Synthesis and Structure of Hexatungstochromate(III), [H3CrIIIW6O24]6–
The hexatungstochromate(III) [H3CrIIIW6O24]6- (1) was synthesized in aqueous, basic medium by simple reaction of chromium(III) nitrate nonahydrate and sodium tungstate dihydrate in a 1:6 ratio. Polyanion 1 represents the first Anderson-Evans type heteropolytungstate with a trivalent hetero...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
2015-09-01
|
| Series: | CHIMIA |
| Subjects: | |
| Online Access: | https://www.chimia.ch/chimia/article/view/5795 |
| _version_ | 1819278346195828736 |
|---|---|
| author | Wenjing Liu Zhengguo Lin Bassem S. Bassil Rami Al-Oweini Ulrich Kortz |
| author_facet | Wenjing Liu Zhengguo Lin Bassem S. Bassil Rami Al-Oweini Ulrich Kortz |
| author_sort | Wenjing Liu |
| collection | DOAJ |
| description |
The hexatungstochromate(III) [H3CrIIIW6O24]6- (1) was synthesized in aqueous, basic medium by simple reaction of chromium(III) nitrate nonahydrate and sodium tungstate dihydrate in a 1:6 ratio. Polyanion 1 represents
the first Anderson-Evans type heteropolytungstate with a trivalent hetero element. The sodium salt of 1 with the formula Na6[H3CrIIIW6O24]·22H2O (1a) was fully characterized in the solid state by single crystal XRD, FT-IR spectroscopy, and thermogravimetric analysis.
|
| first_indexed | 2024-12-24T00:10:33Z |
| format | Article |
| id | doaj.art-c63fc0430a5a4a60838982a73ae33c71 |
| institution | Directory Open Access Journal |
| issn | 0009-4293 2673-2424 |
| language | deu |
| last_indexed | 2024-12-24T00:10:33Z |
| publishDate | 2015-09-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj.art-c63fc0430a5a4a60838982a73ae33c712022-12-21T17:24:54ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242015-09-0169910.2533/chimia.2015.537Synthesis and Structure of Hexatungstochromate(III), [H3CrIIIW6O24]6–Wenjing Liu0Zhengguo Lin1Bassem S. Bassil2Rami Al-Oweini3Ulrich Kortz4Department of Life Sciences and Chemistry Jacobs University P.O. Box 750561 28725 Bremen, GermanyDepartment of Life Sciences and Chemistry Jacobs University P.O. Box 750561 28725 Bremen, GermanyDepartment of Life Sciences and Chemistry Jacobs University P.O. Box 750561 28725 Bremen, Germany; Department of Chemistry, Faculty of Sciences University of Balamand, P.O. Box 100, Tripoli, LebanonDepartment of Life Sciences and Chemistry Jacobs University P.O. Box 750561 28725 Bremen, Germany, Department of Chemistry Faculty of Science, Beirut Arab University P.O. Box 11 50 20, Riad El Solh 1107 2809 Beirut, LebanonDepartment of Life Sciences and Chemistry Jacobs University P.O. Box 750561 28725 Bremen, Germany. u.kortz@jacobs-university.de The hexatungstochromate(III) [H3CrIIIW6O24]6- (1) was synthesized in aqueous, basic medium by simple reaction of chromium(III) nitrate nonahydrate and sodium tungstate dihydrate in a 1:6 ratio. Polyanion 1 represents the first Anderson-Evans type heteropolytungstate with a trivalent hetero element. The sodium salt of 1 with the formula Na6[H3CrIIIW6O24]·22H2O (1a) was fully characterized in the solid state by single crystal XRD, FT-IR spectroscopy, and thermogravimetric analysis. https://www.chimia.ch/chimia/article/view/5795Anderson-evans structureChromiumPolyoxometalatesXrd |
| spellingShingle | Wenjing Liu Zhengguo Lin Bassem S. Bassil Rami Al-Oweini Ulrich Kortz Synthesis and Structure of Hexatungstochromate(III), [H3CrIIIW6O24]6– CHIMIA Anderson-evans structure Chromium Polyoxometalates Xrd |
| title | Synthesis and Structure of Hexatungstochromate(III), [H3CrIIIW6O24]6– |
| title_full | Synthesis and Structure of Hexatungstochromate(III), [H3CrIIIW6O24]6– |
| title_fullStr | Synthesis and Structure of Hexatungstochromate(III), [H3CrIIIW6O24]6– |
| title_full_unstemmed | Synthesis and Structure of Hexatungstochromate(III), [H3CrIIIW6O24]6– |
| title_short | Synthesis and Structure of Hexatungstochromate(III), [H3CrIIIW6O24]6– |
| title_sort | synthesis and structure of hexatungstochromate iii h3criiiw6o24 6 |
| topic | Anderson-evans structure Chromium Polyoxometalates Xrd |
| url | https://www.chimia.ch/chimia/article/view/5795 |
| work_keys_str_mv | AT wenjingliu synthesisandstructureofhexatungstochromateiiih3criiiw6o246 AT zhengguolin synthesisandstructureofhexatungstochromateiiih3criiiw6o246 AT bassemsbassil synthesisandstructureofhexatungstochromateiiih3criiiw6o246 AT ramialoweini synthesisandstructureofhexatungstochromateiiih3criiiw6o246 AT ulrichkortz synthesisandstructureofhexatungstochromateiiih3criiiw6o246 |