Effect of a Rubidium Chloride Carrier Confinement Layer on the Characteristics of CsPbBr3 Perovskite Light-Emitting Diodes
Abstract This work describes the effect of a rubidium chloride (RbCl) interlayer in CsPbBr3 perovskite light-emitting diode (LED) structures. RbCl crystallites exhibited polyhedral structures and lattice parameters similar to those of CsPbBr3 perovskite crystallites. The lattice mismatch between the...
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SpringerOpen
2022-01-01
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Series: | Nanoscale Research Letters |
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Online Access: | https://doi.org/10.1186/s11671-021-03641-9 |
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author | Chi-Ta Li Kuan-Lin Lee Sea-Fue Wang Lung-Chien Chen |
author_facet | Chi-Ta Li Kuan-Lin Lee Sea-Fue Wang Lung-Chien Chen |
author_sort | Chi-Ta Li |
collection | DOAJ |
description | Abstract This work describes the effect of a rubidium chloride (RbCl) interlayer in CsPbBr3 perovskite light-emitting diode (LED) structures. RbCl crystallites exhibited polyhedral structures and lattice parameters similar to those of CsPbBr3 perovskite crystallites. The lattice mismatch between the RbCl interlayer and CsPbBr3 active layer was only approximately 2%. The devices exhibited the best quality and performance when RbCl was used as the nucleation and carrier confinement layer. The crystallite sizes of CsPbBr3 with 0.2-, 0.5-, and 1-nm-thick RbCl bottom layers were 55.1, 65.4, and 55.1 nm, respectively. The full width at half maximum (FWHM) of the photoluminescence (PL) emission peak for CsPbBr3 with the RbCl bottom layer was 0.096 eV. |
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institution | Directory Open Access Journal |
issn | 1556-276X |
language | English |
last_indexed | 2024-03-12T20:30:38Z |
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spelling | doaj.art-c6aeed224b3d43e88279eddde426ca5d2023-08-02T00:09:13ZengSpringerOpenNanoscale Research Letters1556-276X2022-01-011711810.1186/s11671-021-03641-9Effect of a Rubidium Chloride Carrier Confinement Layer on the Characteristics of CsPbBr3 Perovskite Light-Emitting DiodesChi-Ta Li0Kuan-Lin Lee1Sea-Fue Wang2Lung-Chien Chen3Department of Materials and Mineral Resources Engineering, National Taipei University of TechnologyDepartment of Electro-optical Engineering, National Taipei University of TechnologyDepartment of Materials and Mineral Resources Engineering, National Taipei University of TechnologyDepartment of Electro-optical Engineering, National Taipei University of TechnologyAbstract This work describes the effect of a rubidium chloride (RbCl) interlayer in CsPbBr3 perovskite light-emitting diode (LED) structures. RbCl crystallites exhibited polyhedral structures and lattice parameters similar to those of CsPbBr3 perovskite crystallites. The lattice mismatch between the RbCl interlayer and CsPbBr3 active layer was only approximately 2%. The devices exhibited the best quality and performance when RbCl was used as the nucleation and carrier confinement layer. The crystallite sizes of CsPbBr3 with 0.2-, 0.5-, and 1-nm-thick RbCl bottom layers were 55.1, 65.4, and 55.1 nm, respectively. The full width at half maximum (FWHM) of the photoluminescence (PL) emission peak for CsPbBr3 with the RbCl bottom layer was 0.096 eV.https://doi.org/10.1186/s11671-021-03641-9CsPbBr3RbCl carrier confinement layerPerovskiteLight-emitting diodes |
spellingShingle | Chi-Ta Li Kuan-Lin Lee Sea-Fue Wang Lung-Chien Chen Effect of a Rubidium Chloride Carrier Confinement Layer on the Characteristics of CsPbBr3 Perovskite Light-Emitting Diodes Nanoscale Research Letters CsPbBr3 RbCl carrier confinement layer Perovskite Light-emitting diodes |
title | Effect of a Rubidium Chloride Carrier Confinement Layer on the Characteristics of CsPbBr3 Perovskite Light-Emitting Diodes |
title_full | Effect of a Rubidium Chloride Carrier Confinement Layer on the Characteristics of CsPbBr3 Perovskite Light-Emitting Diodes |
title_fullStr | Effect of a Rubidium Chloride Carrier Confinement Layer on the Characteristics of CsPbBr3 Perovskite Light-Emitting Diodes |
title_full_unstemmed | Effect of a Rubidium Chloride Carrier Confinement Layer on the Characteristics of CsPbBr3 Perovskite Light-Emitting Diodes |
title_short | Effect of a Rubidium Chloride Carrier Confinement Layer on the Characteristics of CsPbBr3 Perovskite Light-Emitting Diodes |
title_sort | effect of a rubidium chloride carrier confinement layer on the characteristics of cspbbr3 perovskite light emitting diodes |
topic | CsPbBr3 RbCl carrier confinement layer Perovskite Light-emitting diodes |
url | https://doi.org/10.1186/s11671-021-03641-9 |
work_keys_str_mv | AT chitali effectofarubidiumchloridecarrierconfinementlayeronthecharacteristicsofcspbbr3perovskitelightemittingdiodes AT kuanlinlee effectofarubidiumchloridecarrierconfinementlayeronthecharacteristicsofcspbbr3perovskitelightemittingdiodes AT seafuewang effectofarubidiumchloridecarrierconfinementlayeronthecharacteristicsofcspbbr3perovskitelightemittingdiodes AT lungchienchen effectofarubidiumchloridecarrierconfinementlayeronthecharacteristicsofcspbbr3perovskitelightemittingdiodes |