Application of Perovskite as Solution‐Processed Solid Electrolyte in Polymer Electrochemical Transistor

Abstract The electrolyte serves as a key component in organic electrochemical transistors (OECTs) and allows for the modulation of the conductivity of the polymer channel by applying a voltage to the gate electrode. Different from liquid electrolytes in OECTs, the solid electrolyte is beneficial for...

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Main Authors: Xinlu Teng, Lin Lin, Jun Sun, Haoxin Tian, Jia Li, Shichuan Ke, Zhidong Lou, Yanbing Hou, Yufeng Hu, Feng Teng
Format: Article
Language:English
Published: Wiley-VCH 2023-10-01
Series:Advanced Electronic Materials
Subjects:
Online Access:https://doi.org/10.1002/aelm.202300337
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author Xinlu Teng
Lin Lin
Jun Sun
Haoxin Tian
Jia Li
Shichuan Ke
Zhidong Lou
Yanbing Hou
Yufeng Hu
Feng Teng
author_facet Xinlu Teng
Lin Lin
Jun Sun
Haoxin Tian
Jia Li
Shichuan Ke
Zhidong Lou
Yanbing Hou
Yufeng Hu
Feng Teng
author_sort Xinlu Teng
collection DOAJ
description Abstract The electrolyte serves as a key component in organic electrochemical transistors (OECTs) and allows for the modulation of the conductivity of the polymer channel by applying a voltage to the gate electrode. Different from liquid electrolytes in OECTs, the solid electrolyte is beneficial for the integration in the circuit and shows great stability. And considering the fabrication of the device, developing a new solution‐processed solid electrolyte for OECTs is a critical area of research. In this work, the organic–inorganic perovskite is used as the electrolyte to fabricate polymer electrochemical transistors due to its solid‐phase ion migration kinetics. To realize this goal, a separate polyethylene oxide (PEO) layer on top of the poly[2‐methoxy‐5‐(2‐ethylhexyloxy)‐1,4‐phenylenevinylene] (MEH‐PPV) layer plays a crucial role since it can affect the electric field and the ion motion. More importantly, based on this device structure, both a polymer light‐emitting electrochemical transistor and the polymer electrochemical phototransistor are realized. The solution‐processed solid organic–inorganic perovskite electrolytes can enable the development of integration in OECTs, which have significant potential for multifunctional applications.
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spelling doaj.art-c76201c6add24488be3b85959e55f5012023-10-10T05:50:39ZengWiley-VCHAdvanced Electronic Materials2199-160X2023-10-01910n/an/a10.1002/aelm.202300337Application of Perovskite as Solution‐Processed Solid Electrolyte in Polymer Electrochemical TransistorXinlu Teng0Lin Lin1Jun Sun2Haoxin Tian3Jia Li4Shichuan Ke5Zhidong Lou6Yanbing Hou7Yufeng Hu8Feng Teng9Key Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaKey Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaKey Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaKey Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaKey Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaKey Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaKey Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaKey Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaKey Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaKey Laboratory of Luminescence and Optical Information Ministry of Education Institute of Optoelectronic Technology Beijing Jiaotong University Beijing100044P. R. ChinaAbstract The electrolyte serves as a key component in organic electrochemical transistors (OECTs) and allows for the modulation of the conductivity of the polymer channel by applying a voltage to the gate electrode. Different from liquid electrolytes in OECTs, the solid electrolyte is beneficial for the integration in the circuit and shows great stability. And considering the fabrication of the device, developing a new solution‐processed solid electrolyte for OECTs is a critical area of research. In this work, the organic–inorganic perovskite is used as the electrolyte to fabricate polymer electrochemical transistors due to its solid‐phase ion migration kinetics. To realize this goal, a separate polyethylene oxide (PEO) layer on top of the poly[2‐methoxy‐5‐(2‐ethylhexyloxy)‐1,4‐phenylenevinylene] (MEH‐PPV) layer plays a crucial role since it can affect the electric field and the ion motion. More importantly, based on this device structure, both a polymer light‐emitting electrochemical transistor and the polymer electrochemical phototransistor are realized. The solution‐processed solid organic–inorganic perovskite electrolytes can enable the development of integration in OECTs, which have significant potential for multifunctional applications.https://doi.org/10.1002/aelm.202300337electrochemical dopinglight‐emittingperovskite electrolytesphototransistorstransistors
spellingShingle Xinlu Teng
Lin Lin
Jun Sun
Haoxin Tian
Jia Li
Shichuan Ke
Zhidong Lou
Yanbing Hou
Yufeng Hu
Feng Teng
Application of Perovskite as Solution‐Processed Solid Electrolyte in Polymer Electrochemical Transistor
Advanced Electronic Materials
electrochemical doping
light‐emitting
perovskite electrolytes
phototransistors
transistors
title Application of Perovskite as Solution‐Processed Solid Electrolyte in Polymer Electrochemical Transistor
title_full Application of Perovskite as Solution‐Processed Solid Electrolyte in Polymer Electrochemical Transistor
title_fullStr Application of Perovskite as Solution‐Processed Solid Electrolyte in Polymer Electrochemical Transistor
title_full_unstemmed Application of Perovskite as Solution‐Processed Solid Electrolyte in Polymer Electrochemical Transistor
title_short Application of Perovskite as Solution‐Processed Solid Electrolyte in Polymer Electrochemical Transistor
title_sort application of perovskite as solution processed solid electrolyte in polymer electrochemical transistor
topic electrochemical doping
light‐emitting
perovskite electrolytes
phototransistors
transistors
url https://doi.org/10.1002/aelm.202300337
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