Cadmium telluride for high-efficiency solar cells

Problems of the synthesis of cadmium telluride powders having required purity and grain size distribution for high-efficiency solar cells have been analyzed. A test batch of powders has been synthesized and used for the manufacture and study of thin-film solar cell specimens exhibiting parameters co...

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Main Authors: Igor I. Maronchuk, Daria D. Sanikovich, Elena V. Davydova, Nataliya Yu. Tabachkova
Format: Article
Language:English
Published: Pensoft Publishers 2023-03-01
Series:Modern Electronic Materials
Online Access:https://moem.pensoft.net/article/103598/download/pdf/
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author Igor I. Maronchuk
Daria D. Sanikovich
Elena V. Davydova
Nataliya Yu. Tabachkova
author_facet Igor I. Maronchuk
Daria D. Sanikovich
Elena V. Davydova
Nataliya Yu. Tabachkova
author_sort Igor I. Maronchuk
collection DOAJ
description Problems of the synthesis of cadmium telluride powders having required purity and grain size distribution for high-efficiency solar cells have been analyzed. A test batch of powders has been synthesized and used for the manufacture and study of thin-film solar cell specimens exhibiting parameters compliant with the best worldwide standards. The phase composition of the powders has been studied using X-ray diffraction. Structural analysis and elemental composition measurements have been carried out using electron microscopy. The effect of free tellurium phase in the powders on the endurance of devices manufactured from the powder has been described. We show that excess tellurium in the film specimens whose atoms are predominantly localized along grain boundaries may cause temporal degradation of the electrical properties of the manufactured solar cells due to changes in the parameters of the crystalline structure of the cadmium telluride phase which are caused in turn by changes in the stoichiometric composition of the material. Structural studies of the film specimens have not revealed differences in the film structure before and after endurance tests. A new cadmium telluride powder process route has been developed, proven and tested taking into account the advantages and drawbacks of the previously used process and experiments confirming the correctness of the technical solutions chosen have been conducted.
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spelling doaj.art-c5dc9944b28d42d9804ed3d4d587527a2023-09-03T13:04:47ZengPensoft PublishersModern Electronic Materials2452-17792023-03-019191410.3897/j.moem.9.1.103598103598Cadmium telluride for high-efficiency solar cellsIgor I. Maronchuk0Daria D. Sanikovich1Elena V. Davydova2Nataliya Yu. Tabachkova3ADV-Engineering, LLCADV-Engineering, LLCADV-Engineering, LLCProkhorov General Physics Institute of the Russian Academy of SciencesProblems of the synthesis of cadmium telluride powders having required purity and grain size distribution for high-efficiency solar cells have been analyzed. A test batch of powders has been synthesized and used for the manufacture and study of thin-film solar cell specimens exhibiting parameters compliant with the best worldwide standards. The phase composition of the powders has been studied using X-ray diffraction. Structural analysis and elemental composition measurements have been carried out using electron microscopy. The effect of free tellurium phase in the powders on the endurance of devices manufactured from the powder has been described. We show that excess tellurium in the film specimens whose atoms are predominantly localized along grain boundaries may cause temporal degradation of the electrical properties of the manufactured solar cells due to changes in the parameters of the crystalline structure of the cadmium telluride phase which are caused in turn by changes in the stoichiometric composition of the material. Structural studies of the film specimens have not revealed differences in the film structure before and after endurance tests. A new cadmium telluride powder process route has been developed, proven and tested taking into account the advantages and drawbacks of the previously used process and experiments confirming the correctness of the technical solutions chosen have been conducted.https://moem.pensoft.net/article/103598/download/pdf/
spellingShingle Igor I. Maronchuk
Daria D. Sanikovich
Elena V. Davydova
Nataliya Yu. Tabachkova
Cadmium telluride for high-efficiency solar cells
Modern Electronic Materials
title Cadmium telluride for high-efficiency solar cells
title_full Cadmium telluride for high-efficiency solar cells
title_fullStr Cadmium telluride for high-efficiency solar cells
title_full_unstemmed Cadmium telluride for high-efficiency solar cells
title_short Cadmium telluride for high-efficiency solar cells
title_sort cadmium telluride for high efficiency solar cells
url https://moem.pensoft.net/article/103598/download/pdf/
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AT dariadsanikovich cadmiumtellurideforhighefficiencysolarcells
AT elenavdavydova cadmiumtellurideforhighefficiencysolarcells
AT nataliyayutabachkova cadmiumtellurideforhighefficiencysolarcells