Crystal structure of (μ-hydrogen disulfato)-μ-oxido-bis[(4,4′-di-tert-butyl-2,2′-bipyridine)oxidovanadium(IV/V)] acetonitrile monosolvate

Crystal structure of (μ-hydrogen disulfato)-μ-oxido-bis[(4,4′-di-tert-butyl-2,2′-bipyridine)oxidovanadium(IV/V)] acetonitrile monosolvate

The dinuclear oxidovanadium(IV/V) complex, [V2(HS2O8)O3(C18H24N2)2]·CH3CN or [V2O2(μ-O)(μ-H(SO4)2)(4,4′-tBubpy)2]·CH3CN (4,4′-tBubpy = 4,4′-di-tert-butyl-2,2′-bipyridine), has crystallographic C2 symmetry and exhibits a distorted octahedral geometry around the vanadium center, where the two 4,4′-tBu...

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Detalles Bibliográficos
Main Authors: Shintaro Kodama, Terushi Hashiguchi, Akihiro Nomoto
Formato: Artigo
Idioma:English
Publicado: International Union of Crystallography 2023-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
vanadium
bipyridine
sulfate
Acceso en liña:http://scripts.iucr.org/cgi-bin/paper?S2056989023009040

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989023009040

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