Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone
Research into the solvent extraction of iron(III) from a chloride solution after bauxite HCl leaching by neutral oxygen-containing extractants and their mixtures were studied and the iron(III) extraction degree from chloride solutions using alcohols is presented. The effect of dilution of alcohol wi...
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MDPI AG
2021-02-01
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| Online Access: | https://www.mdpi.com/2075-4701/11/2/321 |
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| author | Artem Sokolov Dmitry Valeev Aleksandr Kasikov |
| author_facet | Artem Sokolov Dmitry Valeev Aleksandr Kasikov |
| author_sort | Artem Sokolov |
| collection | DOAJ |
| description | Research into the solvent extraction of iron(III) from a chloride solution after bauxite HCl leaching by neutral oxygen-containing extractants and their mixtures were studied and the iron(III) extraction degree from chloride solutions using alcohols is presented. The effect of dilution of alcohol with a ketone by an extraction mixture in relation to its effectiveness was investigated. The iron(III) was efficiently extracted by the mixture of 1-octanol and 1-decanol (70%) with 2-undecanone (30%) from hydrochloric bauxite leach liquor at an O:A ratio = 2-4:1 at an iron(III) concentration of 7.4 g/L and 6 M HCl. For the removal of iron-containing organic phase from impurities (Al, Ca, Cr) that are co-extracted with iron(III), we used two step scrubbing at O:A = 5:1 by 7 M HCl as a scrub solution. The iron(III) stripping at the O:A ratio is shown. Using counter-current cascade of extractors, it was possible to obtain an FeCl<sub>3</sub> solution with the iron(III) content of 90.5 g/L and total impurities less than 50 mg/L. |
| first_indexed | 2024-03-09T00:56:00Z |
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| institution | Directory Open Access Journal |
| issn | 2075-4701 |
| language | English |
| last_indexed | 2024-03-09T00:56:00Z |
| publishDate | 2021-02-01 |
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| spelling | doaj.art-c6834ae2205440d2aca8d0f0f413226a2023-12-11T16:54:29ZengMDPI AGMetals2075-47012021-02-0111232110.3390/met11020321Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and KetoneArtem Sokolov0Dmitry Valeev1Aleksandr Kasikov2Laboratory for the Development and Implementation the Chemical Technology Processes, Tananaev Institute of Chemistry—Subdivision of the Federal Research Centre, Kola Science Centre of the Russian Academy of Sciences, 184209 Apatity, RussiaLaboratory of Sorption Methods, Vernadsky Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Sciences, 119334 Moscow, RussiaLaboratory for the Development and Implementation the Chemical Technology Processes, Tananaev Institute of Chemistry—Subdivision of the Federal Research Centre, Kola Science Centre of the Russian Academy of Sciences, 184209 Apatity, RussiaResearch into the solvent extraction of iron(III) from a chloride solution after bauxite HCl leaching by neutral oxygen-containing extractants and their mixtures were studied and the iron(III) extraction degree from chloride solutions using alcohols is presented. The effect of dilution of alcohol with a ketone by an extraction mixture in relation to its effectiveness was investigated. The iron(III) was efficiently extracted by the mixture of 1-octanol and 1-decanol (70%) with 2-undecanone (30%) from hydrochloric bauxite leach liquor at an O:A ratio = 2-4:1 at an iron(III) concentration of 7.4 g/L and 6 M HCl. For the removal of iron-containing organic phase from impurities (Al, Ca, Cr) that are co-extracted with iron(III), we used two step scrubbing at O:A = 5:1 by 7 M HCl as a scrub solution. The iron(III) stripping at the O:A ratio is shown. Using counter-current cascade of extractors, it was possible to obtain an FeCl<sub>3</sub> solution with the iron(III) content of 90.5 g/L and total impurities less than 50 mg/L.https://www.mdpi.com/2075-4701/11/2/321solvent extractionbauxiteironaluminumchloride solutionalcohol |
| spellingShingle | Artem Sokolov Dmitry Valeev Aleksandr Kasikov Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone Metals solvent extraction bauxite iron aluminum chloride solution alcohol |
| title | Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone |
| title_full | Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone |
| title_fullStr | Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone |
| title_full_unstemmed | Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone |
| title_short | Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone |
| title_sort | solvent extraction of iron iii from al chloride solution of bauxite hcl leaching by mixture of aliphatic alcohol and ketone |
| topic | solvent extraction bauxite iron aluminum chloride solution alcohol |
| url | https://www.mdpi.com/2075-4701/11/2/321 |
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