Advanced Biofuels from ABE (Acetone/Butanol/Ethanol) and Vegetable Oils (Castor or Sunflower Oil) for Using in Triple Blends with Diesel: Evaluation on a Diesel Engine

From a technical and economic point of view, our aim is to provide viable solutions for the replacement of fossil fuels which are currently used in internal combustion diesel engines. In this research, two new biofuels composed of second-generation vegetable oils (SVO),used oil sunflower (SO) or cas...

Full description

Bibliographic Details
Main Authors: Laura Aguado-Deblas, Francisco J. López-Tenllado, Diego Luna, Felipa M. Bautista, Antonio A. Romero, Rafael Estevez
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/18/6493
_version_ 1797485311607963648
author Laura Aguado-Deblas
Francisco J. López-Tenllado
Diego Luna
Felipa M. Bautista
Antonio A. Romero
Rafael Estevez
author_facet Laura Aguado-Deblas
Francisco J. López-Tenllado
Diego Luna
Felipa M. Bautista
Antonio A. Romero
Rafael Estevez
author_sort Laura Aguado-Deblas
collection DOAJ
description From a technical and economic point of view, our aim is to provide viable solutions for the replacement of fossil fuels which are currently used in internal combustion diesel engines. In this research, two new biofuels composed of second-generation vegetable oils (SVO),used oil sunflower (SO) or castor oil (CO), and the ABE blend (acetone/butanol/ethanol) were evaluated. ABE is an intermediate product from the fermentation of carbohydrates to obtain bio-butanol. Besides, the ABE blend exhibits suitable properties as biofuel, such asvery low kinematic viscosity, reasonable energy density, low autoignition temperature, and broad flammability limits. Diesel/ABE/SVO triple blends were prepared, characterized and then, tested on a diesel engine, evaluating power output, consumption, and exhaust emissions. The power output was slightly reduced due to the low heating values of ABE blend. Also, engine consumed more fuel with the triple blends than with diesel under low engine loads whereas, at medium and high loads, the fuel consumption was very similar to that of diesel. Regarding exhaust gas emissions, soot wasnotably reduced, and nitrogen oxides (NO<sub>x</sub>) and carbon monoxide (CO<sub>2</sub>) emissions were lower or comparable to that of diesel, while the CO emissions increased. The use of these biofuels allows the replacement of high percentagesof diesel without compromising engine power and achievinga significant reduction in pollution emissions. Furthermore, a notable improvement in cold flow properties of the fuel blends is obtained, in comparison with diesel.
first_indexed 2024-03-09T23:16:58Z
format Article
id doaj.art-c724f891621e4eea83cbe08fc95897d1
institution Directory Open Access Journal
issn 1996-1944
language English
last_indexed 2024-03-09T23:16:58Z
publishDate 2022-09-01
publisher MDPI AG
record_format Article
series Materials
spelling doaj.art-c724f891621e4eea83cbe08fc95897d12023-11-23T17:34:35ZengMDPI AGMaterials1996-19442022-09-011518649310.3390/ma15186493Advanced Biofuels from ABE (Acetone/Butanol/Ethanol) and Vegetable Oils (Castor or Sunflower Oil) for Using in Triple Blends with Diesel: Evaluation on a Diesel EngineLaura Aguado-Deblas0Francisco J. López-Tenllado1Diego Luna2Felipa M. Bautista3Antonio A. Romero4Rafael Estevez5Department of Organic Chemistry, University of Cordoba, Campus of Rabanales, Ed. Marie Curie, 14014 Córdoba, SpainDepartment of Organic Chemistry, University of Cordoba, Campus of Rabanales, Ed. Marie Curie, 14014 Córdoba, SpainDepartment of Organic Chemistry, University of Cordoba, Campus of Rabanales, Ed. Marie Curie, 14014 Córdoba, SpainDepartment of Organic Chemistry, University of Cordoba, Campus of Rabanales, Ed. Marie Curie, 14014 Córdoba, SpainDepartment of Organic Chemistry, University of Cordoba, Campus of Rabanales, Ed. Marie Curie, 14014 Córdoba, SpainDepartment of Organic Chemistry, University of Cordoba, Campus of Rabanales, Ed. Marie Curie, 14014 Córdoba, SpainFrom a technical and economic point of view, our aim is to provide viable solutions for the replacement of fossil fuels which are currently used in internal combustion diesel engines. In this research, two new biofuels composed of second-generation vegetable oils (SVO),used oil sunflower (SO) or castor oil (CO), and the ABE blend (acetone/butanol/ethanol) were evaluated. ABE is an intermediate product from the fermentation of carbohydrates to obtain bio-butanol. Besides, the ABE blend exhibits suitable properties as biofuel, such asvery low kinematic viscosity, reasonable energy density, low autoignition temperature, and broad flammability limits. Diesel/ABE/SVO triple blends were prepared, characterized and then, tested on a diesel engine, evaluating power output, consumption, and exhaust emissions. The power output was slightly reduced due to the low heating values of ABE blend. Also, engine consumed more fuel with the triple blends than with diesel under low engine loads whereas, at medium and high loads, the fuel consumption was very similar to that of diesel. Regarding exhaust gas emissions, soot wasnotably reduced, and nitrogen oxides (NO<sub>x</sub>) and carbon monoxide (CO<sub>2</sub>) emissions were lower or comparable to that of diesel, while the CO emissions increased. The use of these biofuels allows the replacement of high percentagesof diesel without compromising engine power and achievinga significant reduction in pollution emissions. Furthermore, a notable improvement in cold flow properties of the fuel blends is obtained, in comparison with diesel.https://www.mdpi.com/1996-1944/15/18/6493ABE blendstraight vegetable oilcastor oilsunflower oilbiofueldiesel engine
spellingShingle Laura Aguado-Deblas
Francisco J. López-Tenllado
Diego Luna
Felipa M. Bautista
Antonio A. Romero
Rafael Estevez
Advanced Biofuels from ABE (Acetone/Butanol/Ethanol) and Vegetable Oils (Castor or Sunflower Oil) for Using in Triple Blends with Diesel: Evaluation on a Diesel Engine
Materials
ABE blend
straight vegetable oil
castor oil
sunflower oil
biofuel
diesel engine
title Advanced Biofuels from ABE (Acetone/Butanol/Ethanol) and Vegetable Oils (Castor or Sunflower Oil) for Using in Triple Blends with Diesel: Evaluation on a Diesel Engine
title_full Advanced Biofuels from ABE (Acetone/Butanol/Ethanol) and Vegetable Oils (Castor or Sunflower Oil) for Using in Triple Blends with Diesel: Evaluation on a Diesel Engine
title_fullStr Advanced Biofuels from ABE (Acetone/Butanol/Ethanol) and Vegetable Oils (Castor or Sunflower Oil) for Using in Triple Blends with Diesel: Evaluation on a Diesel Engine
title_full_unstemmed Advanced Biofuels from ABE (Acetone/Butanol/Ethanol) and Vegetable Oils (Castor or Sunflower Oil) for Using in Triple Blends with Diesel: Evaluation on a Diesel Engine
title_short Advanced Biofuels from ABE (Acetone/Butanol/Ethanol) and Vegetable Oils (Castor or Sunflower Oil) for Using in Triple Blends with Diesel: Evaluation on a Diesel Engine
title_sort advanced biofuels from abe acetone butanol ethanol and vegetable oils castor or sunflower oil for using in triple blends with diesel evaluation on a diesel engine
topic ABE blend
straight vegetable oil
castor oil
sunflower oil
biofuel
diesel engine
url https://www.mdpi.com/1996-1944/15/18/6493
work_keys_str_mv AT lauraaguadodeblas advancedbiofuelsfromabeacetonebutanolethanolandvegetableoilscastororsunfloweroilforusingintripleblendswithdieselevaluationonadieselengine
AT franciscojlopeztenllado advancedbiofuelsfromabeacetonebutanolethanolandvegetableoilscastororsunfloweroilforusingintripleblendswithdieselevaluationonadieselengine
AT diegoluna advancedbiofuelsfromabeacetonebutanolethanolandvegetableoilscastororsunfloweroilforusingintripleblendswithdieselevaluationonadieselengine
AT felipambautista advancedbiofuelsfromabeacetonebutanolethanolandvegetableoilscastororsunfloweroilforusingintripleblendswithdieselevaluationonadieselengine
AT antonioaromero advancedbiofuelsfromabeacetonebutanolethanolandvegetableoilscastororsunfloweroilforusingintripleblendswithdieselevaluationonadieselengine
AT rafaelestevez advancedbiofuelsfromabeacetonebutanolethanolandvegetableoilscastororsunfloweroilforusingintripleblendswithdieselevaluationonadieselengine