Thermal Effect on Thin-Film Formation of the Polymer Sheets by the CO<sub>2</sub> Laser with the Copper Base

A method that makes polymer sheets partially thinner with continuous-wave carbon dioxide (CO<sub>2</sub>) lasers has been developed. This method can create thin polymer films by attaching the polymer sheets to the copper base by vacuum suction through the holes in the base. Applying the...

Full description

Bibliographic Details
Main Authors: Nobukazu Kameyama, Hiroki Yoshida
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/17/3508
_version_ 1797493597597073408
author Nobukazu Kameyama
Hiroki Yoshida
author_facet Nobukazu Kameyama
Hiroki Yoshida
author_sort Nobukazu Kameyama
collection DOAJ
description A method that makes polymer sheets partially thinner with continuous-wave carbon dioxide (CO<sub>2</sub>) lasers has been developed. This method can create thin polymer films by attaching the polymer sheets to the copper base by vacuum suction through the holes in the base. Applying the method to polypropylene (PP), polyethylene terephthalate (PET), polystyrene (PS), and polytetrafluoroethylene (PTFE), the thin-film formation is confirmed in PP, PET, and PS but not PTFE. These polymers have the similar thermal properties. PP, PET, and PS show fluidity with increased temperature, but PTFE does not have fluidity. These characteristics of the polymers indicate that the fluidity of polymer is the important characteristic for film formation. The experiments with PP and PET sheets of different thickness show that thicker sheets make thicker films. The fluid flow of the molten polymer is considered to form the thin film at the bottom of the groove made by laser scribing. The numerical simulation of the 2D thermal model also indicates the week cooling effects of the base on the film formation and importance of polymer fluidity. The results of Fourier transform infrared spectrometer (FT-IR) show thermal degradation of the films. To decrease the heat’s effect on the films, the polymer sheets should be processed at the highest laser-beam scanning speed that can make thin films.
first_indexed 2024-03-10T01:22:19Z
format Article
id doaj.art-c74ea2c5cf0b4e3db4c6293ea398f775
institution Directory Open Access Journal
issn 2073-4360
language English
last_indexed 2024-03-10T01:22:19Z
publishDate 2022-08-01
publisher MDPI AG
record_format Article
series Polymers
spelling doaj.art-c74ea2c5cf0b4e3db4c6293ea398f7752023-11-23T13:58:03ZengMDPI AGPolymers2073-43602022-08-011417350810.3390/polym14173508Thermal Effect on Thin-Film Formation of the Polymer Sheets by the CO<sub>2</sub> Laser with the Copper BaseNobukazu Kameyama0Hiroki Yoshida1Department of Electrical, Electronic and Computer Engineering, Faculty of Engineering, Gifu University, 1-1 Yanagito, Gifu City 501-1193, JapanDepartment of Electrical, Electronic and Computer Engineering, Faculty of Engineering, Gifu University, 1-1 Yanagito, Gifu City 501-1193, JapanA method that makes polymer sheets partially thinner with continuous-wave carbon dioxide (CO<sub>2</sub>) lasers has been developed. This method can create thin polymer films by attaching the polymer sheets to the copper base by vacuum suction through the holes in the base. Applying the method to polypropylene (PP), polyethylene terephthalate (PET), polystyrene (PS), and polytetrafluoroethylene (PTFE), the thin-film formation is confirmed in PP, PET, and PS but not PTFE. These polymers have the similar thermal properties. PP, PET, and PS show fluidity with increased temperature, but PTFE does not have fluidity. These characteristics of the polymers indicate that the fluidity of polymer is the important characteristic for film formation. The experiments with PP and PET sheets of different thickness show that thicker sheets make thicker films. The fluid flow of the molten polymer is considered to form the thin film at the bottom of the groove made by laser scribing. The numerical simulation of the 2D thermal model also indicates the week cooling effects of the base on the film formation and importance of polymer fluidity. The results of Fourier transform infrared spectrometer (FT-IR) show thermal degradation of the films. To decrease the heat’s effect on the films, the polymer sheets should be processed at the highest laser-beam scanning speed that can make thin films.https://www.mdpi.com/2073-4360/14/17/3508polymerpolystyrenepolypropylenepolyethylene terephthalatelaser processingCO<sub>2</sub> laser
spellingShingle Nobukazu Kameyama
Hiroki Yoshida
Thermal Effect on Thin-Film Formation of the Polymer Sheets by the CO<sub>2</sub> Laser with the Copper Base
Polymers
polymer
polystyrene
polypropylene
polyethylene terephthalate
laser processing
CO<sub>2</sub> laser
title Thermal Effect on Thin-Film Formation of the Polymer Sheets by the CO<sub>2</sub> Laser with the Copper Base
title_full Thermal Effect on Thin-Film Formation of the Polymer Sheets by the CO<sub>2</sub> Laser with the Copper Base
title_fullStr Thermal Effect on Thin-Film Formation of the Polymer Sheets by the CO<sub>2</sub> Laser with the Copper Base
title_full_unstemmed Thermal Effect on Thin-Film Formation of the Polymer Sheets by the CO<sub>2</sub> Laser with the Copper Base
title_short Thermal Effect on Thin-Film Formation of the Polymer Sheets by the CO<sub>2</sub> Laser with the Copper Base
title_sort thermal effect on thin film formation of the polymer sheets by the co sub 2 sub laser with the copper base
topic polymer
polystyrene
polypropylene
polyethylene terephthalate
laser processing
CO<sub>2</sub> laser
url https://www.mdpi.com/2073-4360/14/17/3508
work_keys_str_mv AT nobukazukameyama thermaleffectonthinfilmformationofthepolymersheetsbythecosub2sublaserwiththecopperbase
AT hirokiyoshida thermaleffectonthinfilmformationofthepolymersheetsbythecosub2sublaserwiththecopperbase