Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation

The induced crystallinity behavior of the polymer of intrinsic microporosity (PIM-1) matrix in mixed matrix membranes (MMMs) by a novel class of two-dimensional (2D) metal-organic framework nanosheets, i.e., NUS-8-COOH, is demonstrated. The proposed ideal of enhanced crystallinity induced by NUS-8-C...

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Main Authors: Dechao Wang, Yunpan Ying, Yaping Zheng, Yunchuan Pu, Ziqi Yang, Dan Zhao
Format: Article
Language:English
Published: Elsevier 2022-05-01
Series:Journal of Membrane Science Letters
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2772421222000058
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author Dechao Wang
Yunpan Ying
Yaping Zheng
Yunchuan Pu
Ziqi Yang
Dan Zhao
author_facet Dechao Wang
Yunpan Ying
Yaping Zheng
Yunchuan Pu
Ziqi Yang
Dan Zhao
author_sort Dechao Wang
collection DOAJ
description The induced crystallinity behavior of the polymer of intrinsic microporosity (PIM-1) matrix in mixed matrix membranes (MMMs) by a novel class of two-dimensional (2D) metal-organic framework nanosheets, i.e., NUS-8-COOH, is demonstrated. The proposed ideal of enhanced crystallinity induced by NUS-8-COOH nanosheets can be extended to other classes of 2D nanosheet-containing MMMs, thus opening up plentiful opportunities for constructing MMMs with superior interfacial compatibility toward enhanced gas separation performance.
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spelling doaj.art-c6d1de0bf38940ffaced02f7a60f18472022-12-22T02:26:01ZengElsevierJournal of Membrane Science Letters2772-42122022-05-0121100017Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separationDechao Wang0Yunpan Ying1Yaping Zheng2Yunchuan Pu3Ziqi Yang4Dan Zhao5Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117585, Singapore; School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, 1 Dongxiang Road, Chang'an District, Xi'an, Shaanxi 710129, PR ChinaDepartment of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117585, SingaporeSchool of Chemistry and Chemical Engineering, Northwestern Polytechnical University, 1 Dongxiang Road, Chang'an District, Xi'an, Shaanxi 710129, PR ChinaDepartment of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117585, Singapore; Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou 350207, PR ChinaDepartment of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117585, SingaporeDepartment of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117585, Singapore; Corresponding author.The induced crystallinity behavior of the polymer of intrinsic microporosity (PIM-1) matrix in mixed matrix membranes (MMMs) by a novel class of two-dimensional (2D) metal-organic framework nanosheets, i.e., NUS-8-COOH, is demonstrated. The proposed ideal of enhanced crystallinity induced by NUS-8-COOH nanosheets can be extended to other classes of 2D nanosheet-containing MMMs, thus opening up plentiful opportunities for constructing MMMs with superior interfacial compatibility toward enhanced gas separation performance.http://www.sciencedirect.com/science/article/pii/S2772421222000058Induced crystallinityMixed matrix membranesPIM-1NUS-8-COOHMetal-organic framework nanosheets
spellingShingle Dechao Wang
Yunpan Ying
Yaping Zheng
Yunchuan Pu
Ziqi Yang
Dan Zhao
Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation
Journal of Membrane Science Letters
Induced crystallinity
Mixed matrix membranes
PIM-1
NUS-8-COOH
Metal-organic framework nanosheets
title Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation
title_full Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation
title_fullStr Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation
title_full_unstemmed Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation
title_short Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation
title_sort induced polymer crystallinity in mixed matrix membranes by metal organic framework nanosheets for gas separation
topic Induced crystallinity
Mixed matrix membranes
PIM-1
NUS-8-COOH
Metal-organic framework nanosheets
url http://www.sciencedirect.com/science/article/pii/S2772421222000058
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AT yapingzheng inducedpolymercrystallinityinmixedmatrixmembranesbymetalorganicframeworknanosheetsforgasseparation
AT yunchuanpu inducedpolymercrystallinityinmixedmatrixmembranesbymetalorganicframeworknanosheetsforgasseparation
AT ziqiyang inducedpolymercrystallinityinmixedmatrixmembranesbymetalorganicframeworknanosheetsforgasseparation
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