Comparing the formation, properties and structure between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass and the predecessor Fe75Cr5P9B4C7 metallic glass
In present work, formation, properties and local structure features between novel Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass (HEMG) and the predecessor Fe75Cr5P9B4C7 metallic glass (MG) were thoroughly characterized by experiments and ab-initio molecular dynamics (AIMD) simulatio...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2023-09-01
|
| Series: | Journal of Materials Research and Technology |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2238785423023177 |
| _version_ | 1797646613875785728 |
|---|---|
| author | Tao Xu Xinchao Wang Yuxuan Tu Longchao Zhuo Zengyun Jian |
| author_facet | Tao Xu Xinchao Wang Yuxuan Tu Longchao Zhuo Zengyun Jian |
| author_sort | Tao Xu |
| collection | DOAJ |
| description | In present work, formation, properties and local structure features between novel Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass (HEMG) and the predecessor Fe75Cr5P9B4C7 metallic glass (MG) were thoroughly characterized by experiments and ab-initio molecular dynamics (AIMD) simulation. Compared with predecessor MG, the HEMG possesses a higher thermal stability of supercooled liquid with wider supercooled liquid region of 57 K, superior corrosion resistance with higher corrosion potential, lower corrosion and passive current density along with wider passive region in 3 wt.% NaCl solution. Additionally, the HEMG possesses a paramagnetic feature with low magnetization of only 9.38 emu·g−1, while predecessor MG possesses a good soft-magnetic property with a high saturation magnetization of 115.16 emu·g−1. The corresponding local structure differences deriving from AIMD simulation exhibit that the HEMG possesses a higher content of icosahedra-like structures (with bond pair indexes (BPIs) of 1551, 1541 and 1431) and Voronoi polyhedra (VPs) with relative smaller coordination numbers (8, 9, 11, 12 and 13), lower content of crystal-type structures (with BPIs of 1421, 1422, 1441 and 1661) and VPs with larger coordination numbers (15 and 16) compared with predecessor MG. These results show that the formation, properties and local structures can be visibly changed after present high-entropy alloying by similar solvent elements Co, Ni and Cr equiatomic substitution of Fe in predecessor MG. Additionally, both alloys possess dominant VPs with coordination numbers from 12 to 15 and good ductility without fracture as bent by 180°. |
| first_indexed | 2024-03-11T15:05:06Z |
| format | Article |
| id | doaj.art-c6138674b4794fb98648f5a2739c7209 |
| institution | Directory Open Access Journal |
| issn | 2238-7854 |
| language | English |
| last_indexed | 2024-03-11T15:05:06Z |
| publishDate | 2023-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Materials Research and Technology |
| spelling | doaj.art-c6138674b4794fb98648f5a2739c72092023-10-30T06:04:55ZengElsevierJournal of Materials Research and Technology2238-78542023-09-012682898297Comparing the formation, properties and structure between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass and the predecessor Fe75Cr5P9B4C7 metallic glassTao Xu0Xinchao Wang1Yuxuan Tu2Longchao Zhuo3Zengyun Jian4School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710021, Shaanxi, China; Corresponding author.Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, Beijing 100191, ChinaSchool of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710021, Shaanxi, ChinaSchool of Materials Science and Engineering, Xi'an University of Technology, Xi'an 710048, Shaanxi, China; Corresponding author.School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710021, Shaanxi, ChinaIn present work, formation, properties and local structure features between novel Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass (HEMG) and the predecessor Fe75Cr5P9B4C7 metallic glass (MG) were thoroughly characterized by experiments and ab-initio molecular dynamics (AIMD) simulation. Compared with predecessor MG, the HEMG possesses a higher thermal stability of supercooled liquid with wider supercooled liquid region of 57 K, superior corrosion resistance with higher corrosion potential, lower corrosion and passive current density along with wider passive region in 3 wt.% NaCl solution. Additionally, the HEMG possesses a paramagnetic feature with low magnetization of only 9.38 emu·g−1, while predecessor MG possesses a good soft-magnetic property with a high saturation magnetization of 115.16 emu·g−1. The corresponding local structure differences deriving from AIMD simulation exhibit that the HEMG possesses a higher content of icosahedra-like structures (with bond pair indexes (BPIs) of 1551, 1541 and 1431) and Voronoi polyhedra (VPs) with relative smaller coordination numbers (8, 9, 11, 12 and 13), lower content of crystal-type structures (with BPIs of 1421, 1422, 1441 and 1661) and VPs with larger coordination numbers (15 and 16) compared with predecessor MG. These results show that the formation, properties and local structures can be visibly changed after present high-entropy alloying by similar solvent elements Co, Ni and Cr equiatomic substitution of Fe in predecessor MG. Additionally, both alloys possess dominant VPs with coordination numbers from 12 to 15 and good ductility without fracture as bent by 180°.http://www.sciencedirect.com/science/article/pii/S2238785423023177High-entropyMetallic glassSimilar solvent element substitutionThermal propertiesCorrosionMolecular dynamics simulation |
| spellingShingle | Tao Xu Xinchao Wang Yuxuan Tu Longchao Zhuo Zengyun Jian Comparing the formation, properties and structure between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass and the predecessor Fe75Cr5P9B4C7 metallic glass Journal of Materials Research and Technology High-entropy Metallic glass Similar solvent element substitution Thermal properties Corrosion Molecular dynamics simulation |
| title | Comparing the formation, properties and structure between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass and the predecessor Fe75Cr5P9B4C7 metallic glass |
| title_full | Comparing the formation, properties and structure between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass and the predecessor Fe75Cr5P9B4C7 metallic glass |
| title_fullStr | Comparing the formation, properties and structure between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass and the predecessor Fe75Cr5P9B4C7 metallic glass |
| title_full_unstemmed | Comparing the formation, properties and structure between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass and the predecessor Fe75Cr5P9B4C7 metallic glass |
| title_short | Comparing the formation, properties and structure between Fe20Co20Ni20Cr20(P0.45B0.2C0.35)20 high-entropy metallic glass and the predecessor Fe75Cr5P9B4C7 metallic glass |
| title_sort | comparing the formation properties and structure between fe20co20ni20cr20 p0 45b0 2c0 35 20 high entropy metallic glass and the predecessor fe75cr5p9b4c7 metallic glass |
| topic | High-entropy Metallic glass Similar solvent element substitution Thermal properties Corrosion Molecular dynamics simulation |
| url | http://www.sciencedirect.com/science/article/pii/S2238785423023177 |
| work_keys_str_mv | AT taoxu comparingtheformationpropertiesandstructurebetweenfe20co20ni20cr20p045b02c03520highentropymetallicglassandthepredecessorfe75cr5p9b4c7metallicglass AT xinchaowang comparingtheformationpropertiesandstructurebetweenfe20co20ni20cr20p045b02c03520highentropymetallicglassandthepredecessorfe75cr5p9b4c7metallicglass AT yuxuantu comparingtheformationpropertiesandstructurebetweenfe20co20ni20cr20p045b02c03520highentropymetallicglassandthepredecessorfe75cr5p9b4c7metallicglass AT longchaozhuo comparingtheformationpropertiesandstructurebetweenfe20co20ni20cr20p045b02c03520highentropymetallicglassandthepredecessorfe75cr5p9b4c7metallicglass AT zengyunjian comparingtheformationpropertiesandstructurebetweenfe20co20ni20cr20p045b02c03520highentropymetallicglassandthepredecessorfe75cr5p9b4c7metallicglass |