Bis[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]bis(μ4-diphenylphosphinato-κ4O:O:O′:O′)bis(μ2-trifluoroacetato-κ2O:O′)tetrasilver(I) acetonitrile disolvate
In the cation of the title compound, [Ag4(C2F3O2)2(C12H10O2P)2(C25H22P2)2]·2CH3CN, the two independent Ag+ cations are four-coordinated in a distorted tetrahedral geometry by one P atom from a bis(diphenylphosphanyl)methane (dppm) ligand, one O atom from a trifluoroacetate anion and two...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811045466 |
| _version_ | 1819289292987432960 |
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| author | Li-Li Huang Chen Jia Li-Ping Tang Bai Jing Qi-Hua Deng |
| author_facet | Li-Li Huang Chen Jia Li-Ping Tang Bai Jing Qi-Hua Deng |
| author_sort | Li-Li Huang |
| collection | DOAJ |
| description | In the cation of the title compound, [Ag4(C2F3O2)2(C12H10O2P)2(C25H22P2)2]·2CH3CN, the two independent Ag+ cations are four-coordinated in a distorted tetrahedral geometry by one P atom from a bis(diphenylphosphanyl)methane (dppm) ligand, one O atom from a trifluoroacetate anion and two O atoms from two diphenylphosphinate (dpp) ligands. Two dppm ligands, two dpp ligands and two trifluoroacetate anions bridge four metal atoms, forming a centrosymmetric tetranuclear complex. Intramolecular C—H...O hydrogen bonds and a weak π–π interaction [centroid–centroid distance = 3.9804 (13) Å] are also observed. |
| first_indexed | 2024-12-24T03:04:32Z |
| format | Article |
| id | doaj.art-c637b62be3bf43c1a97fa91f36fceef6 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:04:32Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c637b62be3bf43c1a97fa91f36fceef62022-12-21T17:18:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1677m167810.1107/S1600536811045466Bis[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]bis(μ4-diphenylphosphinato-κ4O:O:O′:O′)bis(μ2-trifluoroacetato-κ2O:O′)tetrasilver(I) acetonitrile disolvateLi-Li HuangChen JiaLi-Ping TangBai JingQi-Hua DengIn the cation of the title compound, [Ag4(C2F3O2)2(C12H10O2P)2(C25H22P2)2]·2CH3CN, the two independent Ag+ cations are four-coordinated in a distorted tetrahedral geometry by one P atom from a bis(diphenylphosphanyl)methane (dppm) ligand, one O atom from a trifluoroacetate anion and two O atoms from two diphenylphosphinate (dpp) ligands. Two dppm ligands, two dpp ligands and two trifluoroacetate anions bridge four metal atoms, forming a centrosymmetric tetranuclear complex. Intramolecular C—H...O hydrogen bonds and a weak π–π interaction [centroid–centroid distance = 3.9804 (13) Å] are also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536811045466 |
| spellingShingle | Li-Li Huang Chen Jia Li-Ping Tang Bai Jing Qi-Hua Deng Bis[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]bis(μ4-diphenylphosphinato-κ4O:O:O′:O′)bis(μ2-trifluoroacetato-κ2O:O′)tetrasilver(I) acetonitrile disolvate Acta Crystallographica Section E |
| title | Bis[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]bis(μ4-diphenylphosphinato-κ4O:O:O′:O′)bis(μ2-trifluoroacetato-κ2O:O′)tetrasilver(I) acetonitrile disolvate |
| title_full | Bis[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]bis(μ4-diphenylphosphinato-κ4O:O:O′:O′)bis(μ2-trifluoroacetato-κ2O:O′)tetrasilver(I) acetonitrile disolvate |
| title_fullStr | Bis[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]bis(μ4-diphenylphosphinato-κ4O:O:O′:O′)bis(μ2-trifluoroacetato-κ2O:O′)tetrasilver(I) acetonitrile disolvate |
| title_full_unstemmed | Bis[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]bis(μ4-diphenylphosphinato-κ4O:O:O′:O′)bis(μ2-trifluoroacetato-κ2O:O′)tetrasilver(I) acetonitrile disolvate |
| title_short | Bis[μ2-bis(diphenylphosphanyl)methane-κ2P:P′]bis(μ4-diphenylphosphinato-κ4O:O:O′:O′)bis(μ2-trifluoroacetato-κ2O:O′)tetrasilver(I) acetonitrile disolvate |
| title_sort | bis amp 956 2 bis diphenylphosphanyl methane amp 954 2p p amp 8242 bis amp 956 4 diphenylphosphinato amp 954 4o o o amp 8242 o amp 8242 bis amp 956 2 trifluoroacetato amp 954 2o o amp 8242 tetrasilver i acetonitrile disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811045466 |
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