Shape-Programmable Liquid Metal Fibers

Conductive and stretchable fibers are the cornerstone of intelligent textiles and imperceptible electronics. Among existing fiber conductors, gallium-based liquid metals (LMs) featuring high conductivity, fluidity, and self-healing are excellent candidates for highly stretchable fibers with sensing,...

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Main Authors: Biao Ma, Jin Zhang, Gangsheng Chen, Yi Chen, Chengtao Xu, Lanjie Lei, Hong Liu
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Biosensors
Subjects:
Online Access:https://www.mdpi.com/2079-6374/13/1/28
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author Biao Ma
Jin Zhang
Gangsheng Chen
Yi Chen
Chengtao Xu
Lanjie Lei
Hong Liu
author_facet Biao Ma
Jin Zhang
Gangsheng Chen
Yi Chen
Chengtao Xu
Lanjie Lei
Hong Liu
author_sort Biao Ma
collection DOAJ
description Conductive and stretchable fibers are the cornerstone of intelligent textiles and imperceptible electronics. Among existing fiber conductors, gallium-based liquid metals (LMs) featuring high conductivity, fluidity, and self-healing are excellent candidates for highly stretchable fibers with sensing, actuation, power generation, and interconnection functionalities. However, current LM fibers fabricated by direct injection or surface coating have a limitation in shape programmability. This hinders their applications in functional fibers with tunable electromechanical response and miniaturization. Here, we reported a simple and efficient method to create shape-programmable LM fibers using the phase transition of gallium. Gallium metal wires in the solid state can be easily shaped into a 3D helical structure, and the structure can be preserved after coating the wire with polyurethane and liquifying the metal. The 3D helical LM fiber offered enhanced stretchability with a high breaking strain of 1273% and showed invariable conductance over 283% strain. Moreover, we can reduce the fiber diameter by stretching the fiber during the solidification of polyurethane. We also demonstrated applications of the programmed fibers in self-powered strain sensing, heart rate monitoring, airflow, and humidity sensing. This work provided simple and facile ways toward functional LM fibers, which may facilitate the broad applications of LM fibers in e-skins, wearable computation, soft robots, and smart fabrics.
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spelling doaj.art-c5711fc9bf4f48f4baa3fa953816f90b2023-11-30T21:24:28ZengMDPI AGBiosensors2079-63742022-12-011312810.3390/bios13010028Shape-Programmable Liquid Metal FibersBiao Ma0Jin Zhang1Gangsheng Chen2Yi Chen3Chengtao Xu4Lanjie Lei5Hong Liu6State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096, ChinaState Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096, ChinaState Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096, ChinaState Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096, ChinaState Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096, ChinaState Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096, ChinaState Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096, ChinaConductive and stretchable fibers are the cornerstone of intelligent textiles and imperceptible electronics. Among existing fiber conductors, gallium-based liquid metals (LMs) featuring high conductivity, fluidity, and self-healing are excellent candidates for highly stretchable fibers with sensing, actuation, power generation, and interconnection functionalities. However, current LM fibers fabricated by direct injection or surface coating have a limitation in shape programmability. This hinders their applications in functional fibers with tunable electromechanical response and miniaturization. Here, we reported a simple and efficient method to create shape-programmable LM fibers using the phase transition of gallium. Gallium metal wires in the solid state can be easily shaped into a 3D helical structure, and the structure can be preserved after coating the wire with polyurethane and liquifying the metal. The 3D helical LM fiber offered enhanced stretchability with a high breaking strain of 1273% and showed invariable conductance over 283% strain. Moreover, we can reduce the fiber diameter by stretching the fiber during the solidification of polyurethane. We also demonstrated applications of the programmed fibers in self-powered strain sensing, heart rate monitoring, airflow, and humidity sensing. This work provided simple and facile ways toward functional LM fibers, which may facilitate the broad applications of LM fibers in e-skins, wearable computation, soft robots, and smart fabrics.https://www.mdpi.com/2079-6374/13/1/28liquid metalconductive fiberstretchable electrodesflexible electronicswearable sensors
spellingShingle Biao Ma
Jin Zhang
Gangsheng Chen
Yi Chen
Chengtao Xu
Lanjie Lei
Hong Liu
Shape-Programmable Liquid Metal Fibers
Biosensors
liquid metal
conductive fiber
stretchable electrodes
flexible electronics
wearable sensors
title Shape-Programmable Liquid Metal Fibers
title_full Shape-Programmable Liquid Metal Fibers
title_fullStr Shape-Programmable Liquid Metal Fibers
title_full_unstemmed Shape-Programmable Liquid Metal Fibers
title_short Shape-Programmable Liquid Metal Fibers
title_sort shape programmable liquid metal fibers
topic liquid metal
conductive fiber
stretchable electrodes
flexible electronics
wearable sensors
url https://www.mdpi.com/2079-6374/13/1/28
work_keys_str_mv AT biaoma shapeprogrammableliquidmetalfibers
AT jinzhang shapeprogrammableliquidmetalfibers
AT gangshengchen shapeprogrammableliquidmetalfibers
AT yichen shapeprogrammableliquidmetalfibers
AT chengtaoxu shapeprogrammableliquidmetalfibers
AT lanjielei shapeprogrammableliquidmetalfibers
AT hongliu shapeprogrammableliquidmetalfibers