Application of the intergranular impedance model in correlating microstructure and electrical properties of doped BaTiO3

Microstructure properties of barium-titanate based materials, expressed in grain boundary contacts, are of basic importance for electric properties of this material. In this study, the model of intergranular impedance applied on a two-grain contact is considered. Globally, a BaTiO3-ceramics sample c...

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Main Authors: Mitić V., Pavlović V.B., Kocić Lj., Paunović V., Mančić D.
Format: Article
Language:English
Published: International Institute for the Science of Sintering, Beograd 2009-01-01
Series:Science of Sintering
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0350-820X/2009/0350-820X0903247M.pdf
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author Mitić V.
Pavlović V.B.
Kocić Lj.
Paunović V.
Mančić D.
author_facet Mitić V.
Pavlović V.B.
Kocić Lj.
Paunović V.
Mančić D.
author_sort Mitić V.
collection DOAJ
description Microstructure properties of barium-titanate based materials, expressed in grain boundary contacts, are of basic importance for electric properties of this material. In this study, the model of intergranular impedance applied on a two-grain contact is considered. Globally, a BaTiO3-ceramics sample consists of a large number of mutually contacted grains, which form clusters. Such clusters can be presented as specific fractal formations. For each of them, it is possible to establish the equivalent electrical model and, for a defined set of input parameters, using symbolic analysis, obtain the frequency diagram. The influence of fractal structure is especially stressed. Realizing the totality of relations between cluster grain groups, their microelectrical schemes and corresponding frequency characteristics, on one hand, and the global equivalent electrical scheme and corresponding acquired frequency characteristics of BaTiO3-ceramics samples, on the other hand, we set a goal of correlating experimental results with the summing effect of microelectric equivalent schemes. The model is successfully tested on doped barium-titanate ceramics.
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spelling doaj.art-c6de35da1fcb4e639d174679e82732842022-12-21T21:09:48ZengInternational Institute for the Science of Sintering, BeogradScience of Sintering0350-820X2009-01-0141324725610.2298/SOS0903247MApplication of the intergranular impedance model in correlating microstructure and electrical properties of doped BaTiO3Mitić V.Pavlović V.B.Kocić Lj.Paunović V.Mančić D.Microstructure properties of barium-titanate based materials, expressed in grain boundary contacts, are of basic importance for electric properties of this material. In this study, the model of intergranular impedance applied on a two-grain contact is considered. Globally, a BaTiO3-ceramics sample consists of a large number of mutually contacted grains, which form clusters. Such clusters can be presented as specific fractal formations. For each of them, it is possible to establish the equivalent electrical model and, for a defined set of input parameters, using symbolic analysis, obtain the frequency diagram. The influence of fractal structure is especially stressed. Realizing the totality of relations between cluster grain groups, their microelectrical schemes and corresponding frequency characteristics, on one hand, and the global equivalent electrical scheme and corresponding acquired frequency characteristics of BaTiO3-ceramics samples, on the other hand, we set a goal of correlating experimental results with the summing effect of microelectric equivalent schemes. The model is successfully tested on doped barium-titanate ceramics.http://www.doiserbia.nb.rs/img/doi/0350-820X/2009/0350-820X0903247M.pdfbarium-titanatemicrostructurefractalsclustersintergranular impedanceoptimization
spellingShingle Mitić V.
Pavlović V.B.
Kocić Lj.
Paunović V.
Mančić D.
Application of the intergranular impedance model in correlating microstructure and electrical properties of doped BaTiO3
Science of Sintering
barium-titanate
microstructure
fractals
clusters
intergranular impedance
optimization
title Application of the intergranular impedance model in correlating microstructure and electrical properties of doped BaTiO3
title_full Application of the intergranular impedance model in correlating microstructure and electrical properties of doped BaTiO3
title_fullStr Application of the intergranular impedance model in correlating microstructure and electrical properties of doped BaTiO3
title_full_unstemmed Application of the intergranular impedance model in correlating microstructure and electrical properties of doped BaTiO3
title_short Application of the intergranular impedance model in correlating microstructure and electrical properties of doped BaTiO3
title_sort application of the intergranular impedance model in correlating microstructure and electrical properties of doped batio3
topic barium-titanate
microstructure
fractals
clusters
intergranular impedance
optimization
url http://www.doiserbia.nb.rs/img/doi/0350-820X/2009/0350-820X0903247M.pdf
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