobic interaction between SC and OMC and the electrostatic interaction between SC and GA.https://www.mdpi.com/2073-4360/13/6/866octyl methoxycinnamatesunscreenmicrocapsulecomplex coacervationsynergistic effects
spellingShingle Chuntao Xu
Xuemin Zeng
Zujin Yang
Hongbing Ji
Sunscreen Enhancement of Octyl Methoxycinnamate Microcapsules by Using Two Biopolymers as Wall Materials
Polymers
octyl methoxycinnamate
sunscreen
microcapsule
complex coacervation
synergistic effects
title Sunscreen Enhancement of Octyl Methoxycinnamate Microcapsules by Using Two Biopolymers as Wall Materials
title_full Sunscreen Enhancement of Octyl Methoxycinnamate Microcapsules by Using Two Biopolymers as Wall Materials
title_fullStr Sunscreen Enhancement of Octyl Methoxycinnamate Microcapsules by Using Two Biopolymers as Wall Materials
title_full_unstemmed Sunscreen Enhancement of Octyl Methoxycinnamate Microcapsules by Using Two Biopolymers as Wall Materials
title_short Sunscreen Enhancement of Octyl Methoxycinnamate Microcapsules by Using Two Biopolymers as Wall Materials
title_sort sunscreen enhancement of octyl methoxycinnamate microcapsules by using two biopolymers as wall materials
topic octyl methoxycinnamate
sunscreen
microcapsule
complex coacervation
synergistic effects
url https://www.mdpi.com/2073-4360/13/6/866
work_keys_str_mv AT chuntaoxu sunscreenenhancementofoctylmethoxycinnamatemicrocapsulesbyusingtwobiopolymersaswallmaterials
AT xueminzeng sunscreenenhancementofoctylmethoxycinnamatemicrocapsulesbyusingtwobiopolymersaswallmaterials
AT zujinyang sunscreenenhancementofoctylmethoxycinnamatemicrocapsulesbyusingtwobiopolymersaswallmaterials
AT hongbingji sunscreenenhancementofoctylmethoxycinnamatemicrocapsulesbyusingtwobiopolymersaswallmaterials