Safety aspects of Organic Rankine Cycles (ORC) with combustible working fluid and sub-ambient condenser pressure

ORCs are often designed with the lower pressure limited by the ambient pressure, to avoid air leaking into the working fluid. Safely lowering this limit will be beneficial for power-production efficiency. First, cycle operations with air inleak are investigated. Exemplary cases with n-pentane and be...

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Main Authors: Håkon Dalbakken, Ivar S. Ertesvåg
Format: Article
Language:English
Published: Elsevier 2024-06-01
Series:Energy Reports
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2352484723016438
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author Håkon Dalbakken
Ivar S. Ertesvåg
author_facet Håkon Dalbakken
Ivar S. Ertesvåg
author_sort Håkon Dalbakken
collection DOAJ
description ORCs are often designed with the lower pressure limited by the ambient pressure, to avoid air leaking into the working fluid. Safely lowering this limit will be beneficial for power-production efficiency. First, cycle operations with air inleak are investigated. Exemplary cases with n-pentane and benzene are used. The investigation combines tools from thermodynamics of cycle working fluids, pump operation and analysis and combustion science. It appears that pumps customarily used in ORC will forward only liquid, and air mixing into the working fluid at the high-pressure side will not be sufficient for flammable conditions. Next, combustion properties of the air/working fluid mixture in the condenser are evaluated. Transient zero-dimensional and one-dimensional steady state laminar premixed flames are applied for the modelling. Detailed chemical mechanisms from the CRECK and TDTVT groups are used for benzene and n-pentane. It is found that some substances, like pentane, will not make flammable mixtures within the conditions of the power cycle. However, fluids that at the relevant temperatures have saturation pressure much lower than the ambient, might give flammable mixtures with air inleak. For potential sub-ambient use of these, ignition energy sources and quenching geometries have to be considered carefully.
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spelling doaj.art-c70c5dac864b4254ab6175ae800fde9c2023-12-29T04:45:34ZengElsevierEnergy Reports2352-48472024-06-0111877886Safety aspects of Organic Rankine Cycles (ORC) with combustible working fluid and sub-ambient condenser pressureHåkon Dalbakken0Ivar S. Ertesvåg1Department of Energy and Process Engineering, NTNU Norwegian University of Science and Technology, Kolbjørn Hejes vei 1b, NO 7491, Trondheim, NorwayCorresponding author.; Department of Energy and Process Engineering, NTNU Norwegian University of Science and Technology, Kolbjørn Hejes vei 1b, NO 7491, Trondheim, NorwayORCs are often designed with the lower pressure limited by the ambient pressure, to avoid air leaking into the working fluid. Safely lowering this limit will be beneficial for power-production efficiency. First, cycle operations with air inleak are investigated. Exemplary cases with n-pentane and benzene are used. The investigation combines tools from thermodynamics of cycle working fluids, pump operation and analysis and combustion science. It appears that pumps customarily used in ORC will forward only liquid, and air mixing into the working fluid at the high-pressure side will not be sufficient for flammable conditions. Next, combustion properties of the air/working fluid mixture in the condenser are evaluated. Transient zero-dimensional and one-dimensional steady state laminar premixed flames are applied for the modelling. Detailed chemical mechanisms from the CRECK and TDTVT groups are used for benzene and n-pentane. It is found that some substances, like pentane, will not make flammable mixtures within the conditions of the power cycle. However, fluids that at the relevant temperatures have saturation pressure much lower than the ambient, might give flammable mixtures with air inleak. For potential sub-ambient use of these, ignition energy sources and quenching geometries have to be considered carefully.http://www.sciencedirect.com/science/article/pii/S2352484723016438EfficiencyLeakagePentaneBenzeneFlammableFire
spellingShingle Håkon Dalbakken
Ivar S. Ertesvåg
Safety aspects of Organic Rankine Cycles (ORC) with combustible working fluid and sub-ambient condenser pressure
Energy Reports
Efficiency
Leakage
Pentane
Benzene
Flammable
Fire
title Safety aspects of Organic Rankine Cycles (ORC) with combustible working fluid and sub-ambient condenser pressure
title_full Safety aspects of Organic Rankine Cycles (ORC) with combustible working fluid and sub-ambient condenser pressure
title_fullStr Safety aspects of Organic Rankine Cycles (ORC) with combustible working fluid and sub-ambient condenser pressure
title_full_unstemmed Safety aspects of Organic Rankine Cycles (ORC) with combustible working fluid and sub-ambient condenser pressure
title_short Safety aspects of Organic Rankine Cycles (ORC) with combustible working fluid and sub-ambient condenser pressure
title_sort safety aspects of organic rankine cycles orc with combustible working fluid and sub ambient condenser pressure
topic Efficiency
Leakage
Pentane
Benzene
Flammable
Fire
url http://www.sciencedirect.com/science/article/pii/S2352484723016438
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