Thermodynamic properties of the GdTe3 compound
The alloys of the Gd-Te system in the range of compositions > 75 at% Te were studied by the methods of X-ray diffraction (XRD) and electromotive forces (EMF). From the EMF measurements of the concentration cells relative to the GdTe electrode in the 300-450 K temperature range, the partial therm...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Vasyl Stefanyk Precarpathian National University
2021-07-01
|
| Series: | Фізика і хімія твердого тіла |
| Subjects: | |
| Online Access: | https://journals.pnu.edu.ua/index.php/pcss/article/view/5023 |
| _version_ | 1798022604441780224 |
|---|---|
| author | Samira Imamaliyeva |
| author_facet | Samira Imamaliyeva |
| author_sort | Samira Imamaliyeva |
| collection | DOAJ |
| description | The alloys of the Gd-Te system in the range of compositions > 75 at% Te were studied by the methods of
X-ray diffraction (XRD) and electromotive forces (EMF). From the EMF measurements of the concentration cells relative to the GdTe electrode in the 300-450 K temperature range, the partial thermodynamic functions of GdTe in alloys were determined. By combining these data with the corresponding functions of Gd in GdTe, the partial molar functions of gadolinium in GdTe3+Te alloys, and standard thermodynamic functions of formation and standard entropy of the GdTe3 compound were calculated. The obtained results were compared with the literature data. |
| first_indexed | 2024-04-11T17:32:39Z |
| format | Article |
| id | doaj.art-c647714d67744a0aaafdec27163a5b20 |
| institution | Directory Open Access Journal |
| issn | 1729-4428 2309-8589 |
| language | English |
| last_indexed | 2024-04-11T17:32:39Z |
| publishDate | 2021-07-01 |
| publisher | Vasyl Stefanyk Precarpathian National University |
| record_format | Article |
| series | Фізика і хімія твердого тіла |
| spelling | doaj.art-c647714d67744a0aaafdec27163a5b202022-12-22T04:11:58ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892021-07-0122342042510.15330/pcss.22.3.420-4255023Thermodynamic properties of the GdTe3 compoundSamira Imamaliyeva0Institute of Catalysis and Inorganic Chemistry named after acad. M. NagiyevThe alloys of the Gd-Te system in the range of compositions > 75 at% Te were studied by the methods of X-ray diffraction (XRD) and electromotive forces (EMF). From the EMF measurements of the concentration cells relative to the GdTe electrode in the 300-450 K temperature range, the partial thermodynamic functions of GdTe in alloys were determined. By combining these data with the corresponding functions of Gd in GdTe, the partial molar functions of gadolinium in GdTe3+Te alloys, and standard thermodynamic functions of formation and standard entropy of the GdTe3 compound were calculated. The obtained results were compared with the literature data.https://journals.pnu.edu.ua/index.php/pcss/article/view/5023gadolinium telluridesemf methodconcentration cellspartial molar functionsthermodynamic functions |
| spellingShingle | Samira Imamaliyeva Thermodynamic properties of the GdTe3 compound Фізика і хімія твердого тіла gadolinium tellurides emf method concentration cells partial molar functions thermodynamic functions |
| title | Thermodynamic properties of the GdTe3 compound |
| title_full | Thermodynamic properties of the GdTe3 compound |
| title_fullStr | Thermodynamic properties of the GdTe3 compound |
| title_full_unstemmed | Thermodynamic properties of the GdTe3 compound |
| title_short | Thermodynamic properties of the GdTe3 compound |
| title_sort | thermodynamic properties of the gdte3 compound |
| topic | gadolinium tellurides emf method concentration cells partial molar functions thermodynamic functions |
| url | https://journals.pnu.edu.ua/index.php/pcss/article/view/5023 |
| work_keys_str_mv | AT samiraimamaliyeva thermodynamicpropertiesofthegdte3compound |