THE STRATEGY OF STUDYING THREE-LIQUID PHASE EQUILIBRIA IN THE CONCENTRATION SPACE OF QUATERNARY MIXTURES
When separating multicomponent heterogeneous mixtures in units consisting of a distillation column and a decanter, a fundamental question is the location of phase separation regions with different numbers of liquid phases in the concentration simplex. A solution of this issue is based on data on the...
| Main Authors: | , |
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2016-10-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/50 |
| _version_ | 1797882066458640384 |
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| author | A. Yu. Sebyakin A. K. Frolkova |
| author_facet | A. Yu. Sebyakin A. K. Frolkova |
| author_sort | A. Yu. Sebyakin |
| collection | DOAJ |
| description | When separating multicomponent heterogeneous mixtures in units consisting of a distillation column and a decanter, a fundamental question is the location of phase separation regions with different numbers of liquid phases in the concentration simplex. A solution of this issue is based on data on the vapor-liquid and liquid-liquid equilibria of the mixture and its components, as well as on the general laws of the formation of the topological structure of phase separation areas. A strategy of studying the three-liquid phase equilibrium area in quaternary mixtures is proposed. The strategy is based on the formula of a topological invariant of the separation region and on the mathematical concept of centroid - the intersection point of three medians. The presence of threeliquid phase areas of separation of open and closed types is shown. They differ in the absence (presence) of region of degeneracy via the critical node. |
| first_indexed | 2024-04-10T03:29:02Z |
| format | Article |
| id | doaj.art-c6f3e89d27df4d40899fd46a2b4bd780 |
| institution | Directory Open Access Journal |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| last_indexed | 2024-04-10T03:29:02Z |
| publishDate | 2016-10-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj.art-c6f3e89d27df4d40899fd46a2b4bd7802023-03-13T07:25:37ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752016-10-01115656910.32362/2410-6593-2016-11-5-65-6950THE STRATEGY OF STUDYING THREE-LIQUID PHASE EQUILIBRIA IN THE CONCENTRATION SPACE OF QUATERNARY MIXTURESA. Yu. Sebyakin0A. K. Frolkova1Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)When separating multicomponent heterogeneous mixtures in units consisting of a distillation column and a decanter, a fundamental question is the location of phase separation regions with different numbers of liquid phases in the concentration simplex. A solution of this issue is based on data on the vapor-liquid and liquid-liquid equilibria of the mixture and its components, as well as on the general laws of the formation of the topological structure of phase separation areas. A strategy of studying the three-liquid phase equilibrium area in quaternary mixtures is proposed. The strategy is based on the formula of a topological invariant of the separation region and on the mathematical concept of centroid - the intersection point of three medians. The presence of threeliquid phase areas of separation of open and closed types is shown. They differ in the absence (presence) of region of degeneracy via the critical node.https://www.finechem-mirea.ru/jour/article/view/50three-phase separation regionphase diagram structuremathematical simulation |
| spellingShingle | A. Yu. Sebyakin A. K. Frolkova THE STRATEGY OF STUDYING THREE-LIQUID PHASE EQUILIBRIA IN THE CONCENTRATION SPACE OF QUATERNARY MIXTURES Тонкие химические технологии three-phase separation region phase diagram structure mathematical simulation |
| title | THE STRATEGY OF STUDYING THREE-LIQUID PHASE EQUILIBRIA IN THE CONCENTRATION SPACE OF QUATERNARY MIXTURES |
| title_full | THE STRATEGY OF STUDYING THREE-LIQUID PHASE EQUILIBRIA IN THE CONCENTRATION SPACE OF QUATERNARY MIXTURES |
| title_fullStr | THE STRATEGY OF STUDYING THREE-LIQUID PHASE EQUILIBRIA IN THE CONCENTRATION SPACE OF QUATERNARY MIXTURES |
| title_full_unstemmed | THE STRATEGY OF STUDYING THREE-LIQUID PHASE EQUILIBRIA IN THE CONCENTRATION SPACE OF QUATERNARY MIXTURES |
| title_short | THE STRATEGY OF STUDYING THREE-LIQUID PHASE EQUILIBRIA IN THE CONCENTRATION SPACE OF QUATERNARY MIXTURES |
| title_sort | strategy of studying three liquid phase equilibria in the concentration space of quaternary mixtures |
| topic | three-phase separation region phase diagram structure mathematical simulation |
| url | https://www.finechem-mirea.ru/jour/article/view/50 |
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