4-[(2-Hydroxy-5-nitrobenzylidene)amino]benzenesulfonamide
The title Schiff base compound, C13H11N3O5S, exists in an E configuration with respect to the C=N double bond. The benzene rings are almost coplanar, making a dihedral angle of 2.82 (6). The sulfonamide group is twisted away from the attached phenyl ring with an N—S&a...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810036949 |
| _version_ | 1818284936891727872 |
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| author | Hoong-Kun Fun Wan-Sin Loh Siang Guan Teoh Yi-Han Tan |
| author_facet | Hoong-Kun Fun Wan-Sin Loh Siang Guan Teoh Yi-Han Tan |
| author_sort | Hoong-Kun Fun |
| collection | DOAJ |
| description | The title Schiff base compound, C13H11N3O5S, exists in an E configuration with respect to the C=N double bond. The benzene rings are almost coplanar, making a dihedral angle of 2.82 (6). The sulfonamide group is twisted away from the attached phenyl ring with an N—S—C—C torsion angle of 64.84 (11)°. An intramolecular O—H...N hydrogen bond stabilizes the molecule, generating an S(6) ring motif. In the crystal, intermolecular N—H...O and C—H...O hydrogen bonds link the molecules into a three-dimensional network. |
| first_indexed | 2024-12-13T01:00:44Z |
| format | Article |
| id | doaj.art-c662a38b5e1a4cb294e111b700853876 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:00:44Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c662a38b5e1a4cb294e111b7008538762022-12-22T00:04:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610o2610o261110.1107/S16005368100369494-[(2-Hydroxy-5-nitrobenzylidene)amino]benzenesulfonamideHoong-Kun FunWan-Sin LohSiang Guan TeohYi-Han TanThe title Schiff base compound, C13H11N3O5S, exists in an E configuration with respect to the C=N double bond. The benzene rings are almost coplanar, making a dihedral angle of 2.82 (6). The sulfonamide group is twisted away from the attached phenyl ring with an N—S—C—C torsion angle of 64.84 (11)°. An intramolecular O—H...N hydrogen bond stabilizes the molecule, generating an S(6) ring motif. In the crystal, intermolecular N—H...O and C—H...O hydrogen bonds link the molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536810036949 |
| spellingShingle | Hoong-Kun Fun Wan-Sin Loh Siang Guan Teoh Yi-Han Tan 4-[(2-Hydroxy-5-nitrobenzylidene)amino]benzenesulfonamide Acta Crystallographica Section E |
| title | 4-[(2-Hydroxy-5-nitrobenzylidene)amino]benzenesulfonamide |
| title_full | 4-[(2-Hydroxy-5-nitrobenzylidene)amino]benzenesulfonamide |
| title_fullStr | 4-[(2-Hydroxy-5-nitrobenzylidene)amino]benzenesulfonamide |
| title_full_unstemmed | 4-[(2-Hydroxy-5-nitrobenzylidene)amino]benzenesulfonamide |
| title_short | 4-[(2-Hydroxy-5-nitrobenzylidene)amino]benzenesulfonamide |
| title_sort | 4 2 hydroxy 5 nitrobenzylidene amino benzenesulfonamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810036949 |
| work_keys_str_mv | AT hoongkunfun 42hydroxy5nitrobenzylideneaminobenzenesulfonamide AT wansinloh 42hydroxy5nitrobenzylideneaminobenzenesulfonamide AT siangguanteoh 42hydroxy5nitrobenzylideneaminobenzenesulfonamide AT yihantan 42hydroxy5nitrobenzylideneaminobenzenesulfonamide |