Photocatalytic properties of ZnO/SnO2 nanocomposite films: role of morphology

ZnO-xSnO2 composite films (x = 0, 25, 50, 75, 100 mol%) were deposited by sol–gel spin coating process. The film's microstructural, optical, and photocatalytic properties were studied by various characterization methods such as X-ray diffractometry, Raman spectroscopy, scanning electron microsc...

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Main Authors: S. Zarei, M. Hasheminiasari, S.M. Masoudpanah, J. Javadpour
Format: Article
Language:English
Published: Elsevier 2022-03-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785422001260
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author S. Zarei
M. Hasheminiasari
S.M. Masoudpanah
J. Javadpour
author_facet S. Zarei
M. Hasheminiasari
S.M. Masoudpanah
J. Javadpour
author_sort S. Zarei
collection DOAJ
description ZnO-xSnO2 composite films (x = 0, 25, 50, 75, 100 mol%) were deposited by sol–gel spin coating process. The film's microstructural, optical, and photocatalytic properties were studied by various characterization methods such as X-ray diffractometry, Raman spectroscopy, scanning electron microscopy, diffuse reflectance, and photoluminescence spectroscopy. Pure hexagonal ZnO and tetragonal SnO2 phases were formed without additional impurity intermediate phases. The microstructure of composite films showed the distinct morphology with hexagonal ZnO pyramids nucleated on SnO2 nanoparticles, as revealed by the elemental distribution map. The ZnO-25 mol% SnO2 film photodegraded about 70% of methylene blue (MB) dye under ultraviolet irradiation, which was higher than that of the pristine ZnO (5%) and SnO2 (10%) films due to the effective separation of hole–electron pairs, as confirmed by PL spectra.
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spelling doaj.art-c70bca984adc41f8a16f17c0f441bae92022-12-21T21:11:18ZengElsevierJournal of Materials Research and Technology2238-78542022-03-011723052312Photocatalytic properties of ZnO/SnO2 nanocomposite films: role of morphologyS. Zarei0M. Hasheminiasari1S.M. Masoudpanah2J. Javadpour3School of Metallurgy & Materials Engineering, Iran University of Science and Technology (IUST), Tehran, IranCorresponding author.; School of Metallurgy & Materials Engineering, Iran University of Science and Technology (IUST), Tehran, IranSchool of Metallurgy & Materials Engineering, Iran University of Science and Technology (IUST), Tehran, IranSchool of Metallurgy & Materials Engineering, Iran University of Science and Technology (IUST), Tehran, IranZnO-xSnO2 composite films (x = 0, 25, 50, 75, 100 mol%) were deposited by sol–gel spin coating process. The film's microstructural, optical, and photocatalytic properties were studied by various characterization methods such as X-ray diffractometry, Raman spectroscopy, scanning electron microscopy, diffuse reflectance, and photoluminescence spectroscopy. Pure hexagonal ZnO and tetragonal SnO2 phases were formed without additional impurity intermediate phases. The microstructure of composite films showed the distinct morphology with hexagonal ZnO pyramids nucleated on SnO2 nanoparticles, as revealed by the elemental distribution map. The ZnO-25 mol% SnO2 film photodegraded about 70% of methylene blue (MB) dye under ultraviolet irradiation, which was higher than that of the pristine ZnO (5%) and SnO2 (10%) films due to the effective separation of hole–electron pairs, as confirmed by PL spectra.http://www.sciencedirect.com/science/article/pii/S2238785422001260ZnOSnO2Sol–gelPhotocatalytic activitySpin coating
spellingShingle S. Zarei
M. Hasheminiasari
S.M. Masoudpanah
J. Javadpour
Photocatalytic properties of ZnO/SnO2 nanocomposite films: role of morphology
Journal of Materials Research and Technology
ZnO
SnO2
Sol–gel
Photocatalytic activity
Spin coating
title Photocatalytic properties of ZnO/SnO2 nanocomposite films: role of morphology
title_full Photocatalytic properties of ZnO/SnO2 nanocomposite films: role of morphology
title_fullStr Photocatalytic properties of ZnO/SnO2 nanocomposite films: role of morphology
title_full_unstemmed Photocatalytic properties of ZnO/SnO2 nanocomposite films: role of morphology
title_short Photocatalytic properties of ZnO/SnO2 nanocomposite films: role of morphology
title_sort photocatalytic properties of zno sno2 nanocomposite films role of morphology
topic ZnO
SnO2
Sol–gel
Photocatalytic activity
Spin coating
url http://www.sciencedirect.com/science/article/pii/S2238785422001260
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AT mhasheminiasari photocatalyticpropertiesofznosno2nanocompositefilmsroleofmorphology
AT smmasoudpanah photocatalyticpropertiesofznosno2nanocompositefilmsroleofmorphology
AT jjavadpour photocatalyticpropertiesofznosno2nanocompositefilmsroleofmorphology