Tailoring Mechanical and Magnetic Properties in Dual-Phase FeCoNi(CuAl)<sub>0.8</sub> High-Entropy Alloy

For tailoring the mechanical and magnetic properties of dual-phase high-entropy alloys (HEAs), it is crucial to understand the effect of each phase on the overall properties. In this paper, the effects of individual FCC and BCC phases on the mechanical and magnetic properties of the FeCoNi(CuAl)<...

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Main Authors: Xiaohua Tan, Lingmiao Chen, Mengxin Lv, Wenfeng Peng, Hui Xu
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/22/7222
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author Xiaohua Tan
Lingmiao Chen
Mengxin Lv
Wenfeng Peng
Hui Xu
author_facet Xiaohua Tan
Lingmiao Chen
Mengxin Lv
Wenfeng Peng
Hui Xu
author_sort Xiaohua Tan
collection DOAJ
description For tailoring the mechanical and magnetic properties of dual-phase high-entropy alloys (HEAs), it is crucial to understand the effect of each phase on the overall properties. In this paper, the effects of individual FCC and BCC phases on the mechanical and magnetic properties of the FeCoNi(CuAl)<sub>0.8</sub> HEA are investigated by nanoindentation and first-principles calculations. The nano-hardness of the BCC phase is 8.73 GPa, which is nearly double the 4.60 GPa of the FCC phase, which ascribes to spherical nanoprecipitates that are only observed in the BCC phase leading to precipitation hardening. First-principles calculations on the electronic structure show that calculated saturation magnetization (M<sub>s</sub>) of the BCC phase is 0.81 T, higher than 0.77 T of the FCC phase. An approximate yield strength and M<sub>s</sub> can be estimated by summing the volume-fraction-weighted contributions from each phase, and are in good agreement with experimental values. It indicates that the overall mechanical and magnetic properties of the dual-phase HEAs can be tailored by tuning the volume fraction of the individual phase. Our findings are helpful to design prospective dual-phase HEAs with both good mechanical properties and soft magnetic performance by adjusting the content of each phase.
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spelling doaj.art-c64c694d4a49449d9cdc9fc812294cd32023-11-24T14:53:53ZengMDPI AGMaterials1996-19442023-11-011622722210.3390/ma16227222Tailoring Mechanical and Magnetic Properties in Dual-Phase FeCoNi(CuAl)<sub>0.8</sub> High-Entropy AlloyXiaohua Tan0Lingmiao Chen1Mengxin Lv2Wenfeng Peng3Hui Xu4Institute of Materials, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaInstitute of Materials, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaInstitute of Materials, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaInstitute of Materials, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaInstitute of Materials, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaFor tailoring the mechanical and magnetic properties of dual-phase high-entropy alloys (HEAs), it is crucial to understand the effect of each phase on the overall properties. In this paper, the effects of individual FCC and BCC phases on the mechanical and magnetic properties of the FeCoNi(CuAl)<sub>0.8</sub> HEA are investigated by nanoindentation and first-principles calculations. The nano-hardness of the BCC phase is 8.73 GPa, which is nearly double the 4.60 GPa of the FCC phase, which ascribes to spherical nanoprecipitates that are only observed in the BCC phase leading to precipitation hardening. First-principles calculations on the electronic structure show that calculated saturation magnetization (M<sub>s</sub>) of the BCC phase is 0.81 T, higher than 0.77 T of the FCC phase. An approximate yield strength and M<sub>s</sub> can be estimated by summing the volume-fraction-weighted contributions from each phase, and are in good agreement with experimental values. It indicates that the overall mechanical and magnetic properties of the dual-phase HEAs can be tailored by tuning the volume fraction of the individual phase. Our findings are helpful to design prospective dual-phase HEAs with both good mechanical properties and soft magnetic performance by adjusting the content of each phase.https://www.mdpi.com/1996-1944/16/22/7222dual-phase high-entropy alloynanoindentationmagnetic propertymechanical propertyfirst-principles calculations
spellingShingle Xiaohua Tan
Lingmiao Chen
Mengxin Lv
Wenfeng Peng
Hui Xu
Tailoring Mechanical and Magnetic Properties in Dual-Phase FeCoNi(CuAl)<sub>0.8</sub> High-Entropy Alloy
Materials
dual-phase high-entropy alloy
nanoindentation
magnetic property
mechanical property
first-principles calculations
title Tailoring Mechanical and Magnetic Properties in Dual-Phase FeCoNi(CuAl)<sub>0.8</sub> High-Entropy Alloy
title_full Tailoring Mechanical and Magnetic Properties in Dual-Phase FeCoNi(CuAl)<sub>0.8</sub> High-Entropy Alloy
title_fullStr Tailoring Mechanical and Magnetic Properties in Dual-Phase FeCoNi(CuAl)<sub>0.8</sub> High-Entropy Alloy
title_full_unstemmed Tailoring Mechanical and Magnetic Properties in Dual-Phase FeCoNi(CuAl)<sub>0.8</sub> High-Entropy Alloy
title_short Tailoring Mechanical and Magnetic Properties in Dual-Phase FeCoNi(CuAl)<sub>0.8</sub> High-Entropy Alloy
title_sort tailoring mechanical and magnetic properties in dual phase feconi cual sub 0 8 sub high entropy alloy
topic dual-phase high-entropy alloy
nanoindentation
magnetic property
mechanical property
first-principles calculations
url https://www.mdpi.com/1996-1944/16/22/7222
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