A One-Dimensional Cu(I) Coordination Polymer with Optical Sensing of Oxygen and Temperature

Due to their tight structures, it is usually difficult for one-dimensional (1D) coordination polymers (CPs) to form permanent pores unless 2D and 3D topologies are formed via supramolecular interactions, so studies in the field of oxygen sensing on 1D CPs are rarely reported. Here, we report a 1D Cu...

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Main Authors: Wan-Tao Chen, Chen-Hui Li, Wan-Qing Zhou, Jing-Tao Huang, Jia-Wen Ye, Ling Chen
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Inorganics
Subjects:
Online Access:https://www.mdpi.com/2304-6740/10/12/253
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author Wan-Tao Chen
Chen-Hui Li
Wan-Qing Zhou
Jing-Tao Huang
Jia-Wen Ye
Ling Chen
author_facet Wan-Tao Chen
Chen-Hui Li
Wan-Qing Zhou
Jing-Tao Huang
Jia-Wen Ye
Ling Chen
author_sort Wan-Tao Chen
collection DOAJ
description Due to their tight structures, it is usually difficult for one-dimensional (1D) coordination polymers (CPs) to form permanent pores unless 2D and 3D topologies are formed via supramolecular interactions, so studies in the field of oxygen sensing on 1D CPs are rarely reported. Here, we report a 1D Cu(I) cluster-based CP with dual sensing characteristics for temperature and oxygen. Even if the porosity is only 6.6%, the quenching rate of this CP reaches 98.4% with 1 bar O<sub>2</sub> at room temperature. Its luminescence intensity exhibits a unique thermal “quenching, then activating” behavior during monotonic variations in temperature.
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spelling doaj.art-c628d386c9ec47588ae859cbd1e58a822023-11-24T15:38:31ZengMDPI AGInorganics2304-67402022-12-01101225310.3390/inorganics10120253A One-Dimensional Cu(I) Coordination Polymer with Optical Sensing of Oxygen and TemperatureWan-Tao Chen0Chen-Hui Li1Wan-Qing Zhou2Jing-Tao Huang3Jia-Wen Ye4Ling Chen5School of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529000, ChinaSchool of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529000, ChinaSchool of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529000, ChinaSchool of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529000, ChinaSchool of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529000, ChinaSchool of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529000, ChinaDue to their tight structures, it is usually difficult for one-dimensional (1D) coordination polymers (CPs) to form permanent pores unless 2D and 3D topologies are formed via supramolecular interactions, so studies in the field of oxygen sensing on 1D CPs are rarely reported. Here, we report a 1D Cu(I) cluster-based CP with dual sensing characteristics for temperature and oxygen. Even if the porosity is only 6.6%, the quenching rate of this CP reaches 98.4% with 1 bar O<sub>2</sub> at room temperature. Its luminescence intensity exhibits a unique thermal “quenching, then activating” behavior during monotonic variations in temperature.https://www.mdpi.com/2304-6740/10/12/253coordination polymerluminescent thermometeroptical oxygen sensing
spellingShingle Wan-Tao Chen
Chen-Hui Li
Wan-Qing Zhou
Jing-Tao Huang
Jia-Wen Ye
Ling Chen
A One-Dimensional Cu(I) Coordination Polymer with Optical Sensing of Oxygen and Temperature
Inorganics
coordination polymer
luminescent thermometer
optical oxygen sensing
title A One-Dimensional Cu(I) Coordination Polymer with Optical Sensing of Oxygen and Temperature
title_full A One-Dimensional Cu(I) Coordination Polymer with Optical Sensing of Oxygen and Temperature
title_fullStr A One-Dimensional Cu(I) Coordination Polymer with Optical Sensing of Oxygen and Temperature
title_full_unstemmed A One-Dimensional Cu(I) Coordination Polymer with Optical Sensing of Oxygen and Temperature
title_short A One-Dimensional Cu(I) Coordination Polymer with Optical Sensing of Oxygen and Temperature
title_sort one dimensional cu i coordination polymer with optical sensing of oxygen and temperature
topic coordination polymer
luminescent thermometer
optical oxygen sensing
url https://www.mdpi.com/2304-6740/10/12/253
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