Photocatalytic aerobic oxidative functionalization (PAOF) reaction of benzyl alcohols by GO-MIL-100(Fe) composite in glycerol/K2CO3 deep eutectic solvent
Abstract An MIL-100 (Fe)/graphene oxide (GO) hybrid, a fairly-known composite, was made through a simple one-step procedure and played a highlighted role in the photo-induced oxidative functionalization of the benzylic C–H bond. To identify the given binary composite, various techniques were applied...
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2022-10-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-022-22369-9 |
| _version_ | 1811257092535746560 |
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| author | Sepideh Abbasi Mohammad Reza Naimi-Jamal Shahrzad Javanshir Akbar Heydari |
| author_facet | Sepideh Abbasi Mohammad Reza Naimi-Jamal Shahrzad Javanshir Akbar Heydari |
| author_sort | Sepideh Abbasi |
| collection | DOAJ |
| description | Abstract An MIL-100 (Fe)/graphene oxide (GO) hybrid, a fairly-known composite, was made through a simple one-step procedure and played a highlighted role in the photo-induced oxidative functionalization of the benzylic C–H bond. To identify the given binary composite, various techniques were applied: FT-IR, P-XRD, SEM, nitrogen absorption–desorption analysis, TGA, TEM, and UV–Visible DRS spectra. Proportions of GO used within the structure of the prepared composite differently ranged from low to high amount, and the most optimized ratio met at 38.5% of GO as the most efficient catalyst. Additionally, the reaction ran in Glycerol/K2CO3 (2:1) as the optimal solvent. The elemental roles of O2 ·− and OH− were supposed to be the major ones for running a tandem oxidation-Knoevenagel reaction. The heterogeneity and reusability of the catalyst were also examined and confirmed after five successive runs. |
| first_indexed | 2024-04-12T17:51:15Z |
| format | Article |
| id | doaj.art-c5aa435384754b47b5f365e4cc3ad24d |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-04-12T17:51:15Z |
| publishDate | 2022-10-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-c5aa435384754b47b5f365e4cc3ad24d2022-12-22T03:22:30ZengNature PortfolioScientific Reports2045-23222022-10-0112111210.1038/s41598-022-22369-9Photocatalytic aerobic oxidative functionalization (PAOF) reaction of benzyl alcohols by GO-MIL-100(Fe) composite in glycerol/K2CO3 deep eutectic solventSepideh Abbasi0Mohammad Reza Naimi-Jamal1Shahrzad Javanshir2Akbar Heydari3Research Laboratory of Green Organic Synthesis and Polymers, Department of Chemistry, Iran University of Science and Technology (IUST)Research Laboratory of Green Organic Synthesis and Polymers, Department of Chemistry, Iran University of Science and Technology (IUST)Pharmaceutical and Heterocyclic Compounds Research Laboratory, Department of Chemistry, Iran University of Science and TechnologyChemistry Department, Tarbiat Modares UniversityAbstract An MIL-100 (Fe)/graphene oxide (GO) hybrid, a fairly-known composite, was made through a simple one-step procedure and played a highlighted role in the photo-induced oxidative functionalization of the benzylic C–H bond. To identify the given binary composite, various techniques were applied: FT-IR, P-XRD, SEM, nitrogen absorption–desorption analysis, TGA, TEM, and UV–Visible DRS spectra. Proportions of GO used within the structure of the prepared composite differently ranged from low to high amount, and the most optimized ratio met at 38.5% of GO as the most efficient catalyst. Additionally, the reaction ran in Glycerol/K2CO3 (2:1) as the optimal solvent. The elemental roles of O2 ·− and OH− were supposed to be the major ones for running a tandem oxidation-Knoevenagel reaction. The heterogeneity and reusability of the catalyst were also examined and confirmed after five successive runs.https://doi.org/10.1038/s41598-022-22369-9 |
| spellingShingle | Sepideh Abbasi Mohammad Reza Naimi-Jamal Shahrzad Javanshir Akbar Heydari Photocatalytic aerobic oxidative functionalization (PAOF) reaction of benzyl alcohols by GO-MIL-100(Fe) composite in glycerol/K2CO3 deep eutectic solvent Scientific Reports |
| title | Photocatalytic aerobic oxidative functionalization (PAOF) reaction of benzyl alcohols by GO-MIL-100(Fe) composite in glycerol/K2CO3 deep eutectic solvent |
| title_full | Photocatalytic aerobic oxidative functionalization (PAOF) reaction of benzyl alcohols by GO-MIL-100(Fe) composite in glycerol/K2CO3 deep eutectic solvent |
| title_fullStr | Photocatalytic aerobic oxidative functionalization (PAOF) reaction of benzyl alcohols by GO-MIL-100(Fe) composite in glycerol/K2CO3 deep eutectic solvent |
| title_full_unstemmed | Photocatalytic aerobic oxidative functionalization (PAOF) reaction of benzyl alcohols by GO-MIL-100(Fe) composite in glycerol/K2CO3 deep eutectic solvent |
| title_short | Photocatalytic aerobic oxidative functionalization (PAOF) reaction of benzyl alcohols by GO-MIL-100(Fe) composite in glycerol/K2CO3 deep eutectic solvent |
| title_sort | photocatalytic aerobic oxidative functionalization paof reaction of benzyl alcohols by go mil 100 fe composite in glycerol k2co3 deep eutectic solvent |
| url | https://doi.org/10.1038/s41598-022-22369-9 |
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