Coordination Chemistry of Polynitriles, Part XII—Serendipitous Synthesis of the Octacyanofulvalenediide Dianion and Study of Its Coordination Chemistry with K<sup>+</sup> and Ag<sup>+</sup>

Coordination Chemistry of Polynitriles, Part XII—Serendipitous Synthesis of the Octacyanofulvalenediide Dianion and Study of Its Coordination Chemistry with K<sup>+</sup> and Ag<sup>+</sup>

The reaction of diazotetracyanocyclopentadiene with copper powder in the presence of NEt<sub>4</sub>Cl yields, unexpectedly, besides the known NEt<sub>4</sub>[C<sub>5</sub>H(CN)<sub>4</sub>] (3), the NEt<sub>4</sub> salt of octacyanofulvale...

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Bibliographic Details
Main Authors: Patrick Nimax, Yannick Kunzelmann, Karlheinz Sünkel
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Inorganics
Subjects:
diazotetracyanocyclopentadiene
octacyanofulvalenediide
radical chemistry
coordination polymers
Online Access:https://www.mdpi.com/2304-6740/11/2/71

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