The physics of photon induced degradation of perovskite solar cells

Lead-trihalide perovskite solar cells are an important photovoltaic technology. We investigate the effect of light induced degradation on perovskite solar cells. During exposure, the open-circuit voltage (Voc) of the device increases, whereas the short-circuit current (Isc) shows a decrease. The deg...

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Main Authors: Pranav H. Joshi, Liang Zhang, Istiaque M. Hossain, Hisham A. Abbas, Ranjith Kottokkaran, Satyapal P. Nehra, Mahendra Dhaka, Max Noack, Vikram L. Dalal
Format: Article
Language:English
Published: AIP Publishing LLC 2016-11-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.4967817
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author Pranav H. Joshi
Liang Zhang
Istiaque M. Hossain
Hisham A. Abbas
Ranjith Kottokkaran
Satyapal P. Nehra
Mahendra Dhaka
Max Noack
Vikram L. Dalal
author_facet Pranav H. Joshi
Liang Zhang
Istiaque M. Hossain
Hisham A. Abbas
Ranjith Kottokkaran
Satyapal P. Nehra
Mahendra Dhaka
Max Noack
Vikram L. Dalal
author_sort Pranav H. Joshi
collection DOAJ
description Lead-trihalide perovskite solar cells are an important photovoltaic technology. We investigate the effect of light induced degradation on perovskite solar cells. During exposure, the open-circuit voltage (Voc) of the device increases, whereas the short-circuit current (Isc) shows a decrease. The degradation can be completely recovered using thermal annealing in dark. We develop a model based on light induced generation of ions and migration of these ions inside the material to explain the changes in Isc, Voc, capacitance and dark current upon light exposure and post-exposure recovery. There was no change in defect density in the material upon exposure.
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spelling doaj.art-c628dffc4237431fb08920ceac91ea6a2022-12-21T19:48:10ZengAIP Publishing LLCAIP Advances2158-32262016-11-01611115114115114-610.1063/1.4967817052611ADVThe physics of photon induced degradation of perovskite solar cellsPranav H. Joshi0Liang Zhang1Istiaque M. Hossain2Hisham A. Abbas3Ranjith Kottokkaran4Satyapal P. Nehra5Mahendra Dhaka6Max Noack7Vikram L. Dalal8Department of Electrical and Computer Engineering, Iowa State University, Ames, Iowa 50011, USADepartment of Electrical and Computer Engineering, Iowa State University, Ames, Iowa 50011, USADepartment of Electrical and Computer Engineering, Iowa State University, Ames, Iowa 50011, USADepartment of Electrical and Computer Engineering, Iowa State University, Ames, Iowa 50011, USADepartment of Electrical and Computer Engineering, Iowa State University, Ames, Iowa 50011, USAMicroelectronics Research Center, Iowa State University, Ames, Iowa 50011, USAMicroelectronics Research Center, Iowa State University, Ames, Iowa 50011, USAMicroelectronics Research Center, Iowa State University, Ames, Iowa 50011, USADepartment of Electrical and Computer Engineering, Iowa State University, Ames, Iowa 50011, USALead-trihalide perovskite solar cells are an important photovoltaic technology. We investigate the effect of light induced degradation on perovskite solar cells. During exposure, the open-circuit voltage (Voc) of the device increases, whereas the short-circuit current (Isc) shows a decrease. The degradation can be completely recovered using thermal annealing in dark. We develop a model based on light induced generation of ions and migration of these ions inside the material to explain the changes in Isc, Voc, capacitance and dark current upon light exposure and post-exposure recovery. There was no change in defect density in the material upon exposure.http://dx.doi.org/10.1063/1.4967817
spellingShingle Pranav H. Joshi
Liang Zhang
Istiaque M. Hossain
Hisham A. Abbas
Ranjith Kottokkaran
Satyapal P. Nehra
Mahendra Dhaka
Max Noack
Vikram L. Dalal
The physics of photon induced degradation of perovskite solar cells
AIP Advances
title The physics of photon induced degradation of perovskite solar cells
title_full The physics of photon induced degradation of perovskite solar cells
title_fullStr The physics of photon induced degradation of perovskite solar cells
title_full_unstemmed The physics of photon induced degradation of perovskite solar cells
title_short The physics of photon induced degradation of perovskite solar cells
title_sort physics of photon induced degradation of perovskite solar cells
url http://dx.doi.org/10.1063/1.4967817
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