4,4′-Bipyridinium bis(2-carboxypyridine-3-carboxylate)
The title salt, C10H10N22+·2C7H4NO4− or (4,4′-bpyH2)(py-2,3-dcH)2, prepared by the reaction between pyridine-2,3-dicarboxylic acid (py-2,3-dcH2) and 4,4′-bipyridine (4,4′-bpy), consists of two anions and one centrosymmetric dication. In the crystal, t...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808042220 |
| _version_ | 1798030814047371264 |
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| author | Janet Soleimannejad Hossein Aghabozorg Ali Morsali Foruzan Hemmati Faranak Manteghi |
| author_facet | Janet Soleimannejad Hossein Aghabozorg Ali Morsali Foruzan Hemmati Faranak Manteghi |
| author_sort | Janet Soleimannejad |
| collection | DOAJ |
| description | The title salt, C10H10N22+·2C7H4NO4− or (4,4′-bpyH2)(py-2,3-dcH)2, prepared by the reaction between pyridine-2,3-dicarboxylic acid (py-2,3-dcH2) and 4,4′-bipyridine (4,4′-bpy), consists of two anions and one centrosymmetric dication. In the crystal, there are two strong O—H...O hydrogen bonds involving the two carboxylate groups, with an O...O distance of 2.478 (1) Å, and an N—H...N hydrogen bond between the anion and cation, with an N...N distance of 2.743 (1) Å. These interactions, along with other O—H...O and C—H...O hydrogen bonds, π–π stacking [centroid–centroid distances 3.621 (7) and 3.612 (7) Å] and ion pairing, lead to the formation of the three-dimensional structure. |
| first_indexed | 2024-04-11T19:47:28Z |
| format | Article |
| id | doaj.art-c58d40eefa054146967e8c2f198fbd6e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:47:28Z |
| publishDate | 2009-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c58d40eefa054146967e8c2f198fbd6e2022-12-22T04:06:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651o153o15310.1107/S16005368080422204,4′-Bipyridinium bis(2-carboxypyridine-3-carboxylate)Janet SoleimannejadHossein AghabozorgAli MorsaliForuzan HemmatiFaranak ManteghiThe title salt, C10H10N22+·2C7H4NO4− or (4,4′-bpyH2)(py-2,3-dcH)2, prepared by the reaction between pyridine-2,3-dicarboxylic acid (py-2,3-dcH2) and 4,4′-bipyridine (4,4′-bpy), consists of two anions and one centrosymmetric dication. In the crystal, there are two strong O—H...O hydrogen bonds involving the two carboxylate groups, with an O...O distance of 2.478 (1) Å, and an N—H...N hydrogen bond between the anion and cation, with an N...N distance of 2.743 (1) Å. These interactions, along with other O—H...O and C—H...O hydrogen bonds, π–π stacking [centroid–centroid distances 3.621 (7) and 3.612 (7) Å] and ion pairing, lead to the formation of the three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808042220 |
| spellingShingle | Janet Soleimannejad Hossein Aghabozorg Ali Morsali Foruzan Hemmati Faranak Manteghi 4,4′-Bipyridinium bis(2-carboxypyridine-3-carboxylate) Acta Crystallographica Section E |
| title | 4,4′-Bipyridinium bis(2-carboxypyridine-3-carboxylate) |
| title_full | 4,4′-Bipyridinium bis(2-carboxypyridine-3-carboxylate) |
| title_fullStr | 4,4′-Bipyridinium bis(2-carboxypyridine-3-carboxylate) |
| title_full_unstemmed | 4,4′-Bipyridinium bis(2-carboxypyridine-3-carboxylate) |
| title_short | 4,4′-Bipyridinium bis(2-carboxypyridine-3-carboxylate) |
| title_sort | 4 4 8242 bipyridinium bis 2 carboxypyridine 3 carboxylate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808042220 |
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