6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione)
Microwave irradiation of maleimide with an excess of furan in water exclusively yields the corresponding exo-cycloadduct in good yield (87%) in 1 hour at 90 oC. Alkylation of the imido nitrogen with tetraethylene glycol under Mitsunobu conditions gives the ROMP monomer in 81% yield.
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| Format: | Article |
| Language: | English |
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MDPI AG
2009-11-01
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| Series: | Molbank |
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| Online Access: | http://www.mdpi.com/1422-8599/2009/4/M638/ |
| _version_ | 1818081715055230976 |
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| author | David M. Gooden |
| author_facet | David M. Gooden |
| author_sort | David M. Gooden |
| collection | DOAJ |
| description | Microwave irradiation of maleimide with an excess of furan in water exclusively yields the corresponding exo-cycloadduct in good yield (87%) in 1 hour at 90 oC. Alkylation of the imido nitrogen with tetraethylene glycol under Mitsunobu conditions gives the ROMP monomer in 81% yield. |
| first_indexed | 2024-12-10T19:10:36Z |
| format | Article |
| id | doaj.art-c689e94a4367401f8d663cbfca957e55 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-12-10T19:10:36Z |
| publishDate | 2009-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-c689e94a4367401f8d663cbfca957e552022-12-22T01:36:47ZengMDPI AGMolbank1422-85992009-11-0120094M63810.3390/M6386-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione)David M. GoodenMicrowave irradiation of maleimide with an excess of furan in water exclusively yields the corresponding exo-cycloadduct in good yield (87%) in 1 hour at 90 oC. Alkylation of the imido nitrogen with tetraethylene glycol under Mitsunobu conditions gives the ROMP monomer in 81% yield.http://www.mdpi.com/1422-8599/2009/4/M638/n/a |
| spellingShingle | David M. Gooden 6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) Molbank n/a |
| title | 6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_full | 6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_fullStr | 6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_full_unstemmed | 6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_short | 6-(4-(2-{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethoxy}-ethyl)-10-oxa-4-aza-tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione) |
| title_sort | 6 4 2 2 2 2 hydroxy ethoxy ethoxy ethoxy ethyl 10 oxa 4 aza tricyclo 5 2 1 02 6 dec 8 ene 3 5 dione |
| topic | n/a |
| url | http://www.mdpi.com/1422-8599/2009/4/M638/ |
| work_keys_str_mv | AT davidmgooden 642222hydroxyethoxyethoxyethoxyethyl10oxa4azatricyclo521026dec8ene35dione |