Tetrakis{1-[4-(1H-imidazol-1-yl-κN3)phenyl]ethanone}bis(isothiocyanato-κN)nickel(II)
The title complex molecule, [Ni(NCS)2(C11H10N2O)4], has a crystallographically imposed centre of symmetry. The NiII atom is coordinated by the N atoms of two trans-arranged NCS− anions and four 1-[4-(1H-imidazol-1-yl)phenyl]ethanone ligands in a distorted octahedral geometry. In the cr...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812027092 |
| _version_ | 1819291441444159488 |
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| author | Juan Zhao Bao-Cheng Liu |
| author_facet | Juan Zhao Bao-Cheng Liu |
| author_sort | Juan Zhao |
| collection | DOAJ |
| description | The title complex molecule, [Ni(NCS)2(C11H10N2O)4], has a crystallographically imposed centre of symmetry. The NiII atom is coordinated by the N atoms of two trans-arranged NCS− anions and four 1-[4-(1H-imidazol-1-yl)phenyl]ethanone ligands in a distorted octahedral geometry. In the crystal, C—H...S hydrogen bonds link the complex molecules into chains parallel to the b axis. The chains are further connected by C—H...O hydrogen bonds, forming layers parallel to the bc plane. |
| first_indexed | 2024-12-24T03:38:41Z |
| format | Article |
| id | doaj.art-c729376a66a34c539216454bc91d8296 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:38:41Z |
| publishDate | 2012-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c729376a66a34c539216454bc91d82962022-12-21T17:16:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m967m96710.1107/S1600536812027092Tetrakis{1-[4-(1H-imidazol-1-yl-κN3)phenyl]ethanone}bis(isothiocyanato-κN)nickel(II)Juan ZhaoBao-Cheng LiuThe title complex molecule, [Ni(NCS)2(C11H10N2O)4], has a crystallographically imposed centre of symmetry. The NiII atom is coordinated by the N atoms of two trans-arranged NCS− anions and four 1-[4-(1H-imidazol-1-yl)phenyl]ethanone ligands in a distorted octahedral geometry. In the crystal, C—H...S hydrogen bonds link the complex molecules into chains parallel to the b axis. The chains are further connected by C—H...O hydrogen bonds, forming layers parallel to the bc plane.http://scripts.iucr.org/cgi-bin/paper?S1600536812027092 |
| spellingShingle | Juan Zhao Bao-Cheng Liu Tetrakis{1-[4-(1H-imidazol-1-yl-κN3)phenyl]ethanone}bis(isothiocyanato-κN)nickel(II) Acta Crystallographica Section E |
| title | Tetrakis{1-[4-(1H-imidazol-1-yl-κN3)phenyl]ethanone}bis(isothiocyanato-κN)nickel(II) |
| title_full | Tetrakis{1-[4-(1H-imidazol-1-yl-κN3)phenyl]ethanone}bis(isothiocyanato-κN)nickel(II) |
| title_fullStr | Tetrakis{1-[4-(1H-imidazol-1-yl-κN3)phenyl]ethanone}bis(isothiocyanato-κN)nickel(II) |
| title_full_unstemmed | Tetrakis{1-[4-(1H-imidazol-1-yl-κN3)phenyl]ethanone}bis(isothiocyanato-κN)nickel(II) |
| title_short | Tetrakis{1-[4-(1H-imidazol-1-yl-κN3)phenyl]ethanone}bis(isothiocyanato-κN)nickel(II) |
| title_sort | tetrakis 1 4 1h imidazol 1 yl amp 954 n3 phenyl ethanone bis isothiocyanato amp 954 n nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812027092 |
| work_keys_str_mv | AT juanzhao tetrakis141himidazol1ylamp954n3phenylethanonebisisothiocyanatoamp954nnickelii AT baochengliu tetrakis141himidazol1ylamp954n3phenylethanonebisisothiocyanatoamp954nnickelii |