Material extrusion-based additive manufacturing of polyetheretherketone cranial implants: Mechanical performance and print quality

Polyetheretherketone (PEEK) is considered a ‘gold-standard’ material choice for cranial bone reconstruction. The introduction of additive manufacturing (AM) into the pipeline for patient specific cranial implant (PSCI) fabrication could accelerate supply chain needs and improve patient outcomes. Fus...

Full description

Bibliographic Details
Main Authors: Sandra Petersmann, James A. Smith, Ute Schäfer, Florian Arbeiter
Format: Article
Language:English
Published: Elsevier 2023-01-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785422018488
_version_ 1797943046025773056
author Sandra Petersmann
James A. Smith
Ute Schäfer
Florian Arbeiter
author_facet Sandra Petersmann
James A. Smith
Ute Schäfer
Florian Arbeiter
author_sort Sandra Petersmann
collection DOAJ
description Polyetheretherketone (PEEK) is considered a ‘gold-standard’ material choice for cranial bone reconstruction. The introduction of additive manufacturing (AM) into the pipeline for patient specific cranial implant (PSCI) fabrication could accelerate supply chain needs and improve patient outcomes. Fused filament fabrication (FFF), a material extrusion-based technology, is a much-researched process due to its accessibility and ease of use. However, the quality of PEEK processed by FFF is highly affected by the applied printing profile. Therefore, in this study, the effects of printing parameters such as build orientation and air flow temperature on mechanical performance (cyclic and impact tests) and implant quality (characterisation of surface topography, discoloration and crystallinity) were analysed and compared with a commercial milled PEEK implant. It has been found that horizontally printed implants show higher mechanical integrity compared to implants printed upright or tilted by 45°, but obtain lower surface quality. In addition, lower air flow temperatures lead to strong implant discolorations due to high amounts of amorphousness, which further result in high absorbed energies during impact as well as large deformations until complete failure. The best results from a mechanical point of view were achieved with PSCIs printed at a build orientation of 180°, an air flow temperature of 210 °C, a shell number of 3, a layer height of 0.15 mm, a printing speed of 50 mm/min, a rectilinear ±45° infill pattern and an implant thickness of 5 mm. However, the surface quality of implants produced this way is not completely satisfactory, and the arrangement of the support structures must be further improved.
first_indexed 2024-04-10T20:18:11Z
format Article
id doaj.art-c75457ae60ef41e3bfd52997305f766c
institution Directory Open Access Journal
issn 2238-7854
language English
last_indexed 2024-04-10T20:18:11Z
publishDate 2023-01-01
publisher Elsevier
record_format Article
series Journal of Materials Research and Technology
spelling doaj.art-c75457ae60ef41e3bfd52997305f766c2023-01-26T04:45:41ZengElsevierJournal of Materials Research and Technology2238-78542023-01-0122642657Material extrusion-based additive manufacturing of polyetheretherketone cranial implants: Mechanical performance and print qualitySandra Petersmann0James A. Smith1Ute Schäfer2Florian Arbeiter3Materials Science and Testing of Polymers, Montanuniversitaet Leoben, Otto Gloeckel-Straße 2, 8700, Leoben, AustriaResearch Unit Experimental Neurotraumatology, Department of Neurosurgery, Medical University of Graz, Auenbruggerplatz 22, 8036, Graz, AustriaResearch Unit Experimental Neurotraumatology, Department of Neurosurgery, Medical University of Graz, Auenbruggerplatz 22, 8036, Graz, Austria; BioTechMed-Graz, Graz, AustriaMaterials Science and Testing of Polymers, Montanuniversitaet Leoben, Otto Gloeckel-Straße 2, 8700, Leoben, Austria; Corresponding author.Polyetheretherketone (PEEK) is considered a ‘gold-standard’ material choice for cranial bone reconstruction. The introduction of additive manufacturing (AM) into the pipeline for patient specific cranial implant (PSCI) fabrication could accelerate supply chain needs and improve patient outcomes. Fused filament fabrication (FFF), a material extrusion-based technology, is a much-researched process due to its accessibility and ease of use. However, the quality of PEEK processed by FFF is highly affected by the applied printing profile. Therefore, in this study, the effects of printing parameters such as build orientation and air flow temperature on mechanical performance (cyclic and impact tests) and implant quality (characterisation of surface topography, discoloration and crystallinity) were analysed and compared with a commercial milled PEEK implant. It has been found that horizontally printed implants show higher mechanical integrity compared to implants printed upright or tilted by 45°, but obtain lower surface quality. In addition, lower air flow temperatures lead to strong implant discolorations due to high amounts of amorphousness, which further result in high absorbed energies during impact as well as large deformations until complete failure. The best results from a mechanical point of view were achieved with PSCIs printed at a build orientation of 180°, an air flow temperature of 210 °C, a shell number of 3, a layer height of 0.15 mm, a printing speed of 50 mm/min, a rectilinear ±45° infill pattern and an implant thickness of 5 mm. However, the surface quality of implants produced this way is not completely satisfactory, and the arrangement of the support structures must be further improved.http://www.sciencedirect.com/science/article/pii/S2238785422018488PolyetheretherketonePEEKFused filament fabricationCranial implantMechanical integrityCrystallinity
spellingShingle Sandra Petersmann
James A. Smith
Ute Schäfer
Florian Arbeiter
Material extrusion-based additive manufacturing of polyetheretherketone cranial implants: Mechanical performance and print quality
Journal of Materials Research and Technology
Polyetheretherketone
PEEK
Fused filament fabrication
Cranial implant
Mechanical integrity
Crystallinity
title Material extrusion-based additive manufacturing of polyetheretherketone cranial implants: Mechanical performance and print quality
title_full Material extrusion-based additive manufacturing of polyetheretherketone cranial implants: Mechanical performance and print quality
title_fullStr Material extrusion-based additive manufacturing of polyetheretherketone cranial implants: Mechanical performance and print quality
title_full_unstemmed Material extrusion-based additive manufacturing of polyetheretherketone cranial implants: Mechanical performance and print quality
title_short Material extrusion-based additive manufacturing of polyetheretherketone cranial implants: Mechanical performance and print quality
title_sort material extrusion based additive manufacturing of polyetheretherketone cranial implants mechanical performance and print quality
topic Polyetheretherketone
PEEK
Fused filament fabrication
Cranial implant
Mechanical integrity
Crystallinity
url http://www.sciencedirect.com/science/article/pii/S2238785422018488
work_keys_str_mv AT sandrapetersmann materialextrusionbasedadditivemanufacturingofpolyetheretherketonecranialimplantsmechanicalperformanceandprintquality
AT jamesasmith materialextrusionbasedadditivemanufacturingofpolyetheretherketonecranialimplantsmechanicalperformanceandprintquality
AT uteschafer materialextrusionbasedadditivemanufacturingofpolyetheretherketonecranialimplantsmechanicalperformanceandprintquality
AT florianarbeiter materialextrusionbasedadditivemanufacturingofpolyetheretherketonecranialimplantsmechanicalperformanceandprintquality